O- vs. N-protonation of 1-dimethylaminonaphthalene-8-ketones: formation of a peri N–C bond or a hydrogen bond to the pi-electron density of a carbonyl group

X-ray crystallography and solid-state NMR measurements show that protonation of a series of 1-dimethylaminonaphthalene-8-ketones leads either to O protonation with formation of a long N–C bond (1.637–1.669 Å) between peri groups, or to N protonation and formation of a hydrogen bond to the π surface of the carbonyl group, the latter occurring for the larger ketone groups (C(O)R, R = t-butyl and phenyl). Solid state 15N MAS NMR studies clearly differentiate the two series, with the former yielding significantly more deshielded resonances. This is accurately corroborated by DFT calculation of the relevant chemical shift parameters. In the parent ketones X-ray crystallography shows that the nitrogen lone pair is directed towards the carbonyl group in all cases

Observation of chi_c2 Production in B-meson Decay

We report the first observation of chi_c2 production in B-meson decays. We find an inclusive B -> chi_c2 X branching fraction of (1.80^{+0.23}_{-0.28}+/- 0.26) 10^-3. The data set, collected with the Belle detector at the KEKB e^+e^- collider, consists of 31.9 million B\bar B events. We also present branching fractions and momentum spectra for both chi_c1 and chi_c2 production.Comment: 5 pages with 2 figure

Observation of Ds+ K- and evidence for Ds+ pi- final states in neutral B decays

We report the first observation of a B meson decay that is not accessible by a direct spectator process. The channel B0bar -> Ds+ K- is found in a sample of 85 timse 10^6 B Bbar events, collected with the Belle detector at KEKB, with a branching fraction Br(B0bar -> Ds+ K-)=(4.6^{+1.2}_{-1.1} +- 1.3) times 10^{-5}. We also obtain evidence for the B0 -> Ds+ pi- decay with branching fraction Br(B0 -> Ds+ pi-)=(2.4^{+1.0}_{-0.8} +- 0.7) times 10^{-5}. This value may be used to extract a model-dependent value of |Vub|.Comment: Accepted to publication in Phys. Rev. Let

Study of CP-Violating Asymmetries in B0 -> pi+pi- Decays

We present a measurement of CP-violating asymmetries in B0 -> pi+pi- decays based on a 41.8 fb-1 data sample collected at the Upsilon(4S) resonance with the Belle detector at the KEKB asymmetric-energy e+e- collider. We fully reconstruct one neutral B meson as a B0 -> pi+pi- CP eigenstate and identify the flavor of the accompanying B meson from its decay products. From the asymmetry in the distribution of the time intervals between the two B meson decay points, we obtain the CP-violating asymmetry parameters Spipi = -1.21 +0.38/-0.27(stat) +0.16/-0.13(syst) and Apipi = +0.94 +0.25/-0.31(stat) +/- 0.09(syst).Comment: 9 pages, 2 figures, accepted for publication in Physical Review Letter

Observation of Mixing-induced CP Violation in the Neutral B Meson System

This report describes an observation of mixing-induced CP violation and a measurement of the CP violation parameter, sin(2phi_1), with the Belle detector at the KEKB asymmetric e+e- collider. Using a data sample of 29.1 fb-1 recorded on the Upsilon(4S) resonance that contains 31.3 million BBbar pairs, we reconstruct decays of neutral B mesons to the following CP eigenstates: J/psi K_S^0, psi(2S) K_S^0, chi_c1 K_S^0, eta_c K_S^0, J/psi K_L^0 and J/psi K^*0. The flavor of the accompanying B meson is identified by combining information from primary and secondary leptons, K+/- mesons, lambda baryons, slow and fast pions. The proper-time interval between the two B meson decays is determined from the distance between the two decay vertices measured with a silicon vertex detector. The result sin(2phi_1) = 0.99 +/- 0.14(stat) +/- 0.06(syst) is obtained by applying a maximum likelihood fit to the 1137 candidate events. We conclude that there is large CP violation in the neutral B meson system. A zero value for sin(2phi_1) is ruled out by more than six standard deviations.Comment: 25 pages, 16 figures, accepted for publication in Physical Review

Observation of the decay B^0->D+D*-

We report the first observation of the decay B^0->D+-D*-+ with the Belle detector at the KEKB e^+e^- collider operated at the Upsilon(4S) resonance. The sum of branching fractions B(B^0->D+D*-)+B(B^0->D-D*+) is measured to be (1.17+-0.26+0.22-0.25)x10^-3 using the full reconstruction method where both charmed mesons from B^0 decays are reconstructed. A consistent value ((1.48+-0.38+0.28-0.31)x10^-3) is obtained using a partial reconstruction technique that only uses the slow pion from the D*- ->bar D^0pi- decay and a fully reconstructed D+ to reconstruct the B^0.Comment: 10 pages, 3 figure