Evidence for suboxic nitrification in recent marine sediments

The classical scheme of biogeochemical zones (BGZ) is known to be an oversimplification of the microbial processes that occur in organic-rich marine sediments. Results from a coupled deployment of pore-water gel probes in Loch Duich, Scotland, provide direct evidence for rapid recycling within the iron reduction (FeR) and sulphate reduction (SR) zones. High resolution porewater profiles obtained using diffusive equilibrium in thin films (DET) gel probes found a nitrate peak at the boundary between the FeR and SR zones. This non-steady state feature is consistent with recycling of reduced N occurring throughout the FeR zone. Both conventional pore-water iron profiles and results from diffusive gradient in thin films (DGT) probes indicate that iron is solubilised and precipitated in rapid Fe/S recycling reactions throughout the SR zone. The presence of such complex recycling reactions confirms the oversimplification of the classical BGZ scheme

Anoxic nitrification in marine sediments

Nitrate peaks are found in pore-water profiles in marine sediments at depths considerably below the conventional zone of oxic nitrification. These have been interpreted to represent nonsteady- state effects produced by the activity of nitrifying bacteria, and suggest that nitrification occurs throughout the anoxic sediment region. In this study, ΣNO3 peaks and molecular analysis of DNA and RNA extracted from anoxic sediments of Loch Duich, an organic-rich marine fjord, are consistent with nitrification occurring in the anoxic zone. Analysis of ammonia oxidiser 16S rRNA gene fragments amplified from sediment DNA indicated the abundance of autotrophic ammonia-oxidising bacteria throughout the sediment depth sampled (40 cm), while RT-PCR analysis indicated their potential activity throughout this region. A large non-steady-state pore-water ΣNO3 peak at ~21 cm correlated with discontinuities in this ammonia-oxidiser community. In addition, a subsurface nitrate peak at ~8 cm below the oxygen penetration depth, correlated with the depth of a peak in nitrification rate, assessed by transformation of 15N-labelled ammonia. The source of the oxidant required to support nitrification within the anoxic region is uncertain. It is suggested that rapid recycling of N is occurring, based on a coupled reaction involving Mn oxides (or possibly highly labile Fe oxides) buried during small-scale slumping events. However, to fully investigate this coupling, advances in the capability of high-resolution pore-water techniques are required

Thermodynamic modeling of the LiF-YF3 phase diagram

A thermodynamic optimization of the LiF-YF3 binary phase diagram was performed by fitting the Gibbs energy functions to experimental data that were taken from the literature, as well as from own thermoanalytic measurements (DTA and DSC) on HF-treated samples. The Gibbs energy functions for the end member compounds were taken from the literature. Excess energy terms, which describe the effect of interaction between the two fluoride compounds in the liquid phase, were expressed by the Redlich-Kister polynomial function. The calculated phase diagram and thermodynamic properties for the unique formed compound, LiYF4, are in reasonable agreement with the experimental data.Comment: 4 pages, 3 figure

Beyond the project cycle: an evaluation of agroforestry adoption and diffusion over the medium term in a south Indian village

Few studies explicitly assess the temporal and spatial dynamics of agroforestry adoption occurring beyond the project cycle. Where ex-post evaluations are published, abandonment of introduced agroforestry after project cessation is often reported. This paper presents an analysis of agroforestry adoption in a poor, peri-urban village in semi-arid south India, where 97 % of initial adopters had retained their plots six to eight years after implementation. The intervention was facilitated by BAIF, an Indian non-governmental organisation specialising in natural resource management. The complex technological package promoted was known as ‘wadi’ and comprised fruit trees planted in crop fields, with a boundary of multi-purpose trees and integrated soil and water conservation measures. Sixty four agroforestry plots belonging to 43 households were surveyed in 2010/11 and interviews were held with both adopting and non-adopting farmers. Beyond retention, a quarter of adopters had expanded the practice on to additional areas of land and some diffusion to initially non-adopting farmers had also occurred. Adopters were found to have modified the practice to suit their own objectives, capabilities and constraints, highlighting that adoption is more than a simple binary choice. The study demonstrates the importance of external support for adoption of agroforestry. The intervention was not, however, especially pro-poor with adoption occurring disproportionately among relatively wealthier households with larger landholdings. Where poorer households adopted, this tended to occur later. Participation was entirely voluntary and, by 2011, conversion of suitable farmland to agroforestry had reached 18 %; while beneficial to individual adopters, this patchy coverage arguably limits the potential for enhanced ecosystem service provision at landscape-scale

Surface-impedance approach solves problems with the thermal Casimir force between real metals

