The spectroscopic parameters of sodium cyanide, NaCN (X 1A'), revisited

The study of the rotational spectrum of NaCN (X $^1$A') has recently been extended in frequency and in quantum numbers. Difficulties have been encountered in fitting the transition frequencies within experimental uncertainties. Various trial fits traced the difficulties to the incomplete diagonalization of the Hamiltonian. Employing fewer spectroscopic parameters than before, the transition frequencies could be reproduced within experimental uncertainties on average. Predictions of $a$-type $R$-branch transitions with $K_a \le 7$ up to 570 GHz should be reliable to better than 1 MHz. In addition, modified spectroscopic parameters have been derived for the 13C isotopic species of NaCN.Comment: 5 pages, no figure, J. Mol. Spectrosc., appeared; CDMS links update

Sub-millimeter Spectroscopy of Astrophysically Important Molecules and Ions: Metal Hydrides, Halides, and Cyanides

With the advent of SOFIA, Herschel, and SAFIR, new wavelength regions will become routinely accessible for astronomical spectroscopy, particularly at submm frequencies (0.5-1.1 THz). Molecular emission dominates the spectra of dense interstellar gas at these wavelengths. Because heterodyne detectors are major instruments of these missions, accurate knowledge of transition frequencies is crucial for their success. The Ziurys spectroscopy laboratory has been focusing on the measurement of the pure rotational transitions of astrophysically important molecules in the sub-mm regime. Of particular interest have been metal hydride species and their ions, as well as metal halides and cyanides. A new avenue of study has included metal bearing molecular ions

Detection of the simplest sugar, glycolaldehyde, in a solar-type protostar with ALMA

Glycolaldehyde (HCOCH2OH) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. In this paper we present the first detection of 13 transitions of glycolaldehyde around a solar-type young star, through Atacama Large Millimeter Array (ALMA) observations of the Class 0 protostellar binary IRAS 16293-2422 at 220 GHz (6 transitions) and 690 GHz (7 transitions). The glycolaldehyde lines have their origin in warm (200-300 K) gas close to the individual components of the binary. Glycolaldehyde co-exists with its isomer, methyl formate (HCOOCH3), which is a factor 10-15 more abundant toward the two sources. The data also show a tentative detection of ethylene glycol, the reduced alcohol of glycolaldehyde. In the 690 GHz data, the seven transitions predicted to have the highest optical depths based on modeling of the 220 GHz lines all show red-shifted absorption profiles toward one of the components in the binary (IRAS16293B) indicative of infall and emission at the systemic velocity offset from this by about 0.2" (25 AU). We discuss the constraints on the chemical formation of glycolaldehyde and other organic species - in particular, in the context of laboratory experiments of photochemistry of methanol-containing ices. The relative abundances appear to be consistent with UV photochemistry of a CH3OH-CO mixed ice that has undergone mild heating. The order of magnitude increase in line density in these early ALMA data illustrate its huge potential to reveal the full chemical complexity associated with the formation of solar system analogs.Comment: Accepted for publication in ApJ Letter

Tentative detection of phosphine in IRC+10216

The J,K = 1,0-0,0 rotational transition of phosphine (PH3) at 267 GHz has been tentatively identified with a T_MB = 40 mK spectral line observed with the IRAM 30-m telescope in the C-star envelope IRC+10216. A radiative transfer model has been used to fit the observed line profile. The derived PH3 abundance relative to H2 is 6 x 10^(-9), although it may have a large uncertainty due to the lack of knowledge about the spatial distribution of this species. If our identification is correct, it implies that PH3 has a similar abundance to that reported for HCP in this source, and that these two molecules (HCP and PH3) together take up about 5 % of phosphorus in IRC+10216. The abundance of PH3, as that of other hydrides in this source, is not well explained by conventional gas phase LTE and non-LTE chemical models, and may imply formation on grain surfaces.Comment: 4 pages, 2 figures; accepted for publication in A&A Letter

Ácidos graxos poli-insaturados na regulação das concentrações séricas de triglicerídeos e ácidos graxos não esterificados em três gerações de ratos wistar.

O objetivo deste estudo foi avaliar o efeito de dietas contendo AGPIs ômega-3 e ômega-6 nas concentrações séricas de ácidos graxos não esterificados (AGNE) e triglicerídeos (TG), no período pré e pós-parto de ratas Wistar, ao longo de três gerações

On the formation of glycolaldehyde in dense molecular cores

Glycolaldehyde is a simple monosaccharide sugar linked to prebiotic chemistry. Recently, it was detected in a molecular core in the star-forming region G31.41+0.31 at a reasonably high abundance. We investigate the formation of glycolaldehyde at 10 K to determine whether it can form efficiently under typical dense core conditions. Using an astrochemical model, we test five different reaction mechanisms that have been proposed in the astrophysical literature, finding that a gas-phase formation route is unlikely. Of the grain-surface formation routes, only two are efficient enough at very low temperatures to produce sufficient glycolaldehyde to match the observational estimates, with the mechanism culminating in CH3OH + HCO being favored. However, when we consider the feasibility of these mechanisms from a reaction chemistry perspective, the second grain-surface route looks more promising, H3CO + HCO

The inner wind of IRC+10216 revisited: New exotic chemistry and diagnostic for dust condensation in carbon stars

Aims. We model the chemistry of the inner wind of the carbon star IRC+10216 and consider the effect of periodic shocks induced by the stellar pulsation on the gas to follow the non-equilibrium chemistry in the shocked gas layers. We consider a very complete set of chemical families, including hydrocarbons and aromatics, hydrides, halogens and phosphorous-bearing species. Derived abundances are compared to the latest observational data from large surveys and Herschel. Results. The shocks induce a non-equilibrium chemistry in the dust formation zone of IRC+10216 where the collision destruction of CO in the post-shock gas triggers the formation of O-bearing species (H2O, SiO). Most of the modelled abundances agree very well with the latest values derived from Herschel data on IRC+10216. Hydrides form a family of abundant species that are expelled into the intermediate envelope. In particular, HF traps all the atomic fluorine in the dust formation zone. Halogens are also abundant and their chemistry is independent of the C/O ratio of the star. Therefore, HCl and other Cl-bearing species should also be present in the inner wind of O-rich AGB or supergiant stars. We identify a specific region ranging from 2.5 R* to 4 R*, where polycyclic aromatic hydrocarbons form and grow. The estimated carbon dust-to-gas mass ratio derived from the mass of aromatics ranges from 1.2 x 10^(-3) to 5.8 x 10^{-3} and agrees well with existing observational values. The aromatic formation region is located outside hot layers where SiC2 is produced as a bi-product of silicon carbide dust synthesis. Finally, we predict that some molecular lines will show flux variation with pulsation phase and time (e.g., H2O) while other species will not (e.g., CO). These variations merely reflect the non-equilibrium chemistry that destroys and reforms molecules over a pulsation period in the shocked gas of the dust formation zone.Comment: 15 pages, 10 figures. Accepted for publication in Astronomy & Astrophysic

Laboratory and tentative interstellar detection of trans-methyl formate using the publicly available Green Bank Telescope PRIMOS survey

The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) \times 10^13 cm-2 and a rotational temperature of 7.6 \pm 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium.Comment: 40 pages, 7 figures, 4 tables; accepted for publication in Ap