The interparticle interaction and crossover in critical lines on field-temperature plane in Pr0.5_{0.5}Sr0.5_{0.5}MnO3_{3} nanoparticles

The magnetic properties and the effects of interparticle interaction on it have been studied in nanoparticles of half doped Pr$_{0.5}$Sr$_{0.5}$MnO$_{3}$. Three samples consisting of nanoparticles of different average particle sizes are synthesized to render the variation in interparticle interaction. Though all the samples crystallize in the same structure to that of their bulk compound, the low temperature ferromagnetic-antiferromagnetic transition, which is present in bulk compound, is not evident in the nanoparticles. Linear as well as nonlinear ac susceptibility coupled with dc magnetic measurements have shown the superparamagnetic behavior of these nanoparticles where the blocking temperature increases with the increasing particle size. Presence of interparticle interaction is confirmed from the temperature variation of coercive field and the analysis of frequency dependent ac susceptibility. We have identified the nature of this interaction to be of dipolar type, and show that its strength decreases with the increasing particle size. The effect of this dipolar interaction on magnetic properties is intriguing as the compounds exhibit crossover from de Almeida-Thouless to Gabay-Toulouse like critical lines on field-temperature plane above their respective interaction field. In agreement with theoretical prediction, we infer that this crossover is induced by the unidirectional anisotropy arising from interparticle interaction, and this is confirmed from the presence of exchange bias phenomenon.Comment: To appear in Phys. Rev.

Spin Disorder and Magnetic Anisotropy in Fe3O4 Nanoparticles

We have studied the magnetic behavior of dextran-coated magnetite (Fe$_3$O$_4$) nanoparticles with median particle size \left=8 $nm$. Magnetization curves and in-field M\"ossbauer spectroscopy measurements showed that the magnetic moment $M_S$ of the particles was much smaller than the bulk material. However, we found no evidence of magnetic irreversibility or non-saturating behavior at high fields, usually associated to spin canting. The values of magnetic anisotropy $K_{eff}$ from different techniques indicate that surface or shape contributions are negligible. It is proposed that these particles have bulk-like ferrimagnetic structure with ordered A and B sublattices, but nearly compensated magnetic moments. The dependence of the blocking temperature with frequency and applied fields, $T_B(H,\omega)$, suggests that the observed non-monotonic behavior is governed by the strength of interparticle interactions.Comment: 11 pages, 7 figures, 3 Table

Large Coercivity in Nanostructured Rare-earth-free MnxGa Films

The magnetic hysteresis of MnxGa films exhibit remarkably large coercive fields as high as 2.5 T when fabricated with nanoscale particles of a suitable size and orientation. This coercivity is an order of magnitude larger than in well-ordered epitaxial film counterparts and bulk materials. The enhanced coercivity is attributed to the combination of large magnetocrystalline anisotropy and ~ 50 nm size nanoparticles. The large coercivity is also replicated in the electrical properties through the anomalous Hall effect. The magnitude of the coercivity approaches that found in rare-earth magnets, making them attractive for rare-earth-free magnet applications

Fretting wear of Ti(CxNy) PVD coatings under variable environmental conditions

Fretting wear as a specific type of degradation is defined as an oscillatory motion at small amplitude between two nominally stationary solid bodies in mutual contact. Under external stresses the interface is being damaged by debris generation and its successive ejections outside the contact area. A potential protection against fretting damage by means of hard coatings is being offered by different surface engineering techniques. For this study TiC, TiN and TiCN hard coatings manufactured by a PVD method have been selected and tested against smooth polycrystalline alumina ball. A fretting test programme has been carried out at the frequency of 5Hz, 100N normal load, 100µm displacement amplitude and at three values of a relative humidity: 10, 50 and 90% at 295-298K temperature. It turned out that the intensity of wear process was depending not only on loading conditions but on environmental ones as well. A significant impact of RH on wear rate and friction behaviour of the coatings under investigation has been observed. Two different damage mechanisms have been identified and related to the phenomena of debris oxidation and debris adhesion to the counterbody surface. In the latter case the debris deposited onto the surface of the alumina ball lead to a change of stress distribution at the interface and as a result to accelerated wear. In this work experiments with variable relative humidity increasing from 10% to 90% within 1 a single fretting test have been completed. It follows from these experiments that there exists an intermediate value of the RH at which the friction coefficient changes rapidly. Finally a dissipated energy approach has been applied in the work in order to quantify and compare fretting wear rates of different hard coatings

Micromagnetic simulations of sweep-rate dependent coercivity in perpendicular recording media

