Role of Layering Oscillations at Liquid Metal Surfaces in Bulk Recrystallization and Surface Melting

The contrasting melting behavior of different surface orientations in metals can be explained in terms of a repulsive or attractive effective interaction between the solid-liquid and the liquid-vapor interface. We show how a crucial part of this interaction originates from the layering effects near the liquid metal surface. Its sign depends on the relative tuning of layering oscillations to the crystal interplanar spacing, thus explaining the orientational dependence. Molecular dynamics recrystallization simulations of Au surfaces provide direct and quantitative evidence of this phenomenon.Comment: 10 pages (RevTeX) plus 3 figures (PostScript

Synthesis of block copolymers of PS-b-PMMA employing control radical polymerization

Se estudió la síntesis de copolímeros bloque de poli (estireno) y poli (metil metacrilato) (PSb -PMMA) empleando polimerización radicalaria por transferencia atómica (ATRP). Se realizaron distintos experimentos variando las relaciones molares de monómero, ligando e iniciador para determinar su influencia en la síntesis de copolímeros PSb -PMMA con masas molares determinadas y estructura homogénea. Los polímeros sintetizados se caracterizaron químicamente por espectroscopia infrarroja con Transformada de Fourier (FTIR) y cromatografía por exclusión de tamaños (SEC), empleando un detector de índice de refracción. Se obtuvieron los copolímeros bloque propuestos, con un buen control de su estructura macromolecular (Mw/Mn < 1,90)Fil: Hanazumi, Vivina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Iarlori, Franco. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Ressia, Jorge Aníbal. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Comisión de Investigaciones Científicas de la Provincia de Buenos Aires; ArgentinaFil: Ciolino, Andrés Eduardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Valles, Enrique Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentin

The ARCADE Raman Lidar System for the Cherenkov Telescope Array

The Cherenkov Telescope Array (CTA) is the next generation of ground-based very high energy gamma-ray instruments; the facility will be organized in two arrays, one for each hemisphere. The atmospheric calibration of the CTA telescopes is a critical task. The atmosphere affects the measured Cherenkov yield in several ways: the air-shower development itself, the variation of the Cherenkov angle with altitude, the loss of photons due to scattering and absorption of Cherenkov light out of the camera field-of-view and the scattering of photons into the camera. In this scenario, aerosols are the most variable atmospheric component in time and space and therefore need a continuous monitoring. Lidars are among the most used instruments in atmospheric physics to measure the aerosol attenuation profiles of light. The ARCADE Lidar system is a very compact and portable Raman Lidar system that has been built within the FIRB 2010 grant and is currently taking data in Lamar, Colorado. The ARCADE Lidar is proposed to operate at the CTA sites with the goal of making a first survey of the aerosol conditions of the selected site and to use it as a calibrated benchmark for the other Lidars that will be installed on site. It is proposed for CTA that the ARCADE Lidar will be first upgraded in Italy and then tested in parallel to a Lidar of the EARLINET network in L'Aquila. Upgrades include the addition of the water vapour Raman channel to the receiver and the use of new and better performing electronics. It is proposed that the upgraded system will travel to and characterize both CTA sites, starting from the first selected site in 2016

Surface structure in simple liquid metals. An orbital free first principles study

Molecular dynamics simulations of the liquid-vapour interfaces in simple sp-bonded liquid metals have been performed using first principles methods. Results are presented for liquid Li, Na, K, Rb, Cs, Mg, Ba, Al, Tl, and Si at thermodynamic conditions near their respective triple points, for samples of 2000 particles in a slab geometry. The longitudinal ionic density profiles exhibit a pronounced stratification extending several atomic diameters into the bulk, which is a feature already experimentally observed in liquid K, Ga, In, Sn and Hg. The wavelength of the ionic oscillations shows a good scaling with the radii of the associated Wigner-Seitz spheres. The structural rearrangements at the interface are analyzed in terms of the transverse pair correlation function, the coordination number and the bond-angle distribution between nearest neighbors. The valence electronic density profile also shows (weaker) oscillations whose phase, with respect to those of the ionic profile, changes from opposite phase in the alkalis to almost in-phase for Si.Comment: 16 pages, 18 figures, 5 tables. Submitted to Phys. Rev.

