A Versatile Active Block: DXCCCII and Tunable Applications

The study describes dual-X controlled current conveyor (DXCCCII) as a versatile active block and its application to inductance simulators for testing. Moreover, the high pass filter application using with DXCCCII based inductance simulator and oscillator with flexible tunable oscillation frequency have been presented and simulated to confirm the theoretical validity. The proposed circuit which has a simple circuit design requires the low-voltage and the DXCCCII can also be tuned in the wide range by the biasing current. The proposed DXCCCII provides a good linearity, high output impedance at Z terminals, and a reasonable current and voltage transfer gain accuracy. The proposed DXCCCII and its applications have been simulated using the CMOS 0.18 µm technology

Yarı Kristal Polimer Malzemelerin Çok Ölçekli Modellenmesi

Konferans Bildirisi -- Teorik ve Uygulamalı Mekanik Türk Milli Komitesi, 2013Conference Paper -- Theoretical and Applied Mechanical Turkish National Committee, 2013Bu çalışmada iki fazlı yarı kristal polimerik malzemeler için geometrik olarak doğrusal olmayan, mikromekaniksel motivasyonlu ve çok ölçekli bir malzeme modeli geliştirilmiştir. Bu amaç doğrultusunda, amorf ve kristal fazlar için en önemli şekil değiştirme mekanizmaları belirlenmiş ve bu bilgi ışığında her iki faz için ayrı ayrı mikromekaniksel motivasyonu bulunan malzeme modelleri kullanılmıştır. Ardından, iki fazlı yapıyı homojenleştirerek yarı kristal polimer malzemenin makroskopik davranışını betimleyecek bir model geliştirilmiştir.In this paper a geometrically non-linear micromechanically-motivated multi-scale model is developed for two phase semi-crystalline polymeric materials. To this end, most important deformation mechanisms of amorphous and crystalline phases are determined; and in the light of this information, micromechanically-motivated material models are employed separately for both phases. Afterwards, by homogenization of the two-phase structure, , a model that would render the macroscopic response of the semi crystalline polymeric material is developed

Possible evolution of dim radio quiet neutron star 1E 1207.4-5209 based on a B-decay model

Dim radio-quiet neutron star (DRQNS) 1E 1207.4-5209 is one of the most heavily examined isolated neutron stars. Wide absorption lines were observed in its spectrum obtained by both XMM-Newton and Chandra X-ray satellites. These absorption lines can be interpreted as a principal frequency centered at 0.7 keV and its harmonics at 1.4, 2.1 and possibly 2.8 keV. The principal line can be formed by resonant proton cyclotron scattering leading to a magnetic field which is two orders of magnitude larger than the perpendicular component of the surface dipole magnetic field (B) found from the rotation period (P) and the time rate of change in the rotation period (\.{P}) of 1E 1207.4-5209. Besides, age of the supernova remnant (SNR) G296.5+10.0 which is physically connected to 1E 1207.4-5209 is two orders of magnitude smaller than the characteristic age ($\tau$=P/2\.{P}) of the neutron star. These huge differences between the magnetic field values and the ages can be explained based on a B-decay model. If the decay is assumed to be exponential, the characteristic decay time turns out to be several thousand years which is three orders of magnitude smaller than the characteristic decay time of radio pulsars represented in an earlier work. The lack of detection of radio emission from DRQNSs and the lack of point sources and pulsar wind nebulae in most of the observed SNRs can also be partly explained by such a very rapid exponential decay. The large difference between the characteristic decay times of DRQNSs and radio pulsars must be related to the differences in the magnetic fields, equation of states and masses of these isolated neutron stars.Comment: 13 pages, 1 figur

RXTE Studies of Long-Term X-ray Spectral Variations in 4U 1820-30

We present the results of detailed spectral studies of the ultra-compact low mass X-ray binary (LMXB) 4U 1820-30 carried out with the Rossi X-ray Timing Explorer (RXTE) during 1996-7. 4U 1820-30 is an ``atoll'' source X-ray burster (XRB) located in the globular cluster NGC 6624. It is known to have an 11 minute binary period and a ~176 day modulation in its 2--12 keV flux. Observations were made with the PCA and HEXTE instruments on RXTE at roughly one-month intervals to sample this long-term period and study flux-related spectral changes. There are clear correlations between our fitted spectral parameters and both the broad-band (2--50 keV) flux and the position in the color-color diagram, as described by the parameter S_a introduced by Mendez et al. (1999). In addition, we find a strong correlation between the position in the color-color diagram and the frequencies of the kilohertz quasi-periodic oscillations (kHz QPOs) reported by Zhang et al. (1998). This lends further support to the notion that evidence for the last stable orbit in the accretion disk of 4U 1820-30 has been observed. For a model consisting of Comptonization of cool photons by hot electrons plus an additional blackbody component, we report an abrupt change in the spectral parameters at the same accretion rate at which the kHz QPOs disappear. For a model consisting of a multicolor disk blackbody plus a cut-off power law, we find that the inner disk radius reaches a minimum at the same accretion rate at which the kHz QPO frequency saturates, as expected if the disk reaches the last stable orbit. Both models face theoretical and observational problems when interpreted physically for this system.Comment: 39 pages, 11 figures, accepted to the Astrophysical Journa

