Operando STM study of the interaction of imidazolium-based ionic liquid with graphite

Understanding interactions at the interfaces of carbon with ionic liquids (ILs) is crucially beneficial for the diagnostics and performance improvement of electrochemical devices containing carbon as active materials or conductive additives in electrodes and ILs as solvents or additives in electrolytes. The interfacial interactions of three typical imidazolium-based ILs, 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (AMImTFSI) ILs having ethyl (C2), butyl (C4) and octyl (C8) chains in their cations, with highly oriented pyrolytic graphite (HOPG) were studied in-situ by electrochemical scanning tunneling microscopy (EC-STM). The etching of HOPG surface and the exfoliation of graphite/graphene flakes as well as cation intercalation were observed at the HOPG/C2MImTFSI interface. The etching also takes place in C4MImTFSI at −1.5 V vs Pt but only at step edges with a much slower rate, whereas C8MIm+ cations adsorbs strongly on the HOPG surface under similar conditions with no observable etching or intercalation. The EC-STM observations can be explained by the increase in van der Waals interaction between the cations and the graphite surface with increasing length of alkyl chains

Non-invasive acquisition of fetal ECG from the maternal xyphoid process: a feasibility study in pregnant sheep and a call for open data sets

Objective: The utility of fetal heart rate (FHR) monitoring can only be achieved with an acquisition sampling rate that preserves the underlying physiological information on the millisecond time scale (1000 Hz rather than 4 Hz). For such acquisition, fetal ECG (fECG) is required, rather than the ultrasound to derive FHR. We tested one recently developed algorithm, SAVER, and two widely applied algorithms to extract fECG from a single channel maternal ECG signal recorded over the xyphoid process rather than the routine abdominal signal. Approach: At 126dG, ECG was attached to near-term ewe and fetal shoulders, manubrium and xyphoid processes (n=12). FECG served as the ground-truth to which the fetal ECG signal extracted from the simultaneously-acquired maternal ECG was compared. All fetuses were in good health during surgery (pH 7.29+/-0.03, pO2 33.2+/-8.4, pCO2 56.0+/-7.8, O2Sat 78.3+/-7.6, lactate 2.8+/-0.6, BE -0.3+/-2.4). Main result: In all animals, single lead fECG extraction algorithm could not extract fECG from the maternal ECG signal over the xyphoid process with the F1 less than 50%. Significance: The applied fECG extraction algorithms might be unsuitable for the maternal ECG signal over the xyphoid process, or the latter does not contain strong enough fECG signal, although the lead is near the mother's abdomen. Fetal sheep model is widely used to mimic various fetal conditions, yet ECG recordings in a public data set form are not available to test the predictive ability of fECG and FHR. We are making this data set openly available to other researchers to foster non-invasive fECG acquisition in this animal model

Optical layer monitoring schemes for fast link failure localization in all-optical networks

Optical layer monitoring and fault localization serves as a critical functional module in the control and management of optical networks. An efficient monitoring scheme aims at minimizing not only the hardware cost required for 100{%} link failure localization, but also the number of redundant alarms and monitors such that the network fault management can be simplified as well. In recent years, several optical layer monitoring schemes were reported for fast and efficient link failure localization, including simple, non-simple monitoring cycle (m-cycle) and monitoring trail (m-trail). Optimal ILP (Integer Linear Program) models and heuristics were also proposed with smart design philosophy on flexibly trading off different objectives. This article summarizes those innovative ideas and methodologies with in-depth analysis on their pros and cons. We also provide insights on future research topics in this area, as well as possible ways for extending the new failure localization approaches to other network applications. © 2005 IEEE.published_or_final_versio

CFP: Cooperative fast protection

Article number: 5062196The 28th Conference on Computer Communications, IEEE INFOCOM 2009, Miniconference, Rio de Janeiro, Brazil, 19-25 April 2009We introduce Cooperative Fast Protection (CFP) as a novel protection scheme in WDM networks. CFP achieves capacity-efficient fast protection with the features of node-autonomy and failure-independency. It differs from p-cycle by reusing the released working capacity of the disrupted lightpaths (i.e. stubs) in a cooperative manner. This is achieved by allowing all the failure-aware nodes to switch the traffic, such that the disrupted lightpaths can be protected even if the end nodes of the failed link are not on the protecting cycles. CFP also differs from FIPP p-cycle by not requiring the source node of the disrupted lightpath on the protecting cycle. By jointly optimizing both working and spare capacity placement, we formulate an ILP for CFP design. Numerical results show that CFP significantly outperforms p-cycle by achieving faster protection with much higher capacity efficiency. © 2009 IEEE.published_or_final_versio