Large scale quantum simulations: C_60 impacts on a semiconducting surface

We present tight binding molecular dynamics simulations of C_60 collisions on the reconstructed diamond(111) surface, carried out with an O(N) method and with cells containing 1140 atoms. The results of our simulations are in very good agreement with experiments performed under the same impact conditions. Furthermore our calculations provide a detailed characterization of the microscopic processes occuring during the collision, and allow the identification of three impact regimes, as a function of the fullerene incident energy. Finally, the study of the reactivity between the cluster and the surface gives insight into the deposition mechanisms of C_60 on semiconducting substrates

Surface layering of liquids: The role of surface tension

Recent measurements show that the free surfaces of liquid metals and alloys are always layered, regardless of composition and surface tension; a result supported by three decades of simulations and theory. Recent theoretical work claims, however, that at low enough temperatures the free surfaces of all liquids should become layered, unless preempted by bulk freezing. Using x-ray reflectivity and diffuse scattering measurements we show that there is no observable surface-induced layering in water at T=298 K, thus highlighting a fundamental difference between dielectric and metallic liquids. The implications of this result for the question in the title are discussed.Comment: 5 pages, 4 figures, to appear in Phys. Rev. B. 69 (2004

Microscopic mechanism for mechanical polishing of diamond (110) surfaces

Mechanically induced degradation of diamond, as occurs during polishing, is studied using total--energy pseudopotential calculations. The strong asymmetry in the rate of polishing between different directions on the diamond (110) surface is explained in terms of an atomistic mechanism for nano--groove formation. The post--polishing surface morphology and the nature of the polishing residue predicted by this mechanism are consistent with experimental evidence.Comment: 4 pages, 5 figure

The Air Microwave Yield (AMY) experiment - A laboratory measurement of the microwave emission from extensive air showers

The AMY experiment aims to measure the microwave bremsstrahlung radiation (MBR) emitted by air-showers secondary electrons accelerating in collisions with neutral molecules of the atmosphere. The measurements are performed using a beam of 510 MeV electrons at the Beam Test Facility (BTF) of Frascati INFN National Laboratories. The goal of the AMY experiment is to measure in laboratory conditions the yield and the spectrum of the GHz emission in the frequency range between 1 and 20 GHz. The final purpose is to characterise the process to be used in a next generation detectors of ultra-high energy cosmic rays. A description of the experimental setup and the first results are presented.Comment: 3 pages -- EPS-HEP'13 European Physical Society Conference on High Energy Physics (July, 18-24, 2013) at Stockholm, Swede

Why Airbnb is impacting housing affordability and how urban planners could respond to it

LAUREA MAGISTRALELa tesi inizia con una panoramica di cosa significa economia della condivisione e quali conseguenze possono avere a livello urbano. L'argomento principale della mia tesi è la piattaforma di home-sharing Airbnb, argomento molto discusso attualmente nelle città in cui la piattaforma ha raggiunto maggior successo, principalmente per l'impatto che sta avendo sulla routine quotidiana dei cittadini, sulla turbolenza delle città e sull'aumento dei prezzi degli affitti. Il mio tentativo è stato quello di andare più a fondo nella situazione di Airbnb a Milano, tuttavia la mancanza di dati mi ha fatto basare principalmente su precedenti esperienze in altre città e sollevato la domanda sulla necessità di affrontare tali problemi dall'amministrazione locale.The thesis starts with an overview of what sharing economy means and which consequences can have on a urban level. The main focus is the home-sharing platform Airbnb, which is on the contemporary debate across the main cities where it operates for the impact that is having on the citizen's daily routin, touristification of cities and the rise of rental prices. My attempt was to go deeper in the Airbnb's situation in Milan, however the lack of data made me base mostly on previous experiences in other cities and raised the question about the need of addressing those issues by the local administration