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Department of Energy Engineering (Battery Science and Technology)The continuous throng in demand for high energy density rechargeable batteries innovatively drives technological development in cell design as well as electrochemically active materials. In that perspective metal-free batteries consisting of a flowing seawater as a cathode active material were introduced. However, the electrochemical performance of the seawater battery was restrained by NASICON (Na3Zr2Si2PO12) ceramic solid electrolyte. Here, we demonstrate a new class of fibrous nanomat hard-carbon (FNHC) anode/1D (one-dimensional) bucky paper (1DBP) cathode hybrid electrode architecture in seawater battery based on 1D building block-interweaved hetero-nanomat frameworks. Differently from conventional slurry-cast electrodes, exquisitely designed hybrid hetero-nanomat electrodes are fabricated through concurrent dual electrospraying and electrospinning for the anode, vacuum-assisted infiltration for the cathode. HC nanoparticles are closely embedded in the spatially reinforced polymeric nanofiber/CNT hetero-nanomat skeletons that play a crucial role in constructing 3D-bicontinuous ion/electron transport pathways and allow to eliminate heavy metallic aluminum foil current collectors. Eventually the FNHC/1DBP seawater full cell, driven by aforementioned physicochemical uniqueness, shows exceptional improvement in electrochemical performance (Energy density = 693 Wh kg-1), (Power density = 3341 W kg-1) removing strong stereotype of ceramic solid electrolyte, which beyond those achievable with innovative next generation battery technologies.ope

Fermion masses and mixings from heterotic orbifold models

We search for a possibility of getting realistic fermion mass ratios and mixing angles from renormalizable couplings on the Z_6-I heterotic orbifold with one pair of Higgs doublets. In the quark sector, we find cases with reasonable m_c/m_t, m_s/m_b, and V_{cb}, if we ignore the first family. In the lepton sector, we can fit the charged lepton mass ratios, the neutrino mass squared difference ratio, and the lepton mixing angles, considering all three families.Comment: 4 pages, 2 figures, 5 tables; talk presented at PASCOS-05, Gyeongju, May 30-Jun 4, 2005; to appear in the proceeding

Lepton flavour violation from right-handed neutrino thresholds

Charged lepton flavour violation is reappraised in the context of supersymmetric see-saw mechanism. It is pointed out that a non-trivial flavour structure of right-handed neutrinos, whose effect has been thus far less studied, can give rise to significant slepton flavour transitions. Under the premise that the neutrino Yukawa couplings are of O(1), the right-handed neutrino mixing contribution could form a basis of the $\mu \rightarrow e \gamma$ amplitude which by itself might lead to an experimentally accessible rate, given a typical low-energy sparticle spectrum. Emphasis is placed on the crucial role of the recently measured lepton mixing angle $\theta_{13}$ as well as the leptonic CP-violating phases.Comment: 6 pages, changed title, added spurion interpretation, conclusions unchanged, published versio

Physical insight into the thermodynamic uncertainty relation using Brownian motion in tilted periodic potentials

Using Brownian motion in periodic potentials $V(x)$ tilted by a force $f$, we provide physical insight into the thermodynamic uncertainty relation, a recently conjectured principle for statistical errors and irreversible heat dissipation in nonequilibrium steady states. According to the relation, nonequilibrium output generated from dissipative processes necessarily incurs an energetic cost or heat dissipation $q$, and in order to limit the output fluctuation within a relative uncertainty $\epsilon$, at least $2k_BT/\epsilon^2$ of heat must be dissipated. Our model shows that this bound is attained not only at near-equilibrium ($f\ll V'(x)$) but also at far-from-equilibrium $(f\gg V'(x))$, more generally when the dissipated heat is normally distributed. Furthermore, the energetic cost is maximized near the critical force when the barrier separating the potential wells is about to vanish and the fluctuation of Brownian particle is maximized. These findings indicate that the deviation of heat distribution from Gaussianity gives rise to the inequality of the uncertainty relation, further clarifying the meaning of the uncertainty relation. Our derivation of the uncertainty relation also recognizes a new bound of nonequilibrium fluctuations that the variance of dissipated heat ($\sigma_q^2$) increases with its mean ($\mu_q$) and cannot be smaller than $2k_BT\mu_q$.Comment: 11 pages, 1 figure, paper revised including changes in title, abstrac