6-Deoxyhexoses froml-Rhamnose in the Search for Inducers of the Rhamnose Operon: Synergy of Chemistry and Biotechnology

In the search for alternative non‐metabolizable inducers in the l ‐rhamnose promoter system, the synthesis of fifteen 6‐deoxyhexoses from l ‐rhamnose demonstrates the value of synergy between biotechnology and chemistry. The readily available 2,3‐acetonide of rhamnonolactone allows inversion of configuration at C4 and/or C5 of rhamnose to give 6‐deoxy‐d ‐allose, 6‐deoxy‐d ‐gulose and 6‐deoxy‐l ‐talose. Highly crystalline 3,5‐benzylidene rhamnonolactone gives easy access to l ‐quinovose (6‐deoxy‐l ‐glucose), l ‐olivose and rhamnose analogue with C2 azido, amino and acetamido substituents. Electrophilic fluorination of rhamnal gives a mixture of 2‐deoxy‐2‐fluoro‐l ‐rhamnose and 2‐deoxy‐2‐fluoro‐l ‐quinovose. Biotechnology provides access to 6‐deoxy‐l ‐altrose and 1‐deoxy‐l ‐fructose

The radial velocity curve of HD153919 (4U1700-37) revisited

We have re-analysed all available high-resolution ultraviolet IUE spectra of the high-mass X-ray binary HD153919/4U1700-37. The radial velocity semi-amplitude of 20.6 +/- 1.0 km/s and orbital eccentricity of 0.22 +/- 0.04 agree very well with the values obtained earlier from optical spectra. They disagree with earlier conclusions for the same data reduced by Heap & Corcoran (1992) and by Stickland & Lloyd (1993).Comment: 6 pages, latex, figure included, Astronomy & Astrophysics, in pres

High-resolution O VI absorption line observations at 1.2 < z < 1.7 in the bright QSO HE 0515-4414

STIS Echelle observations at a resolution of 10 km/s and UVES/VLT spectroscopy at a resolution of 7 km/s of the luminous QSO HE 0515-4414 (z_em = 1.73, B = 15.0) reveal four intervening O VI absorption systems in the redshift range 1.2 < z_abs < 1.7 (1.38503, 1.41601, 1.60175, 1.67359). In addition two associated systems at z = 1.69707 and z = 1.73585 are present. For the first time high resolution observations allow to measure radial velocities of H I, C IV and O VI simultaneously in several absorption systems (1.385, 1.674, 1.697) with the result that significant velocity differences (up to 18 km/s) are observed between H I and O VI, while smaller differences (up to 5 km/s) are seen between C IV and O VI. We tentatively conclude that H I, O VI, and C IV are not formed in the same volumes and that therefore implications on ionization mechanisms are not possible from observed column density ratios O VI/H I or O VI/C IV. The number density of O VI absorbers with W_rest > 25 mA is dN/dz < 10, roughly a factor of 5 less than what has been found by Tripp at al. (2000) at low redshift. An estimate of the cosmological mass-density of the O VI-phase yields Omega_b(O VI) = 0.0003 h^{-1}_{75} for [O/H] = -1 and an assumed ionization fraction O VI/O = 0.2. This corresponds to an increase by roughly a factor of 15 between z = 1.5 (this work) and the value found by Tripp et al. (2000) at z = 0.21, if the same oxygen abundance [O/H] = -1 is assumed. Agreement with the simulations by Dave et al. (2001) can be obtained, if the oxygen abundance increases by a factor of 3 over the same redshift interval.Comment: 8 pages, 1 figure, accepted for publication in A&

Emission Line Galaxies in the STIS Parallel Survey I: Observations and Data Analysis

In the first three years of operation STIS obtained slitless spectra of approximately 2500 fields in parallel to prime HST observations as part of the STIS Parallel Survey (SPS). The archive contains almost 300 fields at high galactic latitude (|b|>30) with spectroscopic exposure times greater than 3000 seconds. This sample contains 220 fields (excluding special regions and requiring a consistent grating angle) observed between 6 June 1997 and 21 September 2000, with a total survey area of about 160 square arcminutes. At this depth, the SPS detects an average of one emission line galaxy per three fields. We present the analysis of these data, and the identification of 131 low to intermediate redshift galaxies detected by optical emission lines. The sample contains 78 objects with emission lines that we infer to be redshifted [OII]3727 emission at 0.43<z<1.7. The comoving number density of these objects is comparable to that of H-alpha emitting galaxies in the NICMOS parallel observations. One quasar and three probable Seyfert galaxies are detected. Many of the emission-line objects show morphologies suggestive of mergers or interactions. The reduced data are available upon request from the authors.Comment: 58 preprint pages, including 26 figures; accepted for publication in ApJ

A hydrodynamic study of the circumstellar envelope of alpha Scorpii

Context: Both the absolute mass-loss rates and the mechanisms that drive the mass loss of late-type supergiants are still not well known. Binaries such as alpha Sco provide the most detailed empirical information about the winds of these stars. Aims: The goal was to improve the binary technique for the determination of the mass-loss rate of alpha Sco A by including a realistic density distribution and velocity field from hydrodynamic and plasma simulations. Methods: We performed 3D hydrodynamic simulations of the circumstellar envelope of alpha Sco in combination with plasma simulations accounting for the heating, ionization, and excitation of the wind by the radiation of alpha Sco B. These simulations served as the basis for an examination of circumstellar absorption lines in the spectrum of alpha Sco B as well as of emission lines from the Antares nebula. Results: The present model of the extended envelope of alpha Sco reproduces some of the structures that were observed in the circumstellar absorption lines in the spectrum of alpha Sco B. Our theoretical density and velocity distributions of the outflow deviate considerably from a spherically expanding model, which was used in previous studies. This results in a higher mass-loss rate of (2 +/- 0.5) x 10^-6 M_sun/yr. The hot H II region around the secondary star induces an additional acceleration of the wind at large distances from the primary, which is seen in absorption lines of Ti II and Cr II at -30 km/s.Comment: 12 pages, 14 figures, accepted for publication in A&

