Studies on ferrous ion-induced lipid peroxidation of rat liver mitochondria. I. Effect of inorganic phosphate

Effect of inorganic phosphate on ferrous ion- and ascorbate-induced lipid. peroxidations of isolated rat liver mitochondria was investigated. As a result it has been shown that phosphate accelerates the ferrous ion.induced lipid peroxidation; namely, phos. phate shortens the induction lag period of the lipid peroxidation reaction but the malondialdehyde after onset of its production is yielded at the same rate in various concentrations of phosphate. On the other hand, phosphate inhibits ascorbate.induced lipid peroxidation. There are stoichiometric interactions between the concentration of phos. phate and the induction period. Oxygen uptake by mitochondria was observed in the presence of both ferrous ion and phosphate at initial step of the reaction without being accompanied by malondialdehyde production, and afterwards there occurred malondialdehyde production with rapid rate of the oxygen uptake. Possible mechanisms and interactions among ferrous ion, ascorbate and phosphate were discussed.</p

Sub-Arcsecond Near-Infrared Images of Massive Star Formation Region NGC 6334 V

We present high spatial resolution (0\farcs3) polarimetric images in the $H$ and $K$ bands and direct images in the $L'$ and $M'$ bands of the NGC 6334 V infrared nebulae. The images show complex structures including the multi-shells and various knots in the nebulae. The appearances and colors of the eastern and western nebulae differ considerably. Our polarization images also show differences between the illuminating sources of the nebulae: the eastern nebula is illuminated by a deeply embedded mid-infrared source, KDJ 4, and the western nebula by our newly detected near-infrared source, WN-A1. The degree of polarization of the nebulae is very large, up to 70% at $K$ and 60% at $H$, which is consistent with a single scattering of near-infrared radiation from each source at the walls of the mass outflows

Ab initio Study of Valley Line on a Total-Energy Surface for Zone-Center Distortions of Ferroelectric Perovskite Oxides BaTiO3 and PbTiO3

An ab initio structure optimization technique is newly developed to determine the valley line on a total-energy surface for zone-center distortions of ferroelectric perovskite oxides and is applied to barium titanate BaTiO3 and lead titanate PbTiO3. The proposed technique is an improvement over King-Smith and Vanderbilt's scheme [Phys. Rev. B 49, p.5828 (1994)] of evaluating total energy as a function of the amplitude of atomic displacements. The results of numerical calculations show that total energy can be expressed as a fourth-order function of the amplitude of atomic displacements in BaTiO3 but not in PbTiO3.Comment: 4 pages, 5 figure

ab initio Study of Strain-Induced Ferroelectricity in SrTiO3

Valley lines on total-energy surfaces for the zone-center distortions of free-standing and in-plane strained SrTiO3 are investigated with a newly developed first-principles structure optimization technique [Jpn. J. Appl. Phys. vol.43 (2004), p.6785]. The results of numerical calculations confirmed that the ferroelectricity is induced, and the Curie temperature is increased, by applying biaxial compressive or tensile strains. Along the distortion, strong nonlinear coupling between the soft- and hard-modes is demonstrated.Comment: 15 pages, 10 figures, submitted to Jpn. J. Appl. Phy