The emergence of nanocellulose aerogels in CO2 adsorption

Mitigating the effect of climate change toward a sustainable development is one of the main challenges of our century. The emission of greenhouse gases, especially carbon dioxide (CO2), is a leading cause of the global warming crisis. To address this issue, various sustainable strategies have been formulated for CO2 capture. Renewable nanocellulose aerogels have risen as a highly attractive candidate for CO2 capture thanks to their porous and surface-tunable nature. Nanocellulose offer distinctive characteristics, including significant aspect ratios, exceptional biodegradability, lightweight nature, and the ability for chemical modification due to the abundant presence of hydroxyl groups. In this review, recent research studies on nanocellulose-based aerogels designed for CO2 absorption have been highlighted. The state-of-the-art of nanocellulose-based aerogel has been thoroughly assessed, including their synthesis, drying methods, and characterization techniques. Additionally, discussions were held about the mechanisms of CO2 adsorption, the effects of the porous structure, surface functionalization, and experimental parameters. Ultimately, this synthesis review provides an overview of the achieved adsorption rates using nanocellulose-based aerogels and outlines potential improvements that could lead to optimal adsorption rates. Overall, this research holds significant promise for tackling the challenges of climate change and contributing to a more sustainable future.The authors would like to acknowledge the financial support of the Basque Government (project IT1498-22) and the University of the Basque Country (PIF21/52)

Functionalization of Cellulose Nanocrystals in Choline Lactate Ionic Liquid

Cellulose nanocrystals (CNCs) are valuable nanomaterials obtained from renewable resources. Their properties make them suitable for a wide range of applications, including polymer reinforcement. However, due to their highly hydrophilic character, it is necessary to modify their surface with non-polar functional groups before their incorporation into a hydrophobic polymer matrix. In this work, cellulose nanocrystals were modified using a silane coupling agent and choline lactate, an ionic liquid derived from renewable resources, as a reaction medium. Modified cellulose nanocrystals were characterized by infrared spectroscopy, showing new peaks associated to the modification performed. X-ray diffraction was used to analyze the crystalline structure of functionalized cellulose nanocrystals and to optimize the amount of silane for functionalization. Poly(lactic acid) (PLA) nanocomposites containing 1 wt % of functionalized cellulose nanocrystals were prepared. They were characterized by field-emission scanning electron microscopy (FE-SEM) and mechanical tests. The use of choline lactate as reaction media has been shown to be an alternative method for the dispersion and silanization of the cellulose nanocrystals without the addition of an external catalyst.Financial support from the European Commission (FP7 Program, ECLIPSE project FP7-NMP-280786) is gratefully acknowledged

Nectandra grandiflora By-Products Obtained by Alternative Extraction Methods as a Source of Phytochemicals with Antioxidant and Antifungal Properties

Nectandra grandiflora Nees (Lauraceae) is a Brazilian native tree recognized by its durable wood and the antioxidant compounds of its leaves. Taking into account that the forest industry offers the opportunity to recover active compounds from its residues and by-products, this study identifies and underlines the potential of natural products from Nectandra grandiflora that can add value to the forest exploitation. This study shows the effect of three different extraction methods: conventional (CE), ultrasound-assisted (UAE) and microwave-assisted (MAE) on Nectandra grandiflora leaf extracts (NGLE) chemical yields, phenolic and flavonoid composition, physical characteristics as well as antioxidant and antifungal properties. Results indicate that CE achieves the highest extraction phytochemical yield (22.16%), but with similar chemical composition to that obtained by UAE and MAE. Moreover, CE also provided a superior thermal stability of NGLE. The phenolic composition of NGLE was confirmed firstly, by colorimetric assays and infrared spectra and then by chromatographic analysis, in which quercetin-3-O-rhamnoside was detected as the major compound (57.75–65.14%). Furthermore, the antioxidant capacity of the NGLE was not altered by the extraction methods, finding a high radical inhibition in all NGLE (>80% at 2 mg/mL). Regarding the antifungal activity, there was observed that NGLE possess effective bioactive compounds, which inhibit the Aspergillus niger growth.This research was financially supported by the Department of Education of Basque Government (IT1008-16) and by Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq process 454447/2014-0). Authors would like to thanks the CNPq for research grants received by Berta Maria Heinzmann, Ph.D. scholarship (process 203796/2014-4) granted to Daniela Thomas da Silva and the Basque Government for scholarship of young researchers training granted to Rene Herrera

