53 research outputs found

    Metal-insulator transition and charge ordering in the extended Hubbard model at one-quarter filling

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    We study with exact diagonalization the zero temperature properties of the quarter-filled extended Hubbard model on a square lattice. We find that increasing the ratio of the intersite Coulomb repulsion, VV, to the band width drives the system from a metal to a charge ordered insulator. The evolution of the optical conductivity spectrum with increasing VV is compared to the observed optical conductivity of several layered molecular crystals with the theta and beta'' crystal structures.Comment: 5 pages, 3 figure

    Superconductivity mediated by charge fluctuations in layered molecular crystals

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    We consider the competition between superconducting, charge ordered, and metallic phases in layered molecular crystals with the theta and beta" structures. Applying slave-boson theory to the relevant extended Hubbard model, we show that the superconductivity is mediated by charge fluctuations and the Cooper pairs have d(xy) symmetry. This is in contrast to the kappa-(BEDT-TTF)(2)X family, for which theoretical calculations give superconductivity mediated by spin fluctuations and with d(x)2(-y)2 symmetry. We predict several materials that should become superconducting under pressure

    Structure and Temporal Change of Credit Network between Banks and Large Firms in Japan

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    Credit relationships between commercial banks and quoted firms are studied for the structure and its temporal change from the year 1980 to 2005. At each year, the credit network is regarded as a weighted bipartite graph where edges correspond to the relationships and weights refer to the amounts of loans. Reduction in the supply of credit affects firms as debtor, and failure of a firm influences banks as creditor. To quantify the dependency and influence between banks and firms, we propose to define a set of scores of