Optical electronics

The development of an optical diode consisting of a metal-dielectric-metal junction in which the high-speed electric conduction process occurs due to quantum mechanical electron tunneling across the dielectric barrier is briefly reviewed. Potential applications of the diode are discussed

High pressure gas laser technology for atmospheric remote sensing

The development of a fixed frequency chirp-free and highly stable intense pulsed laser made for Doppler wind velocity measurements with accurate ranging is described. Energy extraction from a high pressure CO2 laser at a tunable single mode frequency is also examined

Photoexcitation of lasers and chemical reactions for NASA missions: A theoretical study

The possibility of obtaining CW laser oscillation by optical pumping in the infrared at an elevated gas pressure is reviewed. A specific example utilizing a mixture of CO and NO gases is included. The gas pressures considered are in excess of several atmospheres. Laser frequency tuning over a broad region becomes possible at such elevated gas pressures due to collisional broadening of the amplifying transitions. The prior-rate and surprisal analysis are applied to obtain detailed VV and VT rates for CO and NO molecules and the transfer rates in a CO-NO gas mixture. The analysis is capable of giving temperature dependence of the rate constants. Computer estimates of the rates are presented for vibrational levels up to v = 50. The results show that in the high-lying vibrational states the VV transfer rates with Delta nu = 2 become appreciable

Saturation behavior of a Doppler broadened transition involving levels with closely spaced structure

Saturation behavior of Doppler broadened transition involving levels with closely spaced structur

Method and apparatus for stabilizing a gaseous optical maser Patent

Gas laser frequency stabilized by position of mirrors in resonant cavit

Electronic and optical properties of 5-AVA-functionalized BN nanoclusters: A DFT study

We carried out detailed density functional theory (DFT) and time-dependent density functional theory (TD-DFT) calculations upon 5-aminolevulinic acid-functionalized B12N12 and B16N16 nanoclusters with the B3LYP, B3PW91, and PBE methods using the 6-311+G∗∗ basis set. The calculated adsorption energies of 5-aminolevulinic acid with the BN nanoclusters were evaluated at T = 298.15 and 311.15 K in the gaseous and aqueous environments with the B3LYP, B3PW91, and PBE methods. Our results showed that the adsorption of the 5-AVA molecule (NH2 group) with B12N12 is more favorable than-with the B16N16 nanocluster in the gas and solvent phases. It is anticipated that a 5-aminolevulinic acid (5-AVA) drug incorporating BN clusters could find application in drug delivery systems and in biomedical devices. © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2016

Carbon monoxide interactions with pure and doped B₁₁XN₁₂ (X = Mg, Ge, Ga) nano-clusters: a theoretical study

The goal of this investigation was to study a novel sensor for detecting the toxic gas compounds of CO using B₁₁XN₁₂ (X = Ge, Mg, and Ga) nano-clusters in terms of its energetic, geometric, and electronic structure using DFT calculations by the PBE-D method. The reaction of CO gas with these doping atoms results in a weak interaction and an elongation of X-N bond of B₁₁XN₁₂ nano-clusters. After the adsorption of CO gas over the doped positions of B₁₁XN₁₂ nano-cluster, the conductivity of the adsorbent and the atomic charges in some of the nearby B and N atoms around X atoms were dramatically enhanced. These calculations represent the capabilities of the B₁₁XN₁₂ nano-clusters in designing novel materials based on B₁₁XN₁₂ for potential applications in gas sensing. © The Royal Society of Chemistry

Optical and Infrared Masers

Contains reports on one research project

Strong-disorder renormalization-group study of the one-dimensional tight-binding model

We formulate a strong-disorder renormalization-group (SDRG) approach to study the beta function of the tight-binding model in one dimension with both diagonal and off-diagonal disorder for states at the band center. We show that the SDRG method, when used to compute transport properties, yields exact results since it is identical to the transfer matrix method. The beta function is shown to be universal when only off-diagonal disorder is present even though single-parameter scaling is known to be violated. A different single-parameter scaling theory is formulated for this particular (particle-hole symmetric) case. Upon breaking particle-hole symmetry (by adding diagonal disorder), the beta function is shown to crossover from the universal behavior of the particle-hole symmetric case to the conventional non-universal one in agreement with the two-parameter scaling theory. We finally draw an analogy with the random transverse-field Ising chain in the paramagnetic phase. The particle-hole symmetric case corresponds to the critical point of the quantum Ising model while the generic case corresponds to the Griffiths paramagnetic phase.Comment: includes 12 pages, 4 figure

Development of tunable high pressure CO2 laser for lidar measurements of pollutants and wind velocities

The problem of laser energy extraction at a tunable monochromatic frequency from an energetic high pressure CO2 pulsed laser plasma, for application to remote sensing of atmospheric pollutants by Differential Absorption Lidar (DIAL) and of wind velocities by Doppler Lidar, was investigated. The energy extraction principle analyzed is based on transient injection locking (TIL) at a tunable frequency. Several critical experiments for high gain power amplification by TIL are presented