Thermodynamically stable noncomposite vortices in mesoscopic two-gap superconductors

In mesoscopic two-gap superconductors with sizes of the order of the coherence length noncomposite vortices are found to be thermodynamically stable in a large domain of the $T - H$ phase diagram. In these phases the vortex cores of one condensate are spatially separated from the other condensate ones, and their respective distributions can adopt distinct symmetries. The appearance of these vortex phases is caused by a non-negligible effect of the boundary of the sample on the superconducting order parameter and represents therefore a genuine mesoscopic effect. For low values of interband Josephson coupling vortex patterns with $L_1 \neq L_2$ can arise in addition to the phases with $L_1 =L_2$, where $L_1$ and $L_2$ are total vorticities in the two condensates. The calculations show that noncomposite vortices could be observed in thin mesoscopic samples of MgB$_{2}$.Comment: 5 pages, 3 figures, to be published in Europhysics Letter

Quantum fluctuations of D5dD_{5d} polarons on C60C_{60} molecules

The dynamic Jahn-Teller splitting of the six equivalent $D_{5d}$ polarons due to quantum fluctuations is studied in the framework of the Bogoliubov-de Gennes formalism. The tunneling induced level splittings are determined to be $^2 T_{1u} \bigoplus ^2 T_{2u}$ and $^1 A_g \bigoplus ^1 H_g$ for $C_{60}^{1-}$ and $C_{60}^{2-}$, respectively, which should give rise to observable effects in experiments.Comment: REVTEX 3.0, 13 pages, to be published in Phys. Rev.

Theory of Spontaneous Polarization of Endohedral Fullerenes

A pseudo-Jahn-Teller model describing central atom distortions is proposed for endohedral fullerenes of the form A@C$_{60}$ where A is either a rare gas or a metal atom. A critical (dimensionless) coupling $g_c$ is found, below which the symmetric configuration is stable and above which inversion symmetry is broken. Vibronic parameters are given for selected endohedral fullerenes.Comment: 4 pages, REVTEX, 1 Postscript figure. [Phys. Rev. Lett. (in press)

Dynamical Jahn-Teller Effect and Berry Phase in Positively Charged Fullerene I. Basic Considerations

We study the Jahn-Teller effect of positive fullerene ions $^2$C$_{60}^{+}$ and $^1$C$_{60}^{2+}$. The aim is to discover if this case, in analogy with the negative ion, possesses a Berry phase or not, and what are the consequences on dynamical Jahn-Teller quantization. Working in the linear and spherical approximation, we find no Berry phase in $^1$C$_{60}^{2+}$, and presence/absence of Berry phase for coupling of one $L=2$ hole to an $L=4$/$L=2$ vibration. We study in particular the special equal-coupling case ($g_2=g_4$), which is reduced to the motion of a particle on a 5-dimensional sphere. In the icosahedral molecule, the final outcome assesses the presence/absence of a Berry phase of $\pi$ for the $h_u$ hole coupled to $G_g$/$H_h$ vibrations. Some qualitative consequences on ground-state symmetry, low-lying excitations, and electron emission from C$_{60}$ are spelled out.Comment: 31 pages (RevTeX), 3 Postscript figures (uuencoded

Enhanced ozone strongly reduces carbon sink strength of adult beech (Fagus sylvatica) – Resume from the free-air fumigation study at Kranzberg Forest

Ground-level ozone (O3) has gained awareness as an agent of climate change. In this respect, key results are comprehended from a unique 8-year free-air O3-fumigation experiment, conducted on adult beech (Fagus sylvatica) at Kranzberg Forest (Germany). A novel canopy O3 exposure methodology was employed that allowed whole-tree assessment in situ under twice-ambient O3 levels. Elevated O3 significantly weakened the C sink strength of the tree–soil system as evidenced by lowered photosynthesis and 44% reduction in whole-stem growth, but increased soil respiration. Associated effects in leaves and roots at the gene, cell and organ level varied from year to year, with drought being a crucial determinant of O3 responsiveness. Regarding adult individuals of a late-successional tree species, empirical proof is provided first time in relation to recent modelling predictions that enhanced ground-level O3 can substantially mitigate the C sequestration of forests in view of climate change

