Physically based distributed hydrological modelling of the Upper Jordan catchment and investigation of effective model equations

International audienceSufficient freshwater availability in the water scarce environment of the Upper Jordan Catchment (UJC) is a central prerequisite for peaceful agricultural and industrial development. Hydrological modelling is required to understand terrestrial water balance and to provide scientifically sound estimates on water availability. This article aims at two related objectives: First the water balance of the UJC, a hydrogeologically complex catchment located at the borders of Israel, Syria and the Lebanon, is investigated. It is for the first time that a physically based model is set up for this region that accounts both for the entire terrestrial water balance and in particular for the groundwater-surface water interaction. It is shown that the model is able to describe observed river discharges satisfactorily. Secondly, it is investigated if observed and simulated runoff components can be explained by simple lumped approaches based on 1) linear filter theory and 2) neural networks and what the number of degrees of freedom for the runoff components is. It is exemplary shown for the Ayun subcatchment of the UJC that the simulated river discharge, the direct runoff component and the interflow runoff component as modelled by the physically based distributed hydrological model WaSiM can be described by simple effective equations with only 3 to 5 degrees of freedom. Application of simple lumped approaches to observed river discharge values showed much weaker performance

Rigid Chiral Membranes

Statistical ensembles of flexible two-dimensional fluid membranes arise naturally in the description of many physical systems. Typically one encounters such systems in a regime of low tension but high stiffness against bending, which is just the opposite of the regime described by the Polyakov string. We study a class of couplings between membrane shape and in-plane order which break 3-space parity invariance. Remarkably there is only {\it one} such allowed coupling (up to boundary terms); this term will be present for any lipid bilayer composed of tilted chiral molecules. We calculate the renormalization-group behavior of this relevant coupling in a simplified model and show how thermal fluctuations effectively reduce it in the infrared.Comment: 11 pages, UPR-518T (This replaced version has fonts not used removed.

Direct frequency comb measurement of OD + CO → DOCO kinetics

The kinetics of the hydroxyl radical (OH) + carbon monoxide (CO) reaction, which is fundamental to both atmospheric and combustion chemistry, are complex because of the formation of the hydrocarboxyl radical (HOCO) intermediate. Despite extensive studies of this reaction, HOCO has not been observed under thermal reaction conditions. Exploiting the sensitive, broadband, and high-resolution capabilities of time-resolved cavity-enhanced direct frequency comb spectroscopy, we observed deuteroxyl radical (OD) + CO reaction kinetics and detected stabilized trans-DOCO, the deuterated analog of trans-HOCO. By simultaneously measuring the time-dependent concentrations of the trans-DOCO and OD species, we observed unambiguous low-pressure termolecular dependence of the reaction rate coefficients for N_2 and CO bath gases. These results confirm the HOCO formation mechanism and quantify its yield