Artificial interspecific hybridization between Macrobrachium species

Viable F-1 hybrids were obtained from crosses of female Macrobrachium nipponense and male Macrobrachium hainanense involving spermatophore transfer and artificial insemination. This represents the first successful known case of hybridization of two Macrobrachium species by means of artificial insemination. The hatching rate was over 90%. About 20-60% of newly hatched larvae metamorphosed to postlarvae. The morphological characteristics of the hybrids resembled a combination of features of both parents. Malate dehydrogenase (MDH) and esterase (EST) isozyme electrophoresis indicated parents and F-1 hybrids showed co-dominant expression of the paternal and maternal alleles controlling the isozymes and confirmed the hybridization. (C) 2004 Elsevier B.V. All rights reserved.Viable F-1 hybrids were obtained from crosses of female Macrobrachium nipponense and male Macrobrachium hainanense involving spermatophore transfer and artificial insemination. This represents the first successful known case of hybridization of two Macrobrachium species by means of artificial insemination. The hatching rate was over 90%. About 20-60% of newly hatched larvae metamorphosed to postlarvae. The morphological characteristics of the hybrids resembled a combination of features of both parents. Malate dehydrogenase (MDH) and esterase (EST) isozyme electrophoresis indicated parents and F-1 hybrids showed co-dominant expression of the paternal and maternal alleles controlling the isozymes and confirmed the hybridization. (C) 2004 Elsevier B.V. All rights reserved

The enhancement of TiO?photocatalytic activity by hydrogen thermal treatment

Author name used in this publication: H. LiuAuthor name used in this publication: X. Z. Li2002-2003 > Academic research: refereed > Publication in refereed journalAccepted ManuscriptPublishe

Excitation Spectra And Hard-core Thermodynamics Of Bosonic Atoms In Optical Superlattices

A generalized double-well-basis coupled representation is proposed to investigate excitation spectra and thermodynamics of bosonic atoms in double-well optical superlattices. In the hard-core limit and with a filling factor of one, excitations describing the creation of pairs of a doubly occupied state and a simultaneous empty state, and those from a symmetric singly occupied state to an antisymmetric state are carefully analyzed and their excitation spectra are calculated within mean-field theory. Based on the hard-core statistics, the equilibrium properties such as heat capacity and particle populations are studied in detail. The cases with other filling factors are also briefly discussed.published_or_final_versio

School health partnership in service learning : a Hong Kong experience

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Plant Homeo Domain Finger Protein 8 Regulates Mesodermal and Cardiac Differentiation of Embryonic Stem Cells Through Mediating the Histone Demethylation of pmaip1

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Evolution of superconductivity in K2-xFe4+ySe5: Spectroscopic studies of X-ray absorption and emission.

This study investigates the evolution of superconductivity in K2-xFe4+ySe5 using temperature-dependent X-ray absorption and resonant inelastic X-ray scattering techniques. Magnetization measurements show that polycrystalline superconducting (SC) K1.9Fe4.2Se5 has a critical temperature (T c) of ∼31 K with a varying superconducting volume fraction, which strongly depends on its synthesis temperature. An increase in Fe-structural/vacancy disorder in SC samples with more Fe atoms occupying vacant 4d sites is found to be closely related to the decrease in the spin magnetic moment of Fe. Moreover, the nearest-neighbor Fe-Se bond length in SC samples exceeds that in the non-SC (NS) sample, K2Fe4Se5, which indicates a weaker hybridization between the Fe 3d and Se 4p states in SC samples. These results clearly demonstrate the correlations among the local electronic and atomic structures and the magnetic properties of K2-xFe4+ySe5 superconductors, providing deeper insight into the electron pairing mechanisms of superconductivity