Quality improvement of biodiesel blends using different promising fuel additives to reduce fuel consumption and NO emission from CI engine

Considering the low cetane number of biodiesel blends and alcohols, ignition promoter additives 2-ethylhexyl nitrate (EHN) and di-tertiary-butyl peroxide (DTBP) was used in this study at a proportion of 1000 and 2000 ppm to diesel-biodiesel-pentanol blends. Five carbon pentanol was used at a proportion of 10% with 20% jatropha biodiesel-70% diesel blends and engine testing was carried out in a single cylinder DI diesel engine. The fuel properties, engine performance, emission and combustion were studied and mainly the effects of two most widely used ignition promoter on the engine behaviour were compared and analyzed. Experimental results indicated that, the fuel properties like density (0.36–1.45%), viscosity (0.26–3.77%), oxidation stability (5.5–26.4%), cetane number (2–14.58%) are improved remarkably with a moderate change in calorific value for the pentanol and ignition promoter treated biodiesel blends depending on the proportion used and for different benchmark. The brake power (BP) is developed very slightly (0.66–1.52%), which is still below than that of diesel, however, the brake specific energy consumption (BSEC) decreased significantly (0.92–5.84%). Although mixing of pentanol increased the nitric oxide (NO) (2.15% than JB20) with reducing the hydrocarbon (HC), carbon monoxide (CO) and smoke, however, the addition of EHN and DTBP reduced the NO (2–4.62%) and smoke (3.45–15.5%) emissions showing higher CO (1.3–9.15%) and HC (5.1–17.87%) emission based on percentage of ignition promoter used. The NO emission from the peroxide ignition promoter treated fuel blends are consistently lower than those for the nitrate ignition promoter treated fuel blends at similar cetane level. The combustion pressure (CP) and heat release rate (HRR) of the ignition promoters added blends are improved showing advanced combustion pressure (0.11–0.53 bar) and lower heat release rate (0.82–2.29 J/°CA). In conclusion, it can be said that, pentanol and ignition promoters are promising additives for biodiesel blends for improving overall performance of a diesel engine

Attempts to minimize nitrogen oxide emission from diesel engine by using antioxidant-treated diesel-biodiesel blend.

The study represents a comprehensive analysis of engine exhaust emission variation from a compression ignition (CI) diesel engine fueled with diesel-biodiesel blends. Biodiesel used in this investigation was produced through transesterification procedure from Moringa oleifera oil. A single cylinder, four-stroke, water-cooled, naturally aspirated diesel engine was used for this purpose. The pollutants from the exhaust of the engine that are monitored in this study are nitrogen oxide (NO), carbon monoxide (CO), hydrocarbon (HC), and smoke opacity. Engine combustion and performance parameters are also measured together with exhaust emission data. Some researchers have reported that the reason for higher NO emission of biodiesel is higher prompt NO formation. The use of antioxidant-treated biodiesel in a diesel engine is a promising approach because antioxidants reduce the formation of free radicals, which are responsible for the formation of prompt NO during combustion. Two different antioxidant additives namely 2,6-di-tert-butyl-4-methylphenol (BHT) and 2,2'-methylenebis(4-methyl-6-tert-butylphenol) (MBEBP) were individually dissolved at a concentration of 1% by volume in MB30 (30% moringa biodiesel with 70% diesel) fuel blend to investigate and compare NO as well as other emissions. The result shows that both antioxidants reduced NO emission significantly; however, HC, CO, and smoke were found slightly higher compared to pure biodiesel blends, but not more than the baseline fuel diesel. The result also shows that both antioxidants were quite effective in reducing peak heat release rate (HRR) and brake-specific fuel consumption (BSFC) as well as improving brake thermal efficiency (BTE) and oxidation stability. Based on this study, antioxidant-treated M. oleifera biodiesel blend (MB30) can be used as a very promising alternative source of fuel in diesel engine without any modifications

Study of the oxidation stability and exhaust emission analysis of Moringa olifera biodiesel in a multi-cylinder diesel engine with aromatic amine antioxidants