The surface impedance approach to the description of the thermal Casimir effect in the case of real metals is elaborated starting from the free energy of oscillators. The Lifshitz formula expressed in terms of the dielectric permittivity depending only on frequency is shown to be inapplicable in the frequency region where a real current may arise leading to Joule heating of the metal. The standard concept of a fluctuating electromagnetic field on such frequencies meets difficulties when used as a model for the zero-point oscillations or thermal photons in the thermal equilibrium inside metals. Instead, the surface impedance permits not to consider the electromagnetic oscillations inside the metal but taking the realistic material properties into account by means of the effective boundary condition. An independent derivation of the Lifshitz-type formulas for the Casimir free energy and force between two metal plates is presented within the impedance approach. It is shown that they are free of the contradictions with thermodynamics which are specific to the usual Lifshitz formula for dielectrics in combination with the Drude model. We demonstrate that in the impedance approach the zero-frequency contribution is uniquely fixed by the form of impedance function and does not need any of the ad hoc prescriptions intensively discussed in the recent literature. As an example, the computations of the Casimir free energy between two gold plates are performed at different separations and temperatures. It is argued that the surface impedance approach lays a reliable framework for the future measurements of the thermal Casimir force.Comment: 21 pages, 3 figures, to appear in Phys. Rev.

Smeared phase transition in a three-dimensional Ising model with planar defects: Monte-Carlo simulations

We present results of large-scale Monte Carlo simulations for a three-dimensional Ising model with short range interactions and planar defects, i.e., disorder perfectly correlated in two dimensions. We show that the phase transition in this system is smeared, i.e., there is no single critical temperature, but different parts of the system order at different temperatures. This is caused by effects similar to but stronger than Griffiths phenomena. In an infinite-size sample there is an exponentially small but finite probability to find an arbitrary large region devoid of impurities. Such a rare region can develop true long-range order while the bulk system is still in the disordered phase. We compute the thermodynamic magnetization and its finite-size effects, the local magnetization, and the probability distribution of the ordering temperatures for different samples. Our Monte-Carlo results are in good agreement with a recent theory based on extremal statistics.Comment: 9 pages, 6 eps figures, final version as publishe

Measurement of open charm production in dd+Au collisions at sNN\sqrt{s_{NN}}=200 GeV

We present the first comprehensive measurement of $D^{0}, D^{+}, D^{*+}$ and their charge conjugate states at mid-rapidity in $d$+Au collisions at $\sqrt{s_{_{NN}}}$=200 GeV using the STAR TPC. The directly measured open charm multiplicity distribution covers a broad transverse momentum region of 0$<p_{T}<11$ GeV/$c$. The measured $dN/dy$ at mid-rapidity for $D^{0}$ is $0.0265\pm 0.0036 (stat.) \pm 0.0071 (syst.)$ and the measured $D^{*+}/D^{0}$ and $D^{+}/D^{0}$ ratios are approximately equal with a magnitude of $0.40\pm 0.09(stat.) \pm 0.13(syst.)$. The total $c\bar{c}$ cross section per nucleon-nucleon collision extracted from this study is $1.18 \pm 0.21(stat.) \pm 0.39(syst.)$mb. The direct measurement of open charm production is consistent with STAR single electron data. This cross section is higher than expectations from PYTHIA and other pQCD calculations. The measured $p_{T}$ distribution is harder than the pQCD prediction using the Peterson fragmentation function.Comment: Quark Matter 2004 Proceeding

Partonic flow and ϕ\phi-meson production in Au+Au collisions at sNN\sqrt{s_{NN}} = 200 GeV

We present first measurements of the $\phi$-meson elliptic flow ($v_{2}(p_{T})$) and high statistics $p_{T}$ distributions for different centralities from $\sqrt{s_{NN}}$ = 200 GeV Au+Au collisions at RHIC. In minimum bias collisions the $v_{2}$ of the $\phi$ meson is consistent with the trend observed for mesons. The ratio of the yields of the $\Omega$ to those of the $\phi$ as a function of transverse momentum is consistent with a model based on the recombination of thermal $s$ quarks up to $p_{T}\sim 4$ GeV/$c$, but disagrees at higher momenta. The nuclear modification factor ($R_{CP}$) of $\phi$ follows the trend observed in the $K^{0}_{S}$ mesons rather than in $\Lambda$ baryons, supporting baryon-meson scaling. Since $\phi$-mesons are made via coalescence of seemingly thermalized $s$ quarks in central Au+Au collisions, the observations imply hot and dense matter with partonic collectivity has been formed at RHIC.Comment: 6 pages, 4 figures, submit to PR

Azimuthal anisotropy: the higher harmonics

We report the first observations of the fourth harmonic (v_4) in the azimuthal distribution of particles at RHIC. The measurement was done taking advantage of the large elliptic flow generated at RHIC. The integrated v_4 is about a factor of 10 smaller than v_2. For the sixth (v_6) and eighth (v_8) harmonics upper limits on the magnitudes are reported.Comment: 4 pages, 6 figures, contribution to the Quark Matter 2004 proceeding