Contribution of riverine nutrients to the silicon biogeochemistry of the global ocean – a model study

Continental shelf seas are known to support a large fraction of the global primary production. Yet, they are mostly ignored or neglected in global biogeochemical models. A number of processes that control the transfer of dissolved nutrients from rivers to the open ocean remain poorly understood. This applies in particular to dissolved silica which drives the growth of diatoms that form a large part of the phytoplankton biomass and are thus an important contributor to export production of carbon. <br><br> Here, the representation of the biogeochemical cycling along continents is improved by coupling a high resolution database of riverine fluxes of nutrients to the global biogeochemical ocean general circulation model HAMOCC5-OM. Focusing on silicon (Si), but including the whole suite of nutrients – carbon (C), nitrogen (N) and phosphorus (P) in various forms – inputs are implemented in the model at coastal coupling points using the COSCAT global database of 156 mega-river-ensemble catchments from Meybeck et al. (2006). The catchments connect to the ocean through coastal segments according to three sets of criteria: natural limits, continental shelf topography, and geophysical dynamics. <br><br> According to the model the largest effects on nutrient concentrations occur in hot spots such as the Amazon plume, the Arctic – with high nutrient inputs in relation to its total volume, and areas that encounter the largest increase in human activity, e.g., Southern Asia

Enhancements in nocturnal surface ozone at urban sites in the UK

Analysis of diurnal patterns of surface ozone (O3) at multiple urban sites in the UK shows the occurrence of prominent nocturnal enhancements during the winter months (November–March). Whilst nocturnal surface ozone (NSO) enhancement events have been observed at other locations, this is the first time that such features have been demonstrated to occur in the UK and the second location globally. The observed NSO enhancement events in the UK were found to be so prevalent that they are clearly discernible in monthly diurnal cycles averaged over several years of data. Long-term (2000–2010) analysis of hourly surface ozone data from 18 urban background stations shows a bimodal diurnal variation during the winter months with a secondary nighttime peak around 0300 hours along with the primary daytime peak. For all but one site, the daily maxima NSO concentrations during the winter months exceeded 60 μg/m3 on >20 % of the nights. The highest NSO value recorded was 118 μg/m3. During the months of November, December, and January, the monthly averaged O3 concentrations observed at night (0300 h) even exceeded those observed in the daytime (1300 h). The analysis also shows that these NSO enhancements can last for several hours and were regional in scale, extending across several stations simultaneously. Interestingly, the urban sites in the north of the UK exhibited higher NSO than the sites in the south of the UK, despite their daily maxima being similar. In part, this seems to be related to the sites in the north typically having lower concentrations of nitrogen oxides

Climate and carbon-cycle variability over the last millennium

A long-standing task in climate research has been to distinguish between anthropogenic climate change and natural climate variability. A prerequisite for fulfilling this task is the understanding of the relative roles of external drivers and internal variability of climate and the carbon cycle. Here, we present the first ensemble simulations over the last 1200 years with a comprehensive Earth system model including a fully interactive carbon cycle. Applying up-to-date reconstructions of external forcing including the recent low-amplitude estimates of solar variations, the ensemble simulations reproduce temperature evolutions consistent with the range of reconstructions. The 20th-century warming trend stands out against all pre-industrial trends within the ensemble. Volcanic eruptions are necessary to explain variations in pre-industrial climate such as the Little Ice Age; yet only the strongest, repeated eruptions lead to cooling trends that differ significantly from the internal variability across all ensemble members. The simulated atmospheric CO<sub>2</sub> concentrations exhibit a stable carbon cycle over the pre-industrial era with multi-centennial variations somewhat smaller than in the observational records. Early land-cover changes have modulated atmospheric CO<sub>2</sub> concentrations only slightly. We provide a model-based quantification of the sensitivity (termed γ) of the global carbon cycle to temperature for a variety of climate and forcing conditions. We diagnose a distinct dependence of γ on the forcing strength and time-scales involved, thus providing a possible explanation for the systematic difference in the observational estimates for different segments of the last millennium

