OH yields from the CH3CO+O-2 reaction using an internal standard

Laser flash photolysis of CH3C(O)OH at 248 nm was used to create equal zero time yields of CH3CO and OH. The absolute OH yield from the CH3CO + O2 (+M) reaction was determined by following the OH temporal profile using the zero time OH concentration as an internal standard. The OH yield from CH3CO + O2 (+M) was observed to decrease with increasing pressure with an extrapolated zero pressure yield close to unity (1.1 ± 0.2, quoted uncertainties correspond to 95% confidence limits). The results are in quantitative agreement with those obtained from 248 nm acetone photolysis in the presence of O2

The Distances of SNR W41 and overlapping HII regions

New HI images from the VLA Galactic Plane Survey show prominent absorption features associated with the supernovae remnant G23.3-0.3 (SNR W41). We highlight the HI absorption spectra and the $^{13}$CO emission spectra of eight small regions on the face of W41, including four HII regions, three non-thermal emission regions and one unclassified region. The maximum velocity of absorption for W41 is 78$\pm$2 km/s and the CO cloud at radial velocity 95$\pm$5 km/s is behind W41. Because an extended TeV source, a diffuse X-ray enhancement and a large molecular cloud at radial velocity 77$\pm$5 km/s are also projected at the center of W41, these yield the kinematic distance of 3.9 to 4.5 kpc for W41. For HII regions, our analyses reveal that both G23.42-0.21 and G23.07+0.25 are at the far kinematic distances ($\sim$9.9 kpc and $\sim$ 10.6 kpc respectively) of their recombination-line velocities (103$\pm$0.5 km/s and 89.6$\pm$2.1 km/s respectively), G23.07-0.37 is at the near kinematic distance (4.4$\pm$0.3 kpc) of its recombination-line velocity (82.7$\pm$2.0 km/s), and G23.27-0.27 is probably at the near kinematic distance (4.1$\pm$0.3 kpc) of its recombination-line velocity (76.1$\pm$0.6 km/s).Comment: 11 pages, 3 figs., 2 tables, accepted by A

Interaction of laser generated ultrasonic waves with wedge-shaped samples

Wedge-shaped samples can be used as a model of acoustic interactions with samples ranging from ocean wedges, to angled defects such as rolling contact fatigue, to thickness measurements of samples with non-parallel faces. We present work on laser generated ultrasonic waves on metal samples; one can measure the dominant Rayleigh-wave mode, but longitudinal and shear waves are also generated. We present calculations, models, and measurements giving the dependence of the arrival times and amplitudes of these modes on the wedge apex angle and the separation of generation and detection points, and hence give a measure of the wedge characteristics

Fundamental Aspects of the ISM Fractality

The ubiquitous clumpy state of the ISM raises a fundamental and open problem of physics, which is the correct statistical treatment of systems dominated by long range interactions. A simple solvable hierarchical model is presented which explains why systems dominated by gravity prefer to adopt a fractal dimension around 2 or less, like the cold ISM and large scale structures. This has direct relation with the general transparency, or blackness, of the Universe.Comment: 6 pages, LaTeX2e, crckapb macro, no figure, uuencoded compressed tar file. To be published in the proceeedings of the "Dust-Morphology" conference, Johannesburg, 22-26 January, 1996, D. Block (ed.), (Kluwer Dordrecht

The Interstellar Medium and Star Formation in Edge-On Galaxies. I. NGC 891

We analyze images of BIMA 12CO (J = 1 --> 0), VLA HI, and Spitzer 3.6 and 24 \mum emission toward the edge-on galaxy NGC 891 and derive the radial and vertical distributions of gas and the radial distributions of stellar mass and recent star formation. We describe our method of deriving radial profiles for edge-on galaxies, assuming circular motion, and verify basic relationships between star formation rate and gas and stellar content, and between the molecular-to-atomic ratio and hydrostatic midplane pressure, that have been found in other galaxy samples. The Schmidt law index we find for the total gas (H2 + H I) is 0.85\pm0.55, but the Schmidt law provides a poor description of the SFR in comparison to a model that includes the influence of the stellar disk. Using our measurements of the thickness of the gas disk and the assumption of hydrostatic equilibrium, we estimate volume densities and pressures as a function of radius and height in order to test the importance of pressure in controlling the {\rho}H2/{\rho}HI ratio. The gas pressure in two dimensions P(r, z) using constant velocity dispersion does not seem to correlate with the {\rho}H2/{\rho}HI ratio, but the pressure using varying velocity dispersion appears to correlate with the ratio. We test the importance of gravitational instability in determining the sites of massive star formation, and find that the Q parameter using a radially varying gas velocity dispersion is consistent with self-regulation (Q - 1) over a large part of the disk.Comment: 19 pages, 19 figures, accepted for publication in A

The Galactic IMF: origin in the combined mass distribution functions of dust grains and gas clouds

We present here a theoretical model to account for the stellar IMF as a result of the composite behaviour of the gas and dust distribution functions. Each of these has previously been modelled and the models tested against observations. The model presented here implies a relation between the characteristic size of the dust grains and the characteristic final mass of the stars formed within the clouds containing the grains, folded with the relation between the mass of a gas cloud and the characteristic mass of the stars formed within it. The physical effects of dust grain size are due to equilibrium relations between the efficiency of grains in cooling the clouds, which is a falling function of grain size, and the efficiency of grains in catalyzing the production of molecular hydrogen, which is a rising function of grain size. We show that folding in the effects of grain distribution can yield a reasonable quantitative account of the IMF, while gas cloud mass function alone cannot do so.Comment: 8 pages, 6 figures, MNRAS accepted for publicatio

Ram-pressure stripped molecular gas in the Virgo spiral galaxy NGC 4522

IRAM 30m 12CO(1-0) and 12CO(2-1) HERA observations are presented for the ram-pressure stripped Virgo spiral galaxy NGC 4522. The CO emission is detected in the galactic disk and the extraplanar gas. The extraplanar CO emission follows the morphology of the atomic gas closely but is less extended. The CO maxima do not appear to correspond to regions where there is peak massive star formation as probed by Halpha emission. The presence of molecular gas is a necessary but not sufficient condition for star formation. Compared to the disk gas, the molecular fraction of the extraplanar gas is 30% lower and the star formation efficiency of the extraplanar gas is about 3 times lower. The comparison with an existing dynamical model extended by a recipe for distinguishing between atomic and molecular gas shows that a significant part of the gas is stripped in the form of overdense arm-like structures. It is argued that the molecular fraction depends on the square root of the total large-scale density. Based on the combination of the CO/Halpha and an analytical model, the total gas density is estimated to be about 4 times lower than that of the galactic disk. Molecules and stars form within this dense gas according to the same laws as in the galactic disk, i.e. they mainly depend on the total large-scale gas density. Star formation proceeds where the local large-scale gas density is highest. Given the complex 3D morphology this does not correspond to the peaks in the surface density. In the absence of a confining gravitational potential, the stripped gas arms will most probably disperse; i.e. the density of the gas will decrease and star formation will cease.Comment: 11 pages, 15 figures, A&A accepted for publicatio