Nuclear Inelastic X-Ray Scattering of FeO to 48 GPa

The partial density of vibrational states has been measured for Fe in compressed FeO (w\"ustite) using nuclear resonant inelastic x-ray scattering. Substantial changes have been observed in the overall shape of the density of states close to the magnetic transiton around 20 GPa from the paramagnetic (low pressure) to the antiferromagnetic (high pressure) state. Our data indicate a substantial softening of the aggregate sound velocities far below the transition, starting between 5 and 10 GPa. This is consistent with recent radial x-ray diffraction measurements of the elastic constants in FeO. The results indicate that strong magnetoelastic coupling in FeO is the driving force behind the changes in the phonon spectrum of FeO.Comment: 4 pages, 4 figure

Electronic Structures of an [Fe(NNR_2)]^(+/0/–) Redox Series: Ligand Noninnocence and Implications for Catalytic Nitrogen Fixation

The intermediacy of metal–NNH_2 complexes has been implicated in the catalytic cycles of several examples of transition-metal-mediated nitrogen (N_2) fixation. In this context, we have shown that triphosphine-supported Fe(N_2) complexes can be reduced and protonated at the distal N atom to yield Fe(NNH_2) complexes over an array of charge and oxidation states. Upon exposure to further H^+/e^– equivalents, these species either continue down a distal-type Chatt pathway to yield a terminal iron(IV) nitride or instead follow a distal-to-alternating pathway resulting in N–H bond formation at the proximal N atom. To understand the origin of this divergent selectivity, herein we synthesize and elucidate the electronic structures of a redox series of Fe(NNMe_2) complexes, which serve as spectroscopic models for their reactive protonated congeners. Using a combination of spectroscopies, in concert with density functional theory and correlated ab initio calculations, we evidence one-electron redox noninnocence of the “NNMe_2” moiety. Specifically, although two closed-shell configurations of the “NNR_2” ligand have been commonly considered in the literature—isodiazene and hydrazido(2−)—we provide evidence suggesting that, in their reduced forms, the present iron complexes are best viewed in terms of an open-shell [NNR_2]^•–ligand coupled antiferromagnetically to the Fe center. This one-electron redox noninnocence resembles that of the classically noninnocent ligand NO and may have mechanistic implications for selectivity in N_2 fixation activity

Turner syndrome and associated problems in turkish children: A multicenter study

Objective: Turner syndrome (TS) is a chromosomal disorder caused by complete or partial X chromosome monosomy that manifests various clinical features depending on the karyotype and on the genetic background of affected girls. This study aimed to systematically investigate the key clinical features of TS in relationship to karyotype in a large pediatric Turkish patient population. Methods: Our retrospective study included 842 karyotype-proven TS patients aged 0-18 years who were evaluated in 35 different centers in Turkey in the years 2013-2014. Results: The most common karyotype was 45,X (50.7%), followed by 45,X/46,XX (10.8%), 46,X,i(Xq) (10.1%) and 45,X/46,X,i(Xq) (9.5%). Mean age at diagnosis was 10.2±4.4 years. The most common presenting complaints were short stature and delayed puberty. Among patients diagnosed before age one year, the ratio of karyotype 45,X was significantly higher than that of other karyotype groups. Cardiac defects (bicuspid aortic valve, coarctation of the aorta and aortic stenosi) were the most common congenital anomalies, occurring in 25% of the TS cases. This was followed by urinary system anomalies (horseshoe kidney, double collector duct system and renal rotation) detected in 16.3%. Hashimoto’s thyroiditis was found in 11.1% of patients, gastrointestinal abnormalities in 8.9%, ear nose and throat problems in 22.6%, dermatologic problems in 21.8% and osteoporosis in 15.3%. Learning difficulties and/or psychosocial problems were encountered in 39.1%. Insulin resistance and impaired fasting glucose were detected in 3.4% and 2.2%, respectively. Dyslipidemia prevalence was 11.4%. Conclusion: This comprehensive study systematically evaluated the largest group of karyotype-proven TS girls to date. The karyotype distribution, congenital anomaly and comorbidity profile closely parallel that from other countries and support the need for close medical surveillance of these complex patients throughout their lifespan. © Journal of Clinical Research in Pediatric Endocrinology