99 research outputs found
The Return of the State? French economic policy under Nicolas Sarkozy
This paper addresses the EU’s influence on the design of market-building objectives and dispute settlement mechanisms in Mercosur and SADC over time. It argues that such influence has had an independent effect on the evolution of regional institutional design that is not reducible to mere functional dynamics, which dominant explanations emphasize. Instead, it suggests that EU influence is best conceived as a process of spurred emulation, according to which major political or economic crises in the regions have led to the increasing emulation of EU arrangements, spurred by the EU’s active involvement in the process. This has, however, neither led to a wholesale copying of EU institutional models nor to the adoption of EU practices, but EU templates have regularly been adapted to fit with policy-makers’ normative convictions, especially their continuing concerns about national sovereignty
Ion-Implanted Li Nuclear Magnetic Resonance in Highly Oriented Pyrolytic Graphite
We report -detected nuclear magnetic resonance of ultra-dilute
Li implanted in highly oriented pyrolytic graphite (HOPG). The
absence of motional narrowing and diffusional spin-lattice relaxation implies
Li is not appreciably mobile up to 400 K, in sharp contrast to the highly
lithiated stage compounds. However, the relaxation is remarkably fast and
persists down to cryogenic temperatures. Ruling out extrinsic paramagnetic
impurities and intrinsic ferromagnetism, we conclude the relaxation is due to
paramagnetic centers correlated with implantation. While the resulting effects
are not consistent with a Kondo impurity, they also differ from free
paramagnetic centers, and we suggest that a resonant scattering approach may
account for much of the observed phenomenology
Nuclear magnetic resonance of ion implanted Li in ZnO
We report on the stability and magnetic state of ion implanted Li in
single crystals of the semiconductor ZnO using -detected nuclear
magnetic resonance. At ultradilute concentrations, the spectra reveal distinct
Li sites from 7.6 to 400 K. Ionized shallow donor interstitial Li is stable
across the entire temperature range, confirming its ability to self-compensate
the acceptor character of its (Zn) substitutional counterpart. Above 300 K,
spin-lattice relaxation indicates the onset of correlated local motion of
interacting defects, and the spectra show a site change transition from
disordered configurations to substitutional. Like the interstitial, the
substitutional shows no resolved hyperfine splitting, indicating it is also
fully ionized above 210 K. The electric field gradient at the interstitial
Li exhibits substantial temperature dependence with a power law typical of
non-cubic metals.Comment: 15 pages and 11 figure
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