Tuning the electrical conductivity of Pt-containing granular metals by postgrowth electron irradiation

We have fabricated Pt-containing granular metals by focused electron beam induced deposition from the $(CH_3)_3CH_3C_5H_4Pt$ precursor gas. The granular metals are made of platinum nanocrystallites embedded in a carbonaceous matrix. We have exposed the as-grown nanocomposites to low energy electron beam irradiation and we have measured the electrical conductivity as a function of the irradiation dose. Postgrowth electron beam irradiation transforms the matrix microstructure and thus the strength of the tunneling coupling between Pt nanocrystallites. For as-grown samples (weak tunnel coupling regime) we find that the temperature dependence of the electrical conductivity follows the stretched exponential behavior characteristic of the correlated variable-range hopping transport regime. For briefly irradiated samples (strong tunnel coupling regime) the electrical conductivity is tuned across the metal-insulator transition. For long-time irradiated samples the electrical conductivity behaves like that of a metal. In order to further analyze changes of the microstructure as a function of the electron irradiation dose we have carried out transmission electron microscope (TEM), micro-Raman and atomic force microscopy (AFM) investigations. TEM pictures reveal that the crystallites' size of long-time irradiated samples is larger than that of as-grown samples. Furthermore we do not have evidence of microstructural changes in briefly irradiated samples. By means of micro-Raman we find that by increasing the irradiation dose the matrix changes following a graphitization trajectory between amorphous carbon and nanocrystalline graphite. Finally, by means of AFM measurements we observe a reduction of the volume of the samples with increasing irradiation time which we attribute to the removal of carbon molecules

Effect of Aqueous Ozone on the NF-κB System

Ozone has been proposed as an alternative oral antiseptic in dentistry, due to its antimicrobial power reported for gaseous and aqueous forms, the latter showing a high biocompatibility with mammalian cells. New therapeutic strategies for the treatment of periodontal disease and apical periodontitis should consider not only antibacterial effects, but also their influence on the host immune response. Therefore, our aim was to investigate the effect of aqueous ozone on the NF-κB system, a paradigm for inflammationassociated signaling/transcription. We showed that NF-κB activity in oral cells stimulated with TNF, and in periodontal ligament tissue from root surfaces of periodontally damaged teeth, was inhibited following incubation with ozonized medium. Under this treatment, IκBalpah proteolysis, cytokine expression, and κB-dependent transcription were prevented. Specific ozonized amino acids were shown to represent major inhibitory components of ozonized medium. In summary, our study establishes a condition under which aqueous ozone exerts inhibitory effects on the NF-κB system, suggesting that it has an antiinflammatory capacity

Translocação do inseticida tiametoxam+lambdacialotrina da folha para a haste de plantas de soja.

Foram realizados dois experimentos com objetivo de avaliar a translocação do inseticida tiametoxam+lambdacialotrina da folha para a haste da planta de soja, utilizando o percevejo Edessa meditabunda como bioindicador. Em casa-de-vegetação, plantas de soja da cultivar BRS 284, no estágio R5, foram tratadas com 1,667 mL/L de Engeo Pleno® (tiametoxam+lambdacialotrina), pelo método de imersão da folha. Foi utilizado o delineamento inteiramente casualizado, com unidades experimentais compostas por 3 adultos do percevejo confinados na haste da planta de soja. No EXPERIMENTO A foram estudados 4 tratamentos com 4 repetições. Nos tratamentos T1A e T2A todas as folhas foram tratadas com o inseticida e a haste foi infestada na sua metade superior e inferior, respectivamente. T3A e T4A não receberam inseticida e a haste foi infestada na sua metade superior e inferior, respectivamente. Os resultados mostram que ocorre translocação do inseticida da folha para a haste, em quantidade suficiente para causar mortalidade superior a 93% (T1A) e 83% (T2A), aos 9-12 DAI (dias após a infestação). No EXPERIMENTO B foram estudados 6 tratamentos com 6 repetições. Em T1B e T2B foram tratadas as folhas da metade superior da planta e foi infestada a haste da sua metade superior e inferior, respectivamente. Em T3B e T4B foram tratadas as folhas da metade inferior da planta e foi infestada a sua metade superior e inferior, respectivamente. T5B e T6B não receberam inseticida e a planta foi infestada na sua metade superior e inferior, respectivamente. Neste experimento, as maiores mortalidades foram observadas aos 10 DAI, nos tratamentos em que os insetos foram confinados na mesma metade da planta que recebeu o inseticida, T1B (77%) e T4B (70%) não diferindo de T3B (63%) em que os insetos foram confinados acima do ponto de aplicação do inseticida. Enquanto que em T2B a mortalidade foi inferior a 17%. Assim conclui-se que o produto transloca da folha para a haste e apresenta movimento ascendente