Cellulose Nanocrystal Membranes as Excipients for Drug Delivery Systems

In this work, cellulose nanocrystals (CNCs) were obtained from flax fibers by an acid hydrolysis assisted by sonochemistry in order to reduce reaction times. The cavitation inducted during hydrolysis resulted in CNC with uniform shapes, and thus further pretreatments into the cellulose are not required. The obtained CNC exhibited a homogeneous morphology and high crystallinity, as well as typical values for surface charge. Additionally, CNC membranes were developed from CNC solution to evaluation as a drug delivery system by the incorporation of a model drug. The drug delivery studies were carried out using chlorhexidine (CHX) as a drug and the antimicrobial efficiency of the CNC membrane loaded with CHX was examined against Gram-positive bacteria Staphylococcus aureus (S. Aureus). The release of CHX from the CNC membranes is determined by UV-Vis. The obtaining methodology of the membranes proved to be simple, and these early studies showed a potential use in antibiotic drug delivery systems due to the release kinetics and the satisfactory antimicrobial activity.The authors would like to acknowledge the Department of Education, Universities and Investigation of the Basque Government (project IT1008-16), the Federal Agency for Support and Evaluation of Graduate Education (CAPES) through process BEX 8710/14-7, the Mexican Council of Science and Technology (CONACyT) through scholarship 216178 and theBrazilian National Council for Scientific and Technological Development for financial support through CNPq (# 482251/2013-1) for financially supporting this work. The authors also thank Maite Insausti and Oihane Arriortua for their kind help and support with Nanosizer and SGIker of the University of the Basque Country UPV/EHU for technical and human support provided with XRD, NMR and AFM characterizations and Altair Faes of the Regional Center of Oncology of the Federal University of Pelotas (UFPel) for the use of the equipment Eldorado 78

Evaluation of different lignocellulosic raw materials as potential alternative feedstocks in biorefinery processes

In the present work several alternative lignocellulosic materials have been classified according to their type and origin, and chemically characterized in order to propose their proper exploitation as biorefinery feedstock. In addition, different fractionation processes have been applied to some of these raw materials with the purpose of evaluating their efficiency and applicability for different feedstocks. The yield of each applied treatment has been determined according to the delignification ratio and the carbohydrate dissolution degree achieved. The characterisation results indicated that different lignocellulosic feedstocks could be treated together in Biorefinery processes because of similar compositions and fractionation behaviour. Furthermore, different pretreatments could be applied for the achievement of specific fractionation results, depending on the desired solid or liquid by-product to obtain

Triethyl Citrate (TEC) as a Dispersing Aid in Polylactic Acid/Chitin Nanocomposites Prepared via Liquid-Assisted Extrusion

The production of fully bio-based and biodegradable nanocomposites has gained attention during recent years due to environmental reasons; however, the production of these nanocomposites on the large-scale is challenging. Polylactic acid/chitin nanocrystal (PLA/ChNC) nanocomposites with triethyl citrate (TEC) at varied concentrations (2.5, 5.0, and 7.5 wt %) were prepared using liquid-assisted extrusion. The goal was to find the minimum amount of the TEC plasticizer needed to enhance the ChNC dispersion. The microscopy study showed that the dispersion and distribution of the ChNC into PLA improved with the increasing TEC content. Hence, the nanocomposite with the highest plasticizer content (7.5 wt %) showed the highest optical transparency and improved thermal and mechanical properties compared with its counterpart without the ChNC. Gel permeation chromatography confirmed that the water and ethanol used during the extrusion did not degrade PLA. Further, Fourier transform infrared spectroscopy showed improved interaction between PLA and ChNC through hydrogen bonding when TEC was added. All results confirmed that the plasticizer plays an important role as a dispersing aid in the processing of PLA/ChNC nanocomposites.The authors gratefully acknowledge Bio4Energy, Kempestiftelserna, and Wallenberg Wood Science Center (WWSC) in Sweden for the financial support of this work. We also thank Deodato Radic at the Pontifical Catholic University of Chile (PUC) for supplying the bleached chitin powder and Dipl.-Ing Daniel Schwendemann at IWK University of Applied Sciences Eastern, Switzerland for kindly providing the polylactic acid. The authors also acknowledge Maxime Noel for the technical support with the FTIR and Ph.D. candidate Shiyu Geng for the HR-SEM images

