Accelerated and natural carbonation of concrete with high volumes of fly ash : chemical, mineralogical and microstructural effects

Today, a rather poor carbonation resistance is being reported for high-volume fly ash (HVFA) binder systems. This conclusion is usually drawn from accelerated carbonation experiments conducted at CO2 levels that highly exceed the natural atmospheric CO2 concentration of 0.03-0.04%. However, such accelerated test conditions may change the chemistry of the carbonation reaction (and the resulting amount of CH and C-S-H carbonation), the nature of the mineralogical phases formed (stable calcite versus metastable vaterite, aragonite) and the resulting porosity and pore size distribution of the microstructure after carbonation. In this paper, these phenomena were studied on HVFA and fly ash thorn silica fume (FA + SF) pastes after exposure to 0.03-0.04%, 1% and 10% CO2 using thermogravimetric analysis, quantitative X-ray diffraction and mercury intrusion porosimetry. It was found that none of these techniques unambiguously revealed the reason for significantly underestimating carbonation rates at 1% CO2 from colorimetric carbonation test results obtained after exposure to 10% CO2 that were implemented in a conversion formula that solely accounts for the differences in CO2 concentration. Possibly, excess water production due to carbonation at too high CO2 levels with a pore blocking effect and a diminished solubility for CO2 plays an important role in this

Life cycle assessment of a column supported isostatic beam in high-volume fly ash concrete (HVFA concrete)

Nowadays, a lot of research is being conducted on high-volume fly ash (HVFA) concrete. However, a precise quantification of the environmental benefit is almost never provided. To do this correctly, we adopted a life cycle (LCA) approach. By considering a simple structure and an environment for the material, differences between traditional and HVFA concrete regarding durability and strength were taken into account. This paper presents the LCA results for a column supported isostatic beam made of reinforced HVFA concrete located in a dry environment exposed to carbonation induced corrosion. With a binder content of 425 kg/m3 and a water-to-binder ratio of 0.375, the estimated carbonation depth after 50 years for a 50 % fly ash mixture does not exceed the nominal concrete cover of 20 mm. As a consequence, no additional concrete manufacturing for structure repair needs to be included in the study. Moreover, structure dimensions can be reduced significantly due to a higher strength compared to the reference concrete used in the same environment. In total, about 32 % of cement can be saved this way. The reduction in environmental impact equals 25.8 %, while this is only 11.4 % if the higher material strength is not considered

Life cycle assessment of completely recyclable concrete

Since the construction sector uses 50% of the Earth. s raw materials and produces 50% of its waste, the development of more durable and sustainable building materials is crucial. Today, Construction and Demolition Waste (CDW) is mainly used in low level applications, namely as unbound material for foundations, e.g., in road construction. Mineral demolition waste can be recycled as crushed aggregates for concrete, but these reduce the compressive strength and affect the workability due to higher values of water absorption. To advance the use of concrete rubble, Completely Recyclable Concrete (CRC) is designed for reincarnation within the cement production, following the Cradle-to-Cradle (C2C) principle. By the design, CRC becomes a resource for cement production because the chemical composition of CRC will be similar to that of cement raw materials. If CRC is used on a regular basis, a closed concrete-cement-concrete material cycle will arise, which is completely different from the current life cycle of traditional concrete. Within the research towards this CRC it is important to quantify the benefit for the environment and Life Cycle Assessment (LCA) needs to be performed, of which the results are presented in a this paper. It was observed that CRC could significantly reduce the global warming potential of concrete

Book Review: The Post-9/11 Video Game: A Critical Examination

Review of The Post-9/11 Video Game: A Critical Examination by by Jason C. Thompson and Marc A. Ouellette

Neutron radiography based visualization and profiling of water uptake in (un)cracked and autonomously healed cementitious materials

Given their low tensile strength, cement-based materials are very susceptible to cracking. These cracks serve as preferential pathways for corrosion inducing substances. For large concrete infrastructure works, currently available time-consuming manual repair techniques are not always an option. Often, one simply cannot reach the damaged areas and when making those areas accessible anyway (e.g., by redirecting traffic), the economic impacts involved would be enormous. Under those circumstances, it might be useful to have concrete with an embedded autonomous healing mechanism. In this paper, the effectiveness of incorporating encapsulated high and low viscosity polyurethane-based healing agents to ensure (multiple) crack healing has been investigated by means of capillary absorption tests on mortar while monitoring the time-dependent water ingress with neutron radiography. Overall visual interpretation and water front/sample cross-section area ratios as well as water profiles representing the area around the crack and their integrals do not show a preference for the high or low viscosity healing agent. Another observation is that in presence of two cracks, only one is properly healed, especially when using the latter healing agent. Exposure to water immediately after release of the healing agent stimulates the foaming reaction of the polyurethane and ensures a better crack closure

Internal curing of cement pastes by superabsorbent polymers studied by means of neutron radiography

Autogenous shrinkage is a problem in cementitious materials with a low water-to-binder ratio. When the internal relative humidity decreases due to the ongoing hydration reaction and selfdesiccation, autogenous shrinkage takes place if no external or internal water source is present. This may lead to cracking and eventually cause durability problems in constructions. Ideally, the internal relative humidity should be maintained during hydration of the cement paste. Superabsorbent polymers (SAPs) may be used to mitigate autogenous shrinkage. When self-desiccation occurs, these polymers will release their absorbed additional mixing water due to increasing capillary forces to stimulate internal curing. This release of water towards the cementitious matrix and the effect on the cementitious matrix itself can be studied by means of neutron radiography. In this study, thin samples of cement paste were casted between glass plates and the evolution of the internal water amount was studied as a function of time. In specimens without SAPs and a water-to-binder ratio of 0.30, shrinkage was seen. Furthermore, autogenous shrinkage was reduced in cement pastes when using SAPs and an additional entrained water-to-binder ratio of 0.054. The release of water from smaller SAPs (100 μm dry size) seemed to be more promising compared to bigger SAPs (500 μm) with the same absorption properties. The technique of neutron radiography supports the findings of shrinkage tests where SAPs were already proven to be useful. This opens additional insights towards the application of SAPs in the construction area