Shuttle Ku-band and S-band communications implementation study

Various aspects of the shuttle orbiter S-band network communication system, the S-band payload communication system, and the Ku-band communication system are considered. A method is proposed for obtaining more accurate S-band antenna patterns of the actual shuttle orbiter vehicle during flight because the preliminary antenna patterns using mock-ups are not realistic that they do not include the effects of additional appendages such as wings and tail structures. The Ku-band communication system is discussed especially the TDRS antenna pointing accuracy with respect to the orbiter and the modifications required and resulting performance characteristics of the convolutionally encoded high data rate return link to maintain bit synchronizer lock on the ground. The TDRS user constraints on data bit clock jitter and data asymmetry on unbalanced QPSK with noisy phase references are included. The S-band payload communication system study is outlined including the advantages and experimental results of a peak regulator design built and evaluated by Axiomatrix for the bent-pipe link versus the existing RMS-type regulator. The nominal sweep rate for the deep-space transponder of 250 Hz/s, and effects of phase noise on the performance of a communication system are analyzed

Fabrication of FeSi and Fe3Si compounds by electron beam induced mixing of [Fe/Si]2 and [Fe3/Si]2 multilayers grown by focused electron beam induced deposition

Fe-Si binary compounds have been fabricated by focused electron beam induced deposition by the alternating use of iron pentacarbonyl, Fe(CO)5, and neopentasilane, Si5H12 as precursor gases. The fabrication procedure consisted in preparing multilayer structures which were treated by low-energy electron irradiation and annealing to induce atomic species intermixing. In this way we are able to fabricate FeSi and Fe3Si binary compounds from [Fe=Si]2 and [Fe3=Si]2 multilayers, as shown by transmission electron microscopy investigations. This fabrication procedure is useful to obtain nanostructured binary alloys from precursors which compete for adsorption sites during growth and, therefore, cannot be used simultaneously

Shuttle orbiter Ku-band radar/communications system design evaluation

Tasks performed in an examination and critique of a Ku-band radar communications system for the shuttle orbiter are reported. Topics cover: (1) Ku-band high gain antenna/widebeam horn design evaluation; (2) evaluation of the Ku-band SPA and EA-1 LRU software; (3) system test evaluation; (4) critical design review and development test evaluation; (5) Ku-band bent pipe channel performance evaluation; (6) Ku-band LRU interchangeability analysis; and (7) deliverable test equipment evaluation. Where discrepancies were found, modifications and improvements to the Ku-band system and the associated test procedures are suggested

Perturbation theory for plasmonic eigenvalues

We develop a perturbative approach for calculating, within the quasistatic approximation, the shift of surface resonances in response to a deformation of a dielectric volume. Our strategy is based on the conversion of the homogeneous system for the potential which determines the plasmonic eigenvalues into an inhomogeneous system for the potential's derivative with respect to the deformation strength, and on the exploitation of the corresponding compatibility condition. The resulting general expression for the first-order shift is verified for two explicitly solvable cases, and for a realistic example of a deformed nanosphere. It can be used for scanning the huge parameter space of possible shape fluctuations with only quite small computational effort

Hydrodynamic fluctuations and instabilities in ordered suspensions of self-propelled particles

We construct the hydrodynamic equations for {\em suspensions} of self-propelled particles (SPPs) with spontaneous orientational order, and make a number of striking, testable predictions:(i) SPP suspensions with the symmetry of a true {\em nematic} are {\em always} absolutely unstable at long wavelengths.(ii) SPP suspensions with {\em polar}, i.e., head-tail {\em asymmetric}, order support novel propagating modes at long wavelengths, coupling orientation, flow, and concentration. (iii) In a wavenumber regime accessible only in low Reynolds number systems such as bacteria, polar-ordered suspensions are invariably convectively unstable.(iv) The variance in the number N of particles, divided by the mean , diverges as $^{2/3}$ in polar-ordered SPP suspensions.Comment: submitted to Phys Rev Let