Nanocellulose-based sensors in medical/clinical applications: The state-of-the-art review

In recent years, the considerable importance of healthcare and the indispensable appeal of curative issues, particularly the diagnosis of diseases, have propelled the invention of sensing platforms. With the development of nanotechnology, the integration of nanomaterials in such platforms has been much focused on, boosting their functionality in many fields. In this direction, there has been rapid growth in the utilisation of nanocellulose in sensors with medical applications. Indeed, this natural nanomaterial benefits from striking features, such as biocompatibility, cytocompatibility and low toxicity, as well as unprecedented physical and chemical properties. In this review, different classifications of nanocellulose-based sensors (biosensors, chemical and physical sensors), alongside some subcategories manufactured for health monitoring, stand out. Moreover, the types of nanocellulose and their roles in such sensors are discussed.This work was supported by the University of the Basque Country (Training of Researcher Staff, PIF 20/197)

Reuse of ultrafiltration permeate as a preliminary step in the pulp and paper production

Permeate is a part of the stream generated in the ultrafiltration process. This stream could be utilized due to its composition in low molecular compounds. In this work, different combinations have been used to study the use of ultrafiltration permeate as a preliminary step in the pulp and paper production. The results showed that the use of ultrafiltration permeate, obtained from the black liquor of olive tree pruning fractionation, as cooking liquor instead of the preliminary step is an excellent option, with yields of 35.6% and physical properties of paper sheets similar to those obtained by the use of green traditional liquor (0.599 kN/g burst index and 1.076 mNm2/g tear index)

Acid Hydrolysis of Almond Shells in a Biphasic Reaction System: Obtaining of Purified Hemicellulosic Monosaccharides in a Single Step

The aim of this work is to comprehend the biphasic reaction systems through another perspective; the simultaneous purification and production of carbohydrates during the pretreatment of biomass. A dilute acid hydrolysis of almond shells in a 2-Methyltetrahydrofuran/H2O system was optimised to maximise the obtaining of hemicellulose-derived monosaccharides with the minimum formation of degradation products. The optimised conditions of the biphasic reaction system, which produced 205.3 g hemicellulose-derived monosaccharides/Kg almond shells, were replicated in a monophasic reaction system to assess the benefits of the biphasic reaction systems. The latest system allowed the removal of 85.3% of the furans generated during the dilute acid hydrolysis, creating antioxidant extract, together with the catalysis of the hydrolysis of the hemicelluloses in a 20%. Therefore, the proposed process could become a promising method to purify carbohydrates with an environmentally friendly procedure that allowed the obtaining of multiple added-value products in a single step.Dr. I. Dávila would like acknowledge to the University of the Basque Country (UPV/EHU) for the financial support (Grant reference No. DOCREC19/47

Electrochemical Activity of Lignin Based Composite Membranes

Our society’s most pressing challenges, like high CO2 emission and the constant battle against energy poverty, require a clean and easier solution to store and utilize the renewable energy resources. However, recent electrochemical components are expensive and harmful to the environment, which restricts their widespread deployment. This study proposes an easy method to synthesize and fabricate composite membranes with abundantly found biomass lignin polymer to replace conventional costly and toxic electrode materials. Easier manipulation of lignin within the polymeric matrix could provide the improved composite to enhance its electrochemical activity. Our major focus is to activate the quinone moiety via oxidation in the polymeric mixture using a strong ionic acid. The physico-chemical and electrochemical characterizations of two different lignins within varied polymeric mixture compositions have been carried out to confirm that the redox properties of pure unmodified lignin could be achieved via intrinsic mutual sharing of the structural properties and intercross linkage leading to improved integrity and redox activity/conductivity.This research was funded by the Basque Government (project IT1008-16)