AC impedance study of degradation of porous nickel battery electrodes

AC impedance spectra of porous nickel battery electrodes were recorded periodically during charge/discharge cycling in concentrated KOH solution at various temperatures. A transmission line model (TLM) was adopted to represent the impedance of the porous electrodes, and various model parameters were adjusted in a curve fitting routine to reproduce the experimental impedances. Degradation processes were deduced from changes in model parameters with electrode cycling time. In developing the TLM, impedance spectra of planar (nonporous) electrodes were used to represent the pore wall and backing plate interfacial impedances. These data were measured over a range of potentials and temperatures, and an equivalent circuit model was adopted to represent the planar electrode data. Cyclic voltammetry was used to study the characteristics of the oxygen evolution reaction on planar nickel electrodes during charging, since oxygen evolution can affect battery electrode charging efficiency and ultimately electrode cycle life if the overpotential for oxygen evolution is sufficiently low

Ecological equivalence: a realistic assumption for niche theory as a testable alternative to neutral theory

Hubbell's 2001 neutral theory unifies biodiversity and biogeography by modelling steady-state distributions of species richness and abundances across spatio-temporal scales. Accurate predictions have issued from its core premise that all species have identical vital rates. Yet no ecologist believes that species are identical in reality. Here I explain this paradox in terms of the ecological equivalence that species must achieve at their coexistence equilibrium, defined by zero net fitness for all regardless of intrinsic differences between them. I show that the distinction of realised from intrinsic vital rates is crucial to evaluating community resilience. An analysis of competitive interactions reveals how zero-sum patterns of abundance emerge for species with contrasting life-history traits as for identical species. I develop a stochastic model to simulate community assembly from a random drift of invasions sustaining the dynamics of recruitment following deaths and extinctions. Species are allocated identical intrinsic vital rates for neutral dynamics, or random intrinsic vital rates and competitive abilities for niche dynamics either on a continuous scale or between dominant-fugitive extremes. Resulting communities have steady-state distributions of the same type for more or less extremely differentiated species as for identical species. All produce negatively skewed log-normal distributions of species abundance, zero-sum relationships of total abundance to area, and Arrhenius relationships of species to area. Intrinsically identical species nevertheless support fewer total individuals, because their densities impact as strongly on each other as on themselves. Truly neutral communities have measurably lower abundance/area and higher species/abundance ratios. Neutral scenarios can be parameterized as null hypotheses for testing competitive release, which is a sure signal of niche dynamics. Ignoring the true strength of interactions between and within species risks a substantial misrepresentation of community resilience to habitat los

Waves on the surface of the Orion molecular cloud

Massive stars influence their parental molecular cloud, and it has long been suspected that the development of hydrodynamical instabilities can compress or fragment the cloud. Identifying such instabilities has proved difficult. It has been suggested that elongated structures (such as the `pillars of creation') and other shapes arise because of instabilities, but alternative explanations are available. One key signature of an instability is a wave-like structure in the gas, which has hitherto not been seen. Here we report the presence of `waves' at the surface of the Orion molecular cloud near where massive stars are forming. The waves seem to be a Kelvin-Helmholtz instability that arises during the expansion of the nebula as gas heated and ionized by massive stars is blown over pre-existing molecular gas.Comment: Preprint of publication in Natur

Tracing the Bipolar Outflow from Orion Source I

Using CARMA, we imaged the 87 GHz SiO v=0 J=2-1 line toward Orion-KL with 0.45 arcsec angular resolution. The maps indicate that radio source I drives a bipolar outflow into the surrounding molecular cloud along a NE--SW axis, in agreement with the model of Greenhill et al. (2004). The extended high velocity outflow from Orion-KL appears to be a continuation of this compact outflow. High velocity gas extends farthest along a NW--SE axis, suggesting that the outflow direction changes on time scales of a few hundred years.Comment: 4 pages, 4 figures; accepted for publication in Ap J Letter

First results from CARMA: the combined array for research in millimeter-wave astronomy

The Combined Array for Research in Millimeter-wave Astronomy (CARMA) comprises the millimeter-wave antennas of the Owens Valley Radio Observatory (OVRO), the Berkeley-Illinois-Maryland Association (BIMA) Array, and the new Sunyaev-Zel'dovich Array (SZA). CARMA consists of six 10.4-m, nine 6.1-m, and eventually eight 3.5-m diameter antennas on a site at elevation 2200 m in the Inyo Mountains near Bishop, California. The array will be operated by an association that includes the California Institute of Technology and the Universities of California (Berkeley), Chicago, Illinois (Urbana-Champaign), and Maryland. Observations will be supported at wavelengths of 1 cm, 3 mm, and 1.3 mm, on baselines from 5 m to 2 km. The initial correlator will use field programmable gate array (FPGA) technology to provide all single-polarization cross-correlations on two subarrays of 8 and 15 antennas with a total bandwidth of 8 GHz on the sky. The next generation correlator will correlate the full 23-antenna array in both polarizations. CARMA will support student training, technology development, and front-line astronomical research in a wide range of fields including cosmology, galaxy formation and evolution, star and planet formation, stellar evolution, chemistry of the interstellar medium, and within the Solar System, comets, planets, and the Sun. Commissioning of CARMA began in August 2005, after relocation of the antennas to the new site. The first science observations commenced in April 2006

Signatures of Young Star Formation Activity Within Two Parsecs of Sgr A*

We present radio and infrared observations indicating on-going star formation activity inside the $\sim2-5$ pc circumnuclear ring at the Galactic center. Collectively these measurements suggest a continued disk-based mode of on-going star formation has taken place near Sgr A* over the last few million years. First, VLA observations with spatial resolution 2.17$"\times0.81"$ reveal 13 water masers, several of which have multiple velocity components. The presence of interstellar water masers suggests gas densities that are sufficient for self-gravity to overcome the tidal shear of the 4$\times10^6$ \msol\, black hole. Second, SED modeling of stellar sources indicate massive YSO candidates interior to the molecular ring, supporting in-situ star formation near Sgr A* and appear to show a distribution similar to that of the counter-rotating disks of $\sim$100 OB stars orbiting Sgr A*. Some YSO candidates (e.g., IRS~5) have bow shock structures suggesting that they have have gaseous disks that are phototoevaporated and photoionized by the strong radiation field. Third, we detect clumps of SiO (2-1) and (5-4) line emission in the ring based on CARMA and SMA observations. The FWHM and luminosity of the SiO emission is consistent with shocked protostellar outflows. Fourth, two linear ionized features with an extent of $\sim0.8$ pc show blue and redshifted velocities between $+50$ and $-40$ \kms, suggesting protostellar jet driven outflows with mass loss rates of $\sim5\times10^{-5}$ solar mass yr$^{-1}$. Finally, we present the imprint of radio dark clouds at 44 GHz, representing a reservoir of molecular gas that feeds star formation activity close to Sgr A*.Comment: 38 pages, 10 figures, ApJ (in press

Gravitational redshift of galaxies in clusters as predicted by general relativity

The theoretical framework of cosmology is mainly defined by gravity, of which general relativity is the current model. Recent tests of general relativity within the \Lambda Cold Dark Matter (CDM) model have found a concordance between predictions and the observations of the growth rate and clustering of the cosmic web. General relativity has not hitherto been tested on cosmological scales independent of the assumptions of the \Lambda CDM model. Here we report observation of the gravitational redshift of light coming from galaxies in clusters at the 99 per cent confidence level, based upon archival data. The measurement agrees with the predictions of general relativity and its modification created to explain cosmic acceleration without the need for dark energy (f(R) theory), but is inconsistent with alternative models designed to avoid the presence of dark matter.Comment: Published in Nature issued on 29 September 2011. This version includes the Letter published there as well as the Supplementary Information. 23 pages, 7 figure

Separation of quadrupolar and magnetic contributions to spin-lattice relaxation in the case of a single isotope

We present a NMR pulse double-irradiation method which allows one to separate magnetic from quadrupolar contributions in the spin-lattice relaxation. The pulse sequence fully saturates one transition while another is observed. In the presence of a Delta m = 2 quadrupolar contribution, the intensity of the observed line is altered compared to a standard spin-echo experiment. We calculated analytically this intensity change for spins I=1, 3/2, 5/2, thus providing a quantitative analysis of the experimental results. Since the pulse sequence we used takes care of the absorbed radio-frequency power, no problems due to heating arise. The method is especially suited when only one NMR sensitive isotope is available. Different cross-checks were performed to prove the reliability of the obtained results. The applicability of this method is demonstrated by a study of the plane oxygen 17O (I = 5/2) in the high-temperature superconductor YBa_2Cu_4O_8: the 17O spin-lattice relaxation rate consists of magnetic as well as quadrupolar contributions.Comment: 7 pages, 6 figure

CARMA Large Area Star Formation Survey: Observational Analysis of Filaments in the Serpens South Molecular Cloud

We present the N2H+(J=1-0) map of the Serpens South molecular cloud obtained as part of the CARMA Large Area Star Formation Survey (CLASSy). The observations cover 250 square arcminutes and fully sample structures from 3000 AU to 3 pc with a velocity resolution of 0.16 km/s, and they can be used to constrain the origin and evolution of molecular cloud filaments. The spatial distribution of the N2H+ emission is characterized by long filaments that resemble those observed in the dust continuum emission by Herschel. However, the gas filaments are typically narrower such that, in some cases, two or three quasi-parallel N2H+ filaments comprise a single observed dust continuum filament. The difference between the dust and gas filament widths casts doubt on Herschel ability to resolve the Serpens South filaments. Some molecular filaments show velocity gradients along their major axis, and two are characterized by a steep velocity gradient in the direction perpendicular to the filament axis. The observed velocity gradient along one of these filaments was previously postulated as evidence for mass infall toward the central cluster, but these kind of gradients can be interpreted as projection of large-scale turbulence.Comment: 12 pages, 4 figures, published in ApJL (July 2014

VLT/FLAMES-ARGUS observations of stellar wind--ISM cloud interactions in NGC 6357

We present optical/near-IR IFU observations of a gas pillar in the Galactic HII region NGC 6357 containing the young open star cluster Pismis 24. These observations have allowed us to examined in detail the gas conditions of the strong wind-clump interactions taking place on its surface. We identify the presence of a narrow (~20 km/s) and broad (50-150 km/s) component to the H_alpha emission line, where the broadest broad component widths are found in a region that follows the shape of the eastern pillar edge. These connections have allowed us to firmly associate the broad component with emission from ionized gas within turbulent mixing layers on the pillar's surface set up by the shear flows of the O-star winds from the cluster. We discuss the implications of our findings in terms of the broad emission line component that is increasingly found in extragalactic starburst environments. Although the broad line widths found here are narrower, we conclude that the mechanisms producing both must be the same. The difference in line widths may result from the lower total mechanical wind energy produced by the O stars in Pismis 24 compared to that from a typical young massive star cluster found in a starburst galaxy. The pillar's edge is also clearly defined by dense (<5000 cm^-3), hot (>20000 K), and excited (via [NII]/H_a and [SII]/H_a ratios) gas conditions, implying the presence of a D-type ionization front propagating into the pillar surface. Although there must be both photoevaporation outflows produced by the ionization front, and mass-loss through mechanical ablation, we see no evidence for any significant bulk gas motions on or around the pillar. We postulate that the evaporated/ablated gas must be rapidly heated before being entrained.Comment: 9 pages, 5 figures (3 colour). Accepted for publication in MNRA