The Heavy Element Enrichment of Lyman alpha Clouds in the Virgo Supercluster

Using high S/N STIS echelle spectra (FWHM=7 km/s) of 3C 273, we constrain the metallicities of two Lya clouds in the vicinity of the Virgo cluster. We detect C II, Si II, and Si III absorption lines in the Lya absorber at z = 0.00530. Previous observations with FUSE have revealed Ly beta - Ly theta lines at this redshift, thereby accurately constraining N(H I). We model the ionization of the gas and derive [C/H] = -1.2^{+0.3}_{-0.2}, [Si/C] = 0.2+/-0.1, and log n_{H} = -2.8+/-0.3. The model implies a small absorber thickness, ~70 pc, and thermal pressure p/k ~ 40 cm^{-3} K. It is most likely that the absorber is pressure confined by an external medium because gravitational confinement would require a very high ratio of dark matter to baryonic matter. Based on Milky Way sight lines in which carbon and silicon abundances have been reliably measured in the same interstellar cloud (including new measurements presented herein), we argue that the overabundance of Si relative to C is not due to dust depletion. Instead, this probably indicates that the gas has been predominately enriched by Type II supernovae. Such enrichment is most plausibly provided by an unbound galactic wind, given the absence of galaxies within a projected distance of 100 kpc and the presence of galaxies capable of driving a wind at larger distances. We also constrain the metallicity and physical conditions of the Virgo absorber at z = 0.00337 based on detections of O VI and H I and an upper limit on C IV. If this absorber is collisionally ionized, the O VI/C IV limit requires T > 10^{5.3} K. For either collisional ionization or photoionization, we find that [O/H] > -2.0 at z = 0.00337.Comment: Final Ap.J. versio

What happens if you single out? An experiment

We present an experiment investigating the effects of singling out an individual on trust and trustworthiness. We find that (a) trustworthiness falls if there is a singled out subject; (b) non-singled out subjects discriminate against the singled out subject when they are not responsible of the distinct status of this person; (c) under a negative frame, the singled out subject returns significantly less; (d) under a positive frame, the singled out subject behaves bimodally, either selecting very low or very high return rates. Overall, singling out induces a negligible effect on trust but is potentially disruptive for trustworthiness

Paraphrases and summaries: A means of clarification or a vehicle for articulating a preferred version of student accounts?

The use of group discussions as a means to facilitate learning from experiences is well documented in adventure education literature. Priest and Naismith (1993) assert that the use of the circular discussion method, where the leader poses questions to the participants, is the most common form of facilitation in adventure education. This paper draws on transcripts of facilitation sessions to argue that the widely advocated practice of leader summaries or paraphrases of student responses in these sessions functions as a potential mechanism to control and sponsor particular knowledge(s). Using transcripts from recorded facilitation sessions the analysis focuses on how the leader paraphrases the students’ responses and how these paraphrases or ‘formulations’ function to modify or exclude particular aspects of the students’ responses. I assert that paraphrasing is not simply a neutral activity that merely functions to clarify a student response, it is a subtle means by which the leader of the session can, often inadvertently or unknowingly, alter the student’s reply with the consequence of favouring particular knowledge(s). Revealing the subtle work that leader paraphrases perform is of importance for educators who claim to provide genuine opportunities for students to learn from their experience

Orbital characterization of the \beta Pictoris b giant planet

In June 2010, we confirmed the existence of a giant planet in the disk of the young star Beta Pictoris, located between 8 AU and 15 AU from the star. This young planet offers the rare opportunity to monitor a large fraction of the orbit using the imaging technique over a reasonably short timescale. Using the NAOS-CONICA adaptive-optics instrument (NACO) at the Very Large Telescope (VLT), we obtained repeated follow-up images of the Bpic system in the Ks and L' filters at four new epochs in 2010 and 2011. Complementing these data with previous measurements, we conduct a homogeneous analysis, which covers more than eight yrs, to accurately monitor the Bpic b position relative to the star. On the basis of the evolution of the planet's relative position with time, we derive the best-fit orbital solutions for our measurements. More reliable results are found with a Markov-chain Monte Carlo approach. The solutions favor a low-eccentricity orbit e < 0.17, with semi-major axis in the range 8--9 AU corresponding to orbital periods of 17--21 yrs. Our solutions favor a highly inclined solution with a peak around i=88.5+-1.7 deg, and a longitude of ascending node tightly constrained at Omega = -147.5+-1.5 deg. These results indicate that the orbital plane of the planet is likely to be above the midplane of the main disk, and compatible with the warp component of the disk being tilted between 3.5 deg and 4.0 deg. This suggests that the planet plays a key role in the origin of the inner warped-disk morphology of the Bpic disk. Finally, these orbital parameters are consistent with the hypothesis that the planet is responsible for the transit-like event observed in November 1981, and also linked to the cometary activity observed in the Bpic system.Comment: 10 pages, 12 figures, accepted to A&