Impact de pollutions ponctuelles sur les phytocénoses des rivières acides à neutres du Limousin (Massif Central, France)

L'impact des pollutions ponctuelles sur les phytocénoses aquatiques est étudié autour des rejets de 12 agglomérations dont 9 sont équipées d'une station d'épuration. Un échantillonnage systématique avec segmentation du cours d'eau autour de chaque rejet est réalisé. Sur chaque secteur, des relevés de végétation sont pratiqués au niveau de faciès d'écoulements homogènes dont on caractérise le milieu physique parallèlement à une analyse physicochimique de l'eau.L'ensemble des rejets provoque globalement une élévation de la conductivité, des teneurs en ammonium, nitrates et orthophosphates.Cela ce traduit par la régression de la phytocénose à Callitriche hamulata et Myriophyllum alterniflorum, par le développement de Ranunculus peltatus, Callitriche platycarpa et d'espèces cryptogames telles que Leptodyctium riparium, ou Melosira sp.Une Analyse en Composantes Principales menée sur l'ensemble des données permet d'opposer des phytocénoses propres aux secteurs amonts (Scapania undulata, Chiloscyphus polyanthus) à d'autres situées au niveau de rejets (Callitriche platycarpa, Leptodictyum riparium, Melosira sp.,).Une Analyse Canonique de Correspondances valide le déterminisme de la qualité physicochimique de l'eau sur la végétation. La conductivité, les teneurs en ammonium, nitrates et orthophosphates deviennent prépondérants par rapport aux facteurs du milieu physique classiquement discriminants dans l'installation des phytocénoses dans les rivières limousines.The impact of located pollution on aquatic phytocénoses is studied around 12 cities discharge. Nine of them are fitted out purification plant.The sampling method is based on consecutive segments from upstream to downstream. On each sector, vegetation records are realized in homogeneous water runoff facies, which are characterized by physical factors as well as water value measures.The whole discharge leads globally to an increase of conductivity, ammonium amount, nitrates and orthophosphates. The consequence of that is a decrease of Callitriche hamulata and Myriophyllum alterniflorum phytocénoses, a development of Ranunculus peltatus, Callitriche platycarpa and cryptogams species like Leptodictyum riparium or Melosira sp.A Component Principal Analysis applied on data, distinguishes phytocénoses belonging to upstream sectors (Scapania undulata, Chiloscyphus polyanthus) from the ones of discharges (Callitriche platycarpa, Leptodictyum riparium, Melosira sp.).A Canonical Correspondence Analysis validates the impact of physico-chemical water quality on vegetation. Conductivity, ammonium amount, nitrates and orthophosphates become more preponderant in comparison with physical environments usually discriminant for phytocénoses installation in Limousin rivers

Variability of aerosol vertical distribution in the Sahel

In this work, we have studied the seasonal and inter-annual variability of the aerosol vertical distribution over Sahelian Africa for the years 2006, 2007 and 2008, characterizing the different kind of aerosols present in the atmosphere in terms of their optical properties observed by ground-based and satellite instruments, and their sources searched for by using trajectory analysis. This study combines data acquired by three ground-based micro lidar systems located in Banizoumbou (Niger), Cinzana (Mali) and M'Bour (Senegal) in the framework of the African Monsoon Multidisciplinary Analysis (AMMA), by the AEROsol RObotic NETwork (AERONET) sun-photometers and by the space-based Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) onboard the CALIPSO satellite (Cloud-Aerosol Lidar and Infrared Pathfinder Observations). <br><br> During winter, the lower levels air masses arriving in the Sahelian region come mainly from North, North-West and from the Atlantic area, while in the upper troposphere air flow generally originates from West Africa, crossing a region characterized by the presence of large biomass burning sources. The sites of Cinzana, Banizoumbou and M'Bour, along a transect of aerosol transport from East to West, are in fact under the influence of tropical biomass burning aerosol emission during the dry season, as revealed by the seasonal pattern of the aerosol optical properties, and by back-trajectory studies. <br><br> Aerosol produced by biomass burning are observed mainly during the dry season and are confined in the upper layers of the atmosphere. This is particularly evident for 2006, which was characterized by a large presence of biomass burning aerosols in all the three sites. <br><br> Biomass burning aerosol is also observed during spring when air masses originating from North and East Africa pass over sparse biomass burning sources, and during summer when biomass burning aerosol is transported from the southern part of the continent by the monsoon flow. <br><br> During summer months, the entire Sahelian region is under the influence of Saharan dust aerosols: the air masses in low levels arrive from West Africa crossing the Sahara desert or from the Southern Hemisphere crossing the Guinea Gulf while in the upper layers air masses still originate from North, North-East. The maximum of the desert dust activity is observed in this period which is characterized by large AOD (above 0.2) and backscattering values. It also corresponds to a maximum in the extension of the aerosol vertical distribution (up to 6 km of altitude). In correspondence, a progressive cleaning up of the lowermost layers of the atmosphere is occurring, especially evident in the Banizoumbou and Cinzana sites. <br><br> Summer is in fact characterized by extensive and fast convective phenomena. <br><br> Lidar profiles show at times large dust events loading the atmosphere with aerosol from the ground up to 6 km of altitude. These events are characterized by large total attenuated backscattering values, and alternate with very clear profiles, sometimes separated by only a few hours, indicative of fast removal processes occurring, likely due to intense convective and rain activity. <br><br> The inter-annual variability in the three year monitoring period is not very significant. An analysis of the aerosol transport pathways, aiming at detecting the main source regions, revealed that air originated from the Saharan desert is present all year long and it is observed in the lower levels of the atmosphere at the beginning and at the end of the year. In the central part of the year it extends upward and the lower levels are less affected by air masses from Saharan desert when the monsoon flow carries air from the Guinea Gulf and the Southern Hemisphere inland

Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments

International audienceReplacing fossil fuels with energy sources and carriers that are sustainable, environmentally benign, and affordable is amongst the most pressing challenges for future socio-economic development. To that goal, hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting, if driven by green electricity, would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research, also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first-principles calculations and machine learning. In addition, a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field's physical chemists, materials scientists and engineers, as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains

PHOTONS/AERONET sunphotometer network overview. Description – Activities - Results

Fourteenth International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics celebrado del 24 al 30 de junio de 2007 en Buryatia, Russia

Climatological aspects of the optical properties of fine/coarse mode aerosol mixtures

Aerosol mixtures composed of coarse mode desert dust combined with fine mode combustion generated aerosols (from fossil fuel and biomass burning sources) were investigated at three locations that are in and/or downwind of major global aerosol emission source regions. Multiyear monitoring data at Aerosol Robotic Network sites in Beijing (central eastern China), Kanpur (Indo-Gangetic Plain, northern India), and Ilorin (Nigeria, Sudanian zone of West Africa) were utilized to study the climatological characteristics of aerosol optical properties. Multiyear climatological averages of spectral single scattering albedo (SSA) versus fine mode fraction (FMF) of aerosol optical depth at 675 nm at all three sites exhibited relatively linear trends up to similar to 50% FMF. This suggests the possibility that external linear mixing of both fine and coarse mode components (weighted by FMF) dominates the SSA variation, where the SSA of each component remains relatively constant for this range of FMF only. However, it is likely that a combination of other factors is also involved in determining the dynamics of SSA as a function of FMF, such as fine mode particles adhering to coarse mode dust. The spectral variation of the climatological averaged aerosol absorption optical depth (AAOD) was nearly linear in logarithmic coordinates over the wavelength range of 440-870 nm for both the Kanpur and Ilorin sites. However, at two sites in China (Beijing and Xianghe), a distinct nonlinearity in spectral AAOD in logarithmic space was observed, suggesting the possibility of anomalously strong absorption in coarse mode aerosols increasing the 870 nm AAOD

Temporal variability of mineral dust concentrations over West Africa: analyses of a pluriannual monitoring from the AMMA Sahelian Dust Transect

Abstract. The Sahelian belt is known to be a region where atmospheric levels of suspended mineral dust are among the highest observed on Earth. In the framework of the AMMA (African Monsoon Multidisciplinary Analysis) International Program, a transect of 3 ground based stations, the "Sahelian Dust Transect" (SDT), has been deployed in order to obtain quantitative information on the mineral dust content and its variability over the Sahel. The three stations, namely Banizoumbou (Niger), Cinzana (Mali) and M'Bour (Senegal) are aligned around 14° N along the east-westward main pathway of the Saharan and Sahelian dust towards the Atlantic Ocean. We discuss data collected between January 2006 and December 2008 to investigate the main characteristics of the mineral dust concentration over West Africa and their connection with the dominant meteorological situations. The succession of the dry season during which the Sahel is under the influence of the dry Harmattan wind and the wet season induced by the entrance of the monsoon flow is clearly identified from the basic meteorological parameters (air temperature and moisture, wind direction). Atmospheric dust concentrations at the three stations exhibit a similar seasonal cycle, with a monthly maximum during the dry season and a minimum occurring during the rainy season, indicating that the general pattern of dust concentration is similar at regional scale. This seasonal cycle of the dust concentrations is not phased with the seasonal cycle of surface wind velocity locally measured, suggesting that it is mainly controlled by Saharan dust transport. Local dust emissions induced by strong surface winds are responsible for the occurrence of extremely high daily concentrations observed at the beginning of the rainy season. A decrease in the dust concentration is observed when moving from Niger to Senegal. </jats:p

De Novo

International audienceA proof-of-concept library of pyrrolodiazepinone small molecules was designed based on the Bip-Lys-Tyr motif found in a recently described modulator of the urotensinergic system. Solid-phase synthesis provided 13 analogues, which were tested for their ability to modulate selectively and differentially the potency (EC50) and efficacy (E(max)) of hUII and URP ex vivo in a rat aortic ring bioassay. Notably, at 14 μM, pyrrolodiazepinone R-4a inhibited completely hUII-induced contractions and increased URP-associated vasoconstriction. Pyrrolodiazepinone R-4a represents, to the best of our knowledge, a first-in-class small molecule that exerts a probe-dependent effect on hUII and URP biological activities and proves that UT modulators of the urotensin II receptor (UT) can be rationally designed. The importance of the UT system in the pathogenesis and progression of cardiovascular diseases highlights the utility of pyrrolodiazepinones such as R-4a, which exhibit promising potential as tools for differentiating the respective roles, signaling pathways, and phenotypic outcomes of UII and URP in the UT system

Saharan dust impacts on air quality: What are the potential health risks in West Africa?

Despite the proximity of the Sahara, very few studies about dust impact on air quality and human health have been conducted in West Africa. The lack of data is a major constraint on our understanding of the impacts on human health in this area. We analyzed PM10 concentrations and horizontal visibility recorded in four West African stations. The pollution levels often exceed the standards defined by many countries/regulatory authorities and have been associated with serious health risks outside Africa. Over the Sahelian stations, 45.6% of the days between November 2006 and March 2007 were likely to impact human health and the studied Sudanian population was exposed to potential health effects every 5 days