98 research outputs found
{2-[(2,6-Difluorophenoxy)methyl]phenyl}boronic acid
The planes of the two benzene rings in the molecule of the title compound, C13H11BF2O3, form a dihedral angle of 76.06 (3)°; the C—O—C—C torsion angle characterizing the conformation of the central link of the molecule is −79.20 (1)°. The dihydroxyboron group is not coplanar with the benzene ring bonded to the B atom; one of the C—C—B—O torsion angles is 32.39 (2)°. One of the OH groups of the boronic acid fragment is engaged in an intramolecular hydrogen bond, whereas the second OH group participates in intermolecular hydrogen bonding, which leads to the formation of centrosymmetric dimers
[3-Bromo-2-(3-fluorobenzyloxy)phenyl]boronic acid
In the title compound, C13H11BBrFO3, the dioxyboron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intramolecular O—H⋯O hydrogen-bonding interaction. The second OH group is involved in intermolecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio
(2-Butoxyphenyl)boronic acid
The title compound, 2-(CH3CH2CH2CH2O)C6H4B(OH)2, exists as a centrosymmetric hydrogen-bonded dimer. Dimers are linked via C—H⋯π and π–π [with closest C⋯C contact of 3.540 (3) Å] interactions to produce a two-dimensional array
2,4-Dibutoxyphenylboronic acid
In the crystal of the title compound, C14H23BO4, centrosymmetric dimers linked by pairs of O—H⋯O hydrogen bonds occur. The dimers are linked via C—H⋯O contacts, generating a two-dimensional array parallel to (12). These are interconnected by weak O—H⋯O hydrogen bonds, as well as C—H⋯π interactions
(2,4-Dipropoxyphenyl)boronic acid
In the crystal, the title compound, C12H19BO4, exists as a centrosymmetric O—H⋯O hydrogen-bonded dimer. Dimers are linked via C—H⋯O hydrogen bonds, generating an infinite zigzag chain oriented parallel to [11]. The chains are assembled, giving sheets aligned parallel to (21) and interconnected by weak C—H⋯π interactions, producing a three-dimensional network
1,2:3,5-Bis[(4-tert-butylphenyl)boranediyl]-α-d-glucofuranose
The crystal structure of the title compound, C26H34B2O6, comprises two crystallographically independent molecules. In the crystal, the molecules are linked by multiple intermolecular O—H⋯O and C—H⋯O hydrogen bonds into a two-dimensional array
Mesityl(2,4,6-trimethoxyphenyl)borinic acid
In the title molecule, C18H23BO4, the dihedral angle between the least-squares planes of the aromatic rings is 84.88 (3)°. The B atom deviates by 0.202 (1) Å from the least-squares plane of the mesityl ring. All of the methoxy groups are approximately coplanar with the 2,4,6-trimethoxyphenyl ring, whereas the BOH group is twisted with respect to it by 19.5°. The borinic OH group is engaged in an intramolecular O—H⋯O hydrogen bond with one of ortho-methoxy groups. The molecular structure is stabilized by weak C—H⋯O contacts. In the crystal, molecules are linked by weak C—H⋯O and C—H⋯π interactions, generating a three-dimensional network
Ammonia–triphenylborane
The asymmetric unit of the title compound, C18H18BN or (C6H5)3B·NH3, comprises two crystallographically independent but virtually identical molecules. Molecules of one type are linked with each other by N—H⋯π interactions, generating an infinite column aligned along the b-axis direction. The columns of different types of molecules are interconnected by C—H⋯π interactions, producing a three-dimensional array
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