The results of micromagnetic simulations are presented which examine the impact of thermal fluctuations on sweep rate dependent coercivities of both single-layer and exchange-coupled-composite (ECC) perpendicular magnetic recording media. M-H loops are calculated at four temperatures and sweep rates spanning five decades with fields applied normal to the plane and at 45 degrees. The impact of interactions between grains is evaluated. The results indicate a significantly weaker sweep-rate dependence for ECC media suggesting more robustness to long-term thermal effects. Fitting the modeled results to Sharrock-like scaling proposed by Feng and Visscher [J. Appl. Phys. 95, 7043 (2004)] is successful only in the case of single-layer media with the field normal to the plane.Comment: 7 pages, 14 figure

Fairness as “appropriate impartiality” and the problem of the self-serving bias

Garrett Cullity contends that fairness is appropriate impartiality (See Cullity (2004) Chapters 8 and 10 and Cullity (2008)). Cullity deploys his account of fairness as a means of limiting the extreme moral demand to make sacrifices in order to aid others that was posed by Peter Singer in his seminal article ‘Famine, Affluence and Morality’. My paper is founded upon the combination of (1) the observation that the idea that fairness consists in appropriate impartiality is very vague and (2) the fact that psychological studies show the self-serving bias is especially likely to infect one’s judgements when the ideas involved are vague. I argue that Cullity’s solution to extreme moral demandingness is threatened by these findings. I then comment on whether some other theories of fairness are vulnerable to the same objection

Electric-field-induced phase transition of <001> oriented Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals

oriented 0.7Pb(Mg1/3Nb2/3)O3-0.3PbTiO3 single crystals were poled under different electric fields, i.e. Epoling=4 kV/cm and Epoling=13 kV/cm. In addition to the temperature-dependent dielectric constant measurement, X-ray diffraction was also used to identify the poling-induced phase transitions. Results showed that the phase transition significantly depends on the poling intensity. A weaker field (Epoling=4 kV/cm) can overcome the effect of random internal field to perform the phase transition from rhombohedral ferroelectric state with short range ordering (microdomain) FESRO to rhombohedral ferroelectric state with long range ordering (macrodomain) FElRO. But the rhombohedral ferroelectric to tetragonal ferroelectric phase transition originating from to polarization rotation can only be induced by a stronger field (Epoling=13 kV/cm). The sample poled at Epoling=4 kV/cm showed higher piezoelectric constant, d33>1500 pC/N, than the sample poled at Epoling=13 kV/cm.Comment: 7 pages, 2 figure

Stoichiometry control of sputtered CuCl thin films: Influence on ultraviolet emission properties

We demonstrate that the chemical composition of the sputtered CuCl thin films could be finely controlled by adjusting the bias to the substrate. The films deposited without any intentional bias were Cl rich (CuCl1+x), a bias of −22 V yielded stoichiometric CuCl, and a further increase in the negative bias resulted in Cl deficient films (CuCl1−x). The crystalline and optical properties were found to be associated with the chemical composition. Cl rich films showed a deep level green emission at around 515 nm in addition to ultraviolet (UV) excitonic emission. The stoichiometric films have higher optical quality, exhibiting a sharp UV emission at around 385 nm at room temperature, compared to nonstoichiometric samples. Visible luminescence related to deep level defects was not observed in the stoichiometric films. Changes in energy of the flux from the target and the subsequent ion bombardment on the substrate surface are correlated with the variations in chemical composition and their impact on the film microstructure and UV emission

Spinel ferrite nanocrystals embedded inside ZnO: magnetic, electronic and magneto-transport properties

In this paper we show that spinel ferrite nanocrystals (NiFe2O4, and CoFe2O4) can be texturally embedded inside a ZnO matrix by ion implantation and post-annealing. The two kinds of ferrites show different magnetic properties, e.g. coercivity and magnetization. Anomalous Hall effect and positive magnetoresistance have been observed. Our study suggests a ferrimagnet/semiconductor hybrid system for potential applications in magneto-electronics. This hybrid system can be tuned by selecting different transition metal ions (from Mn to Zn) to obtain various magnetic and electronic properties.Comment: 12 pages, 14 figs. accepted for publication at PR

Formation of iron nitride thin films with Al and Ti additives

In this work we investigate the process of iron nitride (Fe-N) phase formation using 2 at.% Al or 2 at.% Ti as additives. The samples were prepared with a magnetron sputtering technique using different amount of nitrogen during the deposition process. The nitrogen partial pressure (\pn) was varied between 0-50% (rest Argon) and the targets of pure Fe, [Fe+Ti] and [Fe+Al] were sputtered. The addition of small amount of Ti or Al results in improved soft-magnetic properties when sputtered using \pn $\leq$ 10\p. When \pn is increased to 50\p non-magnetic Fe-N phases are formed. We found that iron mononitride (FeN) phases (N at% $\sim$50) are formed with Al or Ti addition at \pn =50% whereas in absence of such addition \eFeN phases (N\pat$\sim$30) are formed. It was found that the overall nitrogen content can be increased significantly with Al or Ti additions. On the basis of obtained result we propose a mechanism describing formation of Fe-N phases Al and Ti additives.Comment: 9 Pages, 7 Figure