In this study, the two most effective aromatic amine antioxidants N,N'-diphenyl-1,4-phenylenediamine (DPPD) and N-phenyl-1,4-phenylenediamine (NPPD), were used at a concentration of 2000 ppm. The impact of antioxidants on the oxidation stability, exhaust emission and engine performance of a multi-cylinder diesel engine fuelled with MB20 (20% Moringa oil methyl ester and 80% diesel fuel blend) were analysed at varying speed conditions at an interval of 500 rpm and a constant load. It was observed that, blending with diesel enhanced the oxidation stability of the moringa biodiesel by approximately 6.97 h, and the addition of DPPD and NPPD to MB20 increased the oxidation stability up to 34.5 and 18.4 h, respectively. The results also showed that the DPPD- and NPPD-treated blends reduced the NOx emission by 7.4% and 3.04%, respectively, compared to the untreated blend. However, they do have higher carbon monoxide (CO) and hydrocarbon (HC) levels and smoke opacities, but it should be noted that these emissions are still well below the diesel fuel emission level. The results show that the addition of antioxidant with MB20 also improves the engine's performance characteristics. Based on this study, MB20 blends with amine antioxidants can be used in diesel engines without any modification

Study of the oxidation stability and exhaust emission analysis of Moringa olifera biodiesel in a multi-cylinder diesel engine with aromatic amine antioxidants

In this study, the two most effective aromatic amine antioxidants N,N'-diphenyl-1,4-phenylenediamine (DPPD) and N-phenyl-1,4-phenylenediamine (NPPD), were used at a concentration of 2000 ppm. The impact of antioxidants on the oxidation stability, exhaust emission and engine performance of a multi-cylinder diesel engine fuelled with MB20 (20% Moringa oil methyl ester and 80% diesel fuel blend) were analysed at varying speed conditions at an interval of 500 rpm and a constant load. It was observed that, blending with diesel enhanced the oxidation stability of the moringa biodiesel by approximately 6.97 h, and the addition of DPPD and NPPD to MB20 increased the oxidation stability up to 34.5 and 18.4 h, respectively. The results also showed that the DPPD- and NPPD-treated blends reduced the NOx emission by 7.4% and 3.04%, respectively, compared to the untreated blend. However, they do have higher carbon monoxide (CO) and hydrocarbon (HC) levels and smoke opacities, but it should be noted that these emissions are still well below the diesel fuel emission level. The results show that the addition of antioxidant with MB20 also improves the engine's performance characteristics. Based on this study, MB20 blends with amine antioxidants can be used in diesel engines without any modification

Gaseous and particle emissions from a compression ignition engine fueled with biodiesel–Diesel blends

© Springer Nature Singapore Pte Ltd. 2018. This chapter investigates the sustainability of rice bran biodiesel from environmental point of view. In this study, 5 and 20% biodiesel was tested in a naturally aspirated four-stroke multi-cylinder diesel engine at different load and speed conditions. It was found that all biodiesel blended fuel reduces the brake power (BP) and increases brake specific fuel consumption (BSFC) slightly than diesel fuel. Engine emission results indicated that blended fuel reduces the average particulate matter (PM), carbon monoxide (CO), and hydrocarbons (HC) except nitric oxides (NO) emissions than diesel fuel. Finally, it can be concluded that up to 20% rice bran biodiesel could replace diesel fuel to help in controlling the air pollution to a great extent without sacrificing engine power significantly

A comprehensive study on the improvement of oxidation stability and NO<inf>x</inf> emission levels by antioxidant addition to biodiesel blends in a light-duty diesel engine

Moringa oleifera oil, a non-edible biodiesel feedstock with high unsaturated fatty acid content, was used in this study. MB20 (20% Moringa oil methyl ester and 80% diesel fuel blend) was mixed with three antioxidants, namely, N,N′-diphenyl-1,4-phenylenediamine (DPPD), N-phenyl-1,4-phenylenediamine (NPPD) and 2-ethylhexyl nitrate (EHN), at a concentration of 1000 ppm. The effects of these antioxidants on the oxidation stability of biodiesel as well as on the exhaust emission and performance of a single-cylinder diesel engine were analysed. After the Rancimat test, oxidation stability was enhanced by the antioxidants in the order of DPPD > NPPD > EHN. Results also showed that DPPD-, NPPD- and EHN-treated blends reduced NOx emissions within 5.9-8.80% compared with those in the untreated blend because of suppressed free radical formation. Antioxidant-treated blends contained high amounts of carbon monoxide and hydrocarbon and showed improved smoke opacity, thereby indicating that emissions were below the diesel fuel emission levels. Results demonstrated that antioxidant addition to MB20 improves engine performance characteristics. This study shows that MB20 blends with antioxidants can be used in diesel engines without any modification

Experimental assessment of non-edible candlenut biodiesel and its blend characteristics as diesel engine fuel.

