A TR ESR Study of the Quenching of Photoexcited Dioxouranium (VI) Salts by Stable Nitroxyl Free Radicals

TR ESR spectroscopy was applied to the study of the quenching of excited dioxouranium (VI) (uranyl) nitrate and sulfate by stable nitroxyl radicals of the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) family. Photoexcitation of uranyl in solutions of alcohols of moderate viscosity (η = 3-10 cP) in the presence of TEMPO leads to CIDEP signals of TEMPO due to a radical triplet pair mechanism (RTPM). Polarized nitroxyls were also observed in solutions of polyelectrolyte sodium poly(styrenesulfonate), NaPSS, in the presence of the nitroxyl with a positively charged trimethylammonium group. Photolysis of uranyl salts in solutions of alcohols leads to the generation of free radicals of alcohols. No CIDEP of these radicals was observed, distinguishing U2 2+* from its organic analog, the triplet benzophenone. The probable reason for the lack of polarization in uranyl photoreduction reactions is the difficult access of free radicals to the U atom of the solvated radical UO2+ (V); this atom bears the unpaired electron. The role of polyelectrolytes in the enhancement of the quenching of excited states is discussed. Results are in agreement with the statement that photoexcited uranyl has a triplet multiplicity

Nonequilibrium electron spin polarization in a double quantum dot. Lande mechanism

In moderately strong magnetic fields, the difference in Lande g-factors in each of the dots of a coupled double quantum dot device may induce oscillations between singlet and triplet states of the entangled electron pair and lead to a nonequilibrium electron spin polarization. We will show that this polarization may partially survive the rapid inhomogeneous decoherence due to random nuclear magnetic fields.Comment: New version contains figures. New title better reflects the content of the pape

Transcriptome analysis of northern elephant seal (Mirounga angustirostris) muscle tissue provides a novel molecular resource and physiological insights

BackgroundThe northern elephant seal, Mirounga angustirostris, is a valuable animal model of fasting adaptation and hypoxic stress tolerance. However, no reference sequence is currently available for this and many other marine mammal study systems, hindering molecular understanding of marine adaptations and unique physiology.ResultsWe sequenced a transcriptome of M. angustirostris derived from muscle sampled during an acute stress challenge experiment to identify species-specific markers of stress axis activation and recovery. De novo assembly generated 164,966 contigs and a total of 522,699 transcripts, of which 68.70% were annotated using mouse, human, and domestic dog reference protein sequences. To reduce transcript redundancy, we removed highly similar isoforms in large gene families and produced a filtered assembly containing 336,657 transcripts. We found that a large number of annotated genes are associated with metabolic signaling, immune and stress responses, and muscle function. Preliminary differential expression analysis suggests a limited transcriptional response to acute stress involving alterations in metabolic and immune pathways and muscle tissue maintenance, potentially driven by early response transcription factors such as Cebpd.ConclusionsWe present the first reference sequence for Mirounga angustirostris produced by RNA sequencing of muscle tissue and cloud-based de novo transcriptome assembly. We annotated 395,102 transcripts, some of which may be novel isoforms, and have identified thousands of genes involved in key physiological processes. This resource provides elephant seal-specific gene sequences, complementing existing metabolite and protein expression studies and enabling future work on molecular pathways regulating adaptations such as fasting, hypoxia, and environmental stress responses in marine mammals