Global carbon budget 2013

Accurate assessment of anthropogenic carbon dioxide (CO2) emissions and their redistribution among the atmosphere, ocean, and terrestrial biosphere is important to better understand the global carbon cycle, support the development of climate policies, and project future climate change. Here we describe data sets and a methodology to quantify all major components of the global carbon budget, including their uncertainties, based on the combination of a range of data, algorithms, statistics and model estimates and their interpretation by a broad scientific community. We discuss changes compared to previous estimates, consistency within and among components, alongside methodology and data limitations. CO2 emissions from fossil-fuel combustion and cement production (EFF) are based on energy statistics, while emissions from land-use change (ELUC), mainly deforestation, are based on combined evidence from land-cover change data, fire activity associated with deforestation, and models. The global atmospheric CO2 concentration is measured directly and its rate of growth (GATM) is computed from the annual changes in concentration. The mean ocean CO2 sink (SOCEAN) is based on observations from the 1990s, while the annual anomalies and trends are estimated with ocean models. The variability in SOCEAN is evaluated for the first time in this budget with data products based on surveys of ocean CO2 measurements. The global residual terrestrial CO2 sink (SLAND) is estimated by the difference of the other terms of the global carbon budget and compared to results of independent dynamic global vegetation models forced by observed climate, CO2 and land cover change (some including nitrogen–carbon interactions). All uncertainties are reported as ±1σ, reflecting the current capacity to characterise the annual estimates of each component of the global carbon budget. For the last decade available (2003–2012), EFF was 8.6 ± 0.4 GtC yr−1, ELUC 0.9 ± 0.5 GtC yr−1, GATM 4.3 ± 0.1 GtC yr−1, SOCEAN 2.5 ± 0.5 GtC yr−1, and SLAND 2.8 ± 0.8 GtC yr−1. For year 2012 alone, EFF grew to 9.7 ± 0.5 GtC yr−1, 2.2% above 2011, reflecting a continued growing trend in these emissions, GATM was 5.1 ± 0.2 GtC yr−1, SOCEAN was 2.9 ± 0.5 GtC yr−1, and assuming an ELUC of 1.0 ± 0.5 GtC yr−1 (based on the 2001–2010 average), SLAND was 2.7 ± 0.9 GtC yr−1. GATM was high in 2012 compared to the 2003–2012 average, almost entirely reflecting the high EFF. The global atmospheric CO2 concentration reached 392.52 ± 0.10 ppm averaged over 2012. We estimate that EFF will increase by 2.1% (1.1–3.1%) to 9.9 ± 0.5 GtC in 2013, 61% above emissions in 1990, based on projections of world gross domestic product and recent changes in the carbon intensity of the economy. With this projection, cumulative emissions of CO2 will reach about 535 ± 55 GtC for 1870–2013, about 70% from EFF (390 ± 20 GtC) and 30% from ELUC (145 ± 50 GtC). This paper also documents any changes in the methods and data sets used in this new carbon budget from previous budgets (Le Quéré et al., 2013). All observations presented here can be downloaded from the Carbon Dioxide Information Analysis Center (doi:10.3334/CDIAC/GCP_2013_V2.3)

Untersuchungen zur Aufnahme und zum Einbau von anthropogenen Stickoxiden (NOx_{x}) durch Sonnenblumen und Mais mittels 15^{15}N-Isotopen-Markierung

Trace gases such as carbon dioxide (CO$_{2}$), sulphur dioxide (SO$_{2}$) and the nitrogen oxides (NO$_{x}$) formed during the combustion of fossil energy carriers (oil; coal; gas) alter the composition of the atmosphere. In the Federal Republic of Germany, the emitted quantity of nitrogen oxides (NO$_{x}$ = NO + NO$_{2}$) was approx. 3 million t in 1986 (UBA, 1990). In contrast to other atmospheric pollutants, despite the introduction of corresponding methods it has not yet been possible to determine any significant reduction in the emissions of nitrogen oxides. The reason for this is mainly to be found in the overproportional increase of traffic, particularly in the diesel vehicle sector. After atmospheric transport, some of the emitted nitrogen oxides reach the biosphere via dry deposition. As part of the biosphere, plants are able to take up nitrogen oxides and incorporate the NO$_{x}$ nitrogen into their biomass (HILL, 1971; ROGERS et al., 1979). The extent to which the nitrogen oxides in the range of concentrations currently present in the atmosphere (up to 80 ppb) can be used by the plants as an additional nitrogen source or whether they should be regarded as pollutants due to the change in corresponding nutrient equilibria is still largely unclear (WELLBURN, 1990). In order to make a contribution towards clarifying this problem, an interdisciplinary project has been carried out at the Research Centre Jülich (KFA) since 1986 involving theInstitute of Chemistry of the Geosphere (ICG 2), the Institute of Biotechnology (IBT 3) and the Institute of Radioagronomy (IRA). Within this cooperation, the aim of the present thesis was to quantify the uptake of nitrogen dioxide (NO$_{2}$) and nitrogen monoxide (NO) by sunflowers (Helianthus annuus L.) and maize (Zea mays L.) in a concentration range corresponding to the concentration range in the present atmosphere. Furthermore, work was carried out on characterizing the parameters responsible for NO$_{2}$ and NO uptake by varying the different exposure conditions. In addition by applying $^{15}$N-enriched nitrogen oxides ($^{15}NO_{2}; ^{15}NO$) it was also possible to investigate the incorporation and distribution of the $^{15}$NO$_{x}$ nitrogen in the plants. After an appropriate cultivation phase, the plants were transferred individually into a specially designed exposure system (Latus, 1989). Quantification of the NO$_{2}$ or NO uptake was carried out by two independent measuring methods. On the one hand, the quantities of NO$_{2}$ or NO taken up by the plants were determined via the NO$_{2}$ concentration difference [...

Response of the intermediate complexity Mars Climate Simulator to different obliquity angles

A climate model of intermediate complexity, named the Mars Climate Simulator, has been developed based on the Portable University Model of the Atmosphere (PUMA). The main goal of this new development is to simulate the climate variations on Mars resulting from the changes in orbital parameters and their impact on the layered polar terrains (also known as permanent polar ice caps). As a first step towards transient simulations over several obliquity cycles, the model is applied to simulate the dynamical and thermodynamical response of the Martian climate system to different but fixed obliquity angles. The model is forced by the annual and daily cycle of solar insolation. Experiments have been performed for obliquities of φ=15°(minimum), φ=25.2°(present), and φ=35°(maximum). The resulting changes in solar insolation mainly in the polar regions impact strongly on the cross-equatorial circulation which is driven by the meridional temperature gradient and steered by the Martian topography. At high obliquity, the cross-equatorial near surface flow from the winter to the summer hemisphere is strongly enhanced compared to low obliquity periods. The summer ground temperature ranges from 200 K (φ=15°) to 250 K (φ=35°) at 80°N in northern summer, and from 220 K (φ=15°) to 270 K (φ=35°) at 80°S in southern summer. In the atmosphere at 1 km above ground, the respective range is 195–225 K in northern summer, and 210–250 K in southern summer