Exploring new renewable energy sources as a substitute of petroleum reserves is necessary due to fulfilling the oncoming energy needs for industry and transportation systems. In this quest, a lot of research is going on to expose different kinds of new biodiesel sources. The non-edible oil from candlenut possesses the potential as a feedstock for biodiesel production. The present study aims to produce biodiesel from crude candlenut oil by using two-step transesterification process, and 10%, 20%, and 30% of biodiesel were mixed with diesel fuel as test blends for engine testing. Fourier transform infrared (FTIR) and gas chromatography (GC) were performed and analyzed to characterize the biodiesel. Also, the fuel properties of biodiesel and its blends were measured and compared with the specified standards. The thermal stability of the fuel blends was measured by thermogravimetric analysis (TGA) and differential scan calorimetry (DSC) analysis. Engine characteristics were measured in a Yanmar TF120M single cylinder direct injection (DI) diesel engine. Biodiesel produced from candlenut oil contained 15% free fatty acid (FFA), and two-step esterification and transesterification were used. FTIR and GC remarked the biodiesels' existing functional groups and fatty acid methyl ester (FAME) composition. The thermal analysis of the biodiesel blends certified about the blends' stability regarding thermal degradation, melting and crystallization temperature, oxidative temperature, and storage stability. The brake power (BP), brake specific fuel consumption (BSFC), and brake thermal efficiency (BTE) of the biodiesel blends decreased slightly with an increasing pattern of nitric oxide (NO) emission. However, the hydrocarbon (HC) and carbon monoxides (CO) of biodiesel blends were found decreased

Effect of antioxidant on the oxidation stability and combustion-performance-emission characteristics of a diesel engine fueled with diesel-biodiesel blend

Alexandrian laurel or Calophyllum inophyllum oil is recently considered one of the most anticipated nonconsumable or nonedible biodiesel sources. An attempt has been made in this study to increase the oxidation stability and investigate the engine performance, emission, and combustion characteristics of a diesel engine by adding 1% (by vol.) of two antioxidants, such as 2,6-Di-tert.-butyl-4-methylphenol and 2,2′-methylenebis (4-methyl-6-tert-butylphenol), in higher percentages of C. inophyllum biodiesel (CB30) with diesel fuel (B0). The experiment was performed on a single-cylinder, water-cooled, direct-injection diesel engine for this purpose. The addition of both antioxidants increased the oxidation stability without significantly changing other physicochemical properties. Results also show that the antioxidants enhanced the start of combustion of biodiesel, which resulted in a short ignition delay. The peak pressure and the peak heat release rate during premixed combustion phase of pure CB30 and its modified blend with antioxidant were higher than those of B0. Both antioxidant blends showed higher brake power, higher brake thermal efficiency, and lower brake specific fuel consumption than pure CB30. Both antioxidants significantly reduced NOX emission; however, CO, HC, and smoke opacity were slightly higher than those of CB30. Based on this study, Alexandrian laurel or C. inophyllum biodiesel blend (CB30) with antioxidant can be used as an alternative fuel in a diesel engine without modifications

Gaseous and particle emissions from a compression ignition engine fueled with biodiesel–diesel blends

This chapter investigates the sustainability of rice bran biodiesel from environmental point of view. In this study, 5 and 20% biodiesel was tested in a naturally aspirated four-stroke multi-cylinder diesel engine at different load and speed conditions. It was found that all biodiesel blended fuel reduces the brake power (BP) and increases brake specific fuel consumption (BSFC) slightly than diesel fuel. Engine emission results indicated that blended fuel reduces the average particulate matter (PM), carbon monoxide (CO), and hydrocarbons (HC) except nitric oxides (NO) emissions than diesel fuel. Finally, it can be concluded that up to 20% rice bran biodiesel could replace diesel fuel to help in controlling the air pollution to a great extent without sacrificing engine power significantly. © Springer Nature Singapore Pte Ltd. 2018