Atmospheric drivers of storage water use in Scots pine

International audienceIn this study we determined the microclimatic drivers of storage water use in Scots pine (Pinus sylvestris L.) growing in a temperate climate. The storage water use was modeled using the ANAFORE model, integrating a dynamic water flow and ? storage model with a process-based transpiration model. The model was calibrated and validated with sap flow measurements for the growing season of 2000 (26 May?18 October). Because there was no severe soil drought during the study period, we were able to study atmospheric effects. Incoming radiation was the main driver of storage water use. The general trends of sap flow and storage water use are similar, and follow more or less the pattern of incoming radiation. Nevertheless, considerable differences in the day-to-day pattern of sap flow and storage water use were observed, mainly driven by vapour pressure deficit (VPD). During dry atmospheric conditions (high VPD) storage water use was reduced. This reduction was disproportionally higher than the reduction in measured sap flow. Our results suggest that the trees did not rely more on storage water during periods of atmospheric drought, without severe soil drought. A third important factor was the tree water deficit. When storage compartments were depleted beyond a threshold, storage water use was limited due to the low water potential in the storage compartments. The maximum relative contribution of storage water to daily transpiration was also constrained by an increasing tree water deficit

A pictorial visualization of normal mode vibrations of the fullerene C_60 molecule in terms of vibrations of a hollow sphere

Understanding the normal mode vibrations of a molecule is important in the analysis of vibrational spectra. However, the complicated 3D motion of large molecules can be difficult to interpret. We show how images of normal modes of the fullerene molecule C60 can be made easier to understand by superimposing them on images of the normal mode vibrations of a thin spherical shell. We describe an interactive demonstration that allows the normal mode to be viewed with or without the shell. The images of the normal modes can be reoriented, and animated to show the vibration. In addition, supporting information includes images of all 174 normal modes of C60 in a common orientation, each of which can be animated. The ideas could be applied to other molecules in which the atoms all lie close to the surface of a sphere

Thermal adaptation of net ecosystem exchange

Thermal adaptation of gross primary production and ecosystem respiration has been well documented over broad thermal gradients. However, no study has examined their interaction as a function of temperature, i.e. the thermal responses of net ecosystem exchange of carbon (NEE). In this study, we constructed temperature response curves of NEE against temperature using 380 site-years of eddy covariance data at 72 forest, grassland and shrubland ecosystems located at latitudes ranging from ~29° N to 64° N. The response curves were used to define two critical temperatures: transition temperature (<i>T</i><sub>b</sub>) at which ecosystem transfer from carbon source to sink and optimal temperature (<i>T</i><sub>o</sub>) at which carbon uptake is maximized. <i>T</i><sub>b</sub> was strongly correlated with annual mean air temperature. <i>T</i><sub>o</sub> was strongly correlated with mean temperature during the net carbon uptake period across the study ecosystems. Our results imply that the net ecosystem exchange of carbon adapts to the temperature across the geographical range due to intrinsic connections between vegetation primary production and ecosystem respiration

Surprises in the Orbital Magnetic Moment and g-Factor of the Dynamic Jahn-Teller Ion C_{60}^-

We calculate the magnetic susceptibility and g-factor of the isolated C_{60}^- ion at zero temperature, with a proper treatment of the dynamical Jahn-Teller effect, and of the associated orbital angular momentum, Ham-reduced gyromagnetic ratio, and molecular spin-orbit coupling. A number of surprises emerge. First, the predicted molecular spin-orbit splitting is two orders of magnitude smaller than in the bare carbon atom, due to the large radius of curvature of the molecule. Second, this reduced spin-orbit splitting is comparable to Zeeman energies, for instance, in X-band EPR at 3.39KGauss, and a field dependence of the g-factor is predicted. Third, the orbital gyromagnetic factor is strongly reduced by vibron coupling, and so therefore are the effective weak-field g-factors of all low-lying states. In particular, the ground-state doublet of C_{60}^- is predicted to show a negative g-factor of \sim -0.1.Comment: 19 pages RevTex, 2 postscript figures include

Jahn–Teller instability in cationic boron and carbon buckyballs B₈₀⁺ and C₆₀⁺: a comparative study

This paper investigates the Jahn–Teller effect in the icosahedral cation B80+ and compares the descent in symmetry with that in C60+. For both cations the icosahedral ground state is a 2Hu state, which exhibits a H [multiply sign in circle] (g ⊕ 2h) Jahn–Teller instability. A detailed construction of the potential energy surface of B80+ using different DFT methods including B3LYP/6-31G(d), VWN/6-31G(d), PBE/TZP and PBE/6-31G(d) shows that, contrary to C60+, which prefers D5d symmetry, the ground state of B80+ adopts S6 point group symmetry. A D3d structure is identified as a saddle point among the S6 minima of B80+. The distortion of D3d to S6 in B80+ is attributed to a superposition of Jahn–Teller and pseudo-Jahn–Teller effects. Imaginary modes, transforming as the gg representation, which are present in neutral icosahedral B80, form the dominant symmetry breaking active modes. The pronounced difference between the JT effects in the boron and carbon buckyball cations is due to the plasticity of the boron caps. The calculated Jahn–Teller stabilization of B80+ is nearly 1549 cm−1 (PBE/TZP), which exceeds the stabilization of 596 cm−1 computed for C60+ at the same level