Analysis of advanced IGCC economic indicators

In this paper, the influence presence of a shift reactor and a CO2 removal unit (CCS) from syngas (pre-combustion technology) on the thermal efficiency of a combined-cycle plant with in-cycle gasification of solid fuel (IGCC) is considered. The literature sources on the effect of CCS on the thermal efficiency of three oxygen IGCC are analyzed. The calculated influence of the degree of integration of CCS in the demonstration IGCC scheme on the composition of the combusted gas fuel is presented. The principle of shift-reactor operation is given. Various types of catalysts used in the shift reactor are considered. The influence of CCS on the economic and environmental indicators of IGCC is analyzed. The analysis of air IGCC schemes with CCS node and without it is carried out.В данной работе рассматривается влияние наличия shift-реактора и узла удаления СО2 (CCS) из синтез-газа (технология pre-combustion) на термический КПД перспективной парогазовой установки с внутрицикловой газификацией твёрдого топлива (ПГУ-ВЦГ). Проведен анализ литературных источников по влиянию CCS на термический КПД трёх кислородных ПГУ-ВЦГ. Представлено расчетное влияние степени интеграции CCS в схему демонстрационной ПГУ-ВЦГ на состав сжигаемого газового топлива. Приводится принцип работы shift-реактора. Рассматриваются различные типы катализаторов, используемых в shift-реакторе. Проанализировано влияние CCS на экономические и экологические показатели ПГУ-ВЦГ. Проведен анализ схем перспективной воздушной ПГУ-ВЦГ с узлом CCS и без него

Measurement of the K+→μ+νμγK^+\rightarrow{\mu^+}{\nu_{\mu}}{\gamma} decay form factors in the OKA experiment

A precise measurement of the vector and axial-vector form factors difference $F_V-F_A$ in the $K^+\rightarrow{\mu^+}{\nu_{\mu}}{\gamma}$ decay is presented. About 95K events of $K^+\rightarrow{\mu^+}{\nu_{\mu}}{\gamma}$ are selected in the OKA experiment. The result is $F_V-F_A=0.134\pm0.021(stat)\pm0.027(syst)$. Both errors are smaller than in the previous $F_V-F_A$ measurements.Comment: 9 pages, 8 figure

Vector Particle Interactions In the Quasipotential Approach

The composite system, formed by two $S=1$ particles, is considered. The field operators of constituents are transformed on the $(1,0)\oplus (0,1)$ representation of the Lorentz group. The problem of interaction of $S=1$ particle with the electromagnetic field is also discussed.Comment: LateX file, 7pp., Preprint IFUNAM FT-93-01

Ke3K_{e3} decay studies in OKA experiment

Recent results from OKA setup concerning form factor studies in $K_{e3}$ decay are presented. About 5.25M events are selected for the analysis. The linear and quadratic slopes for the decay formfactor $f_{+}(t)$ are measured: $\lambda'_{+}=(26.1 \pm 0.35 \pm 0.28 )\times 10^{-3}$, $\lambda"_{+}=(1.91 \pm 0.19 \pm 0.14)\times 10^{-3}$. The scalar and tensor contributions are compatible with zero. Several alternative parametrizations are tried: the Pole fit parameter is found to be $M_V = 891 \pm 2.0$ MeV ; the parameter of the Dispersive parametrization is measured to be $\Lambda_+ =(24.58 \pm 0.18) \times 10^{-3}$. The presented results are considered as preliminary

Free Energy of an SU(2) Model of (2+1)-dimensional QCD in the Constant Condensate Background

Gluon and quark contributions to the thermodynamic potential (free energy) of a (2+1)-dimensional QCD model at finite temperature in the background of a constant homogeneous chromomagnetic field H combined with A_0 condensate are calculated. The role of the tachyonic mode in the gluon energy spectrum is discussed. A possibility of the free energy global minimum generation at nonzero values of H and A_0 condensates is investigated.Comment: LaTeX 2e, 14 pages, 6 eps figures, some miscalculations were correcte

Prospects for K+→π+ννˉK^+ \to \pi^+ \nu \bar{ \nu } at CERN in NA62

The NA62 experiment will begin taking data in 2015. Its primary purpose is a 10% measurement of the branching ratio of the ultrarare kaon decay $K^+ \to \pi^+ \nu \bar{ \nu }$, using the decay in flight of kaons in an unseparated beam with momentum 75 GeV/c.The detector and analysis technique are described here.Comment: 8 pages for proceedings of 50 Years of CP