2,159 research outputs found

    Simulation of heavy rainfall over Mumbai on 26 july 2005 using high resolution icosahedral gridpoint model GME

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    In this paper an attempt has been made to simulate the exceptionally heavy rainfall event over Mumbai (Bombay) on 26 July 2005. Santa Cruz observatory near the International Airport of Mumbai recorded 944.2 mm of rainfall between 0300 UTC of 26 July 2005 and 0300 UTC of 27 July 2005 breaking all previous records. Some nearby places also recorded very heavy rainfall. Consequently, a deluge flooded the city and life in Mumbai came to a standstill. Mesoscale models or regional models are normally used to simulate such a small scale phenomenon. The model used in this paper to simulate the rainfall is the operational global numerical weather prediction model (GME) developed by the Deutscher Wetterdienst, The German Weather Service. Using European Center for Medium range Weather Forecast-ECMWF at T511 L91 data as the initial condition for the GME model, 24 hours accumulated precipitation has been computed. The model has a horizontal resolution of 40 km with 40 vertical levels and time step of 133s. The computed rainfall agrees reasonably well with the actual precipitation. The localized heavy rainfall might have occurred over Mumbai possibly due to several factors such as: well-marked low pressure over Orissa and adjoining Jharkhand with associated cyclonic circulation extending up to mid-troposheric level; off-shore trough on the west coast of India; low level jet over the peninsular India; intense convection and orographic lifting and interactions among these meteorological phenomena of different scales

    Dynamic modeling of three-phase upflow fixed-bed reactor including pore diffusion

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    The dynamics of a three-phase upflow fixed-bed reactor are investigated using a non-isothermal heterogeneous model including gas–liquid and liquid–solid mass transfer and diffusion/reaction phenomena inside the catalyst. The partial differential and algebraic equations involving three integration variables (time and two space coordinates) are solved via discretization of the spatial coordinates coupled with the Gear method. For a multistep hydrogenation on a shell catalyst, the model exhibits significant effects of the external and above all internal resistance to hydrogen transfer but also non-trivial internal hydrocarbons concentration profiles. A simplified model is compared with the extended one and with experimental data in transient regime. In the investigated conditions—hydrocarbons in large excess—the diffusion of hydrocarbons appears to be actually not limiting, so that the simplest model predicts accurately the transient reactor behavior

    Phenomenological BCS theory of the high-TcT_c cuprates

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    A BCS model characterized by a phenomenological pair potential with on-site (V0V_0), nearest (V1V_1), and next nearest (V2V_2) neighbour coupling constants, and an empirical quasiparticle dispersion taken from angle-resolved photoemission spectra is considered. The model can consistently explain the experimental data concerning the pair state of the hole doped cuprates. Three ingredients are required to make the interpretation possible: the existence of flat bands, a very small effective on-site repulsion, and a slightly dominating effective nnn attraction V2V_2 of the order of 60-80meV with a ratio V2/V11.5V_2/V_1 \approx 1.5.Comment: 13 pages, uuencoded Postscrip

    S and D Wave Mixing in High TcT_c Superconductors

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    For a tight binding model with nearest neighbour attraction and a small orthorhombic distortion, we find a phase diagram for the gap at zero temperature which includes three distinct regions as a function of filling. In the first, the gap is a mixture of mainly dd-wave with a smaller extended ss-wave part. This is followed by a region in which there is a rapid increase in the ss-wave part accompanied by a rapid increase in relative phase between ss and dd from 0 to π\pi. Finally, there is a region of dominant ss with a mixture of dd and zero phase. In the mixed region with a finite phase, the ss-wave part of the gap can show a sudden increase with decreasing temperature accompanied with a rapid increase in phase which shows many of the characteristics measured in the angular resolved photoemission experiments of Ma {\em et al.} in Bi2Sr2CaCu2O8\rm Bi_2Sr_2CaCu_2O_8Comment: 12 pages, RevTeX 3.0, 3 PostScript figures uuencoded and compresse

    Self-generated magnetic flux in YBa2_2Cu3_3O7x_{7-x} grain boundaries

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    Grain boundaries in YBa2_2Cu3_3O7x_{7-x} superconducting films are considered as Josephson junctions with a critical current density jc(x)j_c(x) alternating along the junction. A self-generated magnetic flux is treated both analytically and numerically for an almost periodic distribution of jc(x)j_c(x). We obtained a magnetic flux-pattern similar to the one which was recently observed experimentally.Comment: 7 pages, 3 figure

    On the selection and design of proteins and peptide derivatives for the production of photoluminescent, red-emitting gold quantum clusters

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    Novel pathways of the synthesis of photoluminescent gold quantum clusters (AuQCs) using biomolecules as reactants provide biocompatible products for biological imaging techniques. In order to rationalize the rules for the preparation of red-emitting AuQCs in aqueous phase using proteins or peptides, the role of different organic structural units was investigated. Three systems were studied: proteins, peptides, and amino acid mixtures, respectively. We have found that cysteine and tyrosine are indispensable residues. The SH/S-S ratio in a single molecule is not a critical factor in the synthesis, but on the other hand, the stoichiometry of cysteine residues and the gold precursor is crucial. These observations indicate the importance of proper chemical behavior of all species in a wide size range extending from the atomic distances (in the AuI-S semi ring) to nanometer distances covering the larger sizes of proteins assuring the hierarchical structure of the whole self-assembled system
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