Measuring stellar oscillations using equivalent widths of absorption lines

Kjeldsen et al. (1995, AJ 109, 1313; astro-ph/9411016) have developed a new technique for measuring stellar oscillations and claimed a detection in the G subgiant eta Boo. The technique involves monitoring temperature fluctuations in a star via their effect on the equivalent width of Balmer lines. In this paper we use synthetic stellar spectra to investigate the temperature dependence of the Balmer lines, Ca II, Fe I, the Mg b feature and the G~band. We present a list of target stars likely to show solar-like oscillations and estimate their expected amplitudes. We also show that centre-to-limb variations in Balmer-line profiles allow one to detect oscillation modes with l<=4, which accounts for the detection by Kjeldsen et al. of modes with degree l=3 in integrated sunlight.Comment: MNRAS (accepted); 7 pages, LaTeX with necessary style file and PostScript figures in a single uuencoded Z-compressed .tar fil

Finding the First Stars: The Hamburg/ESO Objective Prism Survey

We report on a search for extremely metal-poor ([Fe/H]<-3.0) turnoff stars in the Hamburg/ESO objective prism survey (HES). Metal-poor stars are selected by automatic spectral classification. Extensive simulations show that the selection efficiency for turnoff stars of [Fe/H]25% at B<16.5. Since the HES is more than 1 mag deeper than the HK survey of Beers et al. (1992), the HES offers the possibility to efficiently increase the total number of metal-poor stars by at least a factor of 4.Comment: To appear in: Proceedings of ESO/MPA conference "The First Stars". 2 pages, 1 figur

Mechanical effect of van der Waals interactions observed in real time in an ultracold Rydberg gas

We present time-resolved spectroscopic measurements of Rydberg-Rydberg interactions in an ultracold gas, revealing the pair dynamics induced by long-range van der Waals interactions between the atoms. By detuning the excitation laser, a specific pair distribution is prepared. Penning ionization on a microsecond timescale serves as a probe for the pair dynamics under the influence of the attractive long-range forces. Comparison with a Monte Carlo model not only explains all spectroscopic features but also gives quantitative information about the interaction potentials. The results imply that the interaction-induced ionization rate can be influenced by the excitation laser. Surprisingly, interaction-induced ionization is also observed for Rydberg states with purely repulsive interactions

A New Type of Stereoselectivity in Baeyer–Villiger Reactions: Access to E- and Z-Olefins

A new concept for accessing configurationally defined trisubstituted olefins has been developed. Starting from a common ketone precursor of the type 4-ethylidenecyclohexanone, Baeyer–Villiger monooxygenases are employed as catalysts in diastereoselective Baeyer–Villiger reactions leading to the corresponding E- or Z-configurated lactones. Wild-type cyclohexanone monooxygenase (CHMO) as catalyst delivers the E-isomers and a directed evolution mutant the opposite Z-isomers. Subsequent transition metal-catalyzed chemical transformations of a key product containing a vinyl bromide moiety provide a variety of different trisubstituted E- or Z-olefins. A model based on QM/MM sheds light on the origin of this unusual type of diastereoselectivity. In contrast to this biocatalytic approach, traditional Baeyer–Villiger reagents such as m-CPBA fail to show any selectivity, 1:1 mixtures of E- and Z-olefins being formed

Use of soil moisture information in yield models

There are no author-identified significant results in this report

NLTE effects on Fe I/II in the atmospheres of FGK stars and application to abundance analysis of their spectra

We describe the first results from our project aimed at large-scale calculations of NLTE abundance corrections for important astrophysical atoms and ions. In this paper, the focus is on Fe which is a proxy of stellar metallicity and is commonly used to derive effective temperature and gravity. We present a small grid of NLTE abundance corrections for Fe I lines and discuss how NLTE effects influence determination of effective temperature, surface gravity, and metallicity for late-type stars.Comment: 6 pages, to be published in IOP The Journal of Physics: Conference Series, proceedings of the Workshop: 'Stellar Atmospheres in the Gaia Era: Quantitative Spectroscopy and Comparative Spectrum Modelling', Brussels, June 201

Measurement of the electric dipole moments for transitions to rubidium Rydberg states via Autler-Townes splitting

We present the direct measurements of electric-dipole moments for $5P_{3/2}\to nD_{5/2}$ transitions with $20<n<48$ for Rubidium atoms. The measurements were performed in an ultracold sample via observation of the Autler-Townes splitting in a three-level ladder scheme, commonly used for 2-photon excitation of Rydberg states. To the best of our knowledge, this is the first systematic measurement of the electric dipole moments for transitions from low excited states of rubidium to Rydberg states. Due to its simplicity and versatility, this method can be easily extended to other transitions and other atomic species with little constraints. Good agreement of the experimental results with theory proves the reliability of the measurement method.Comment: 12 pages, 6 figures; figure 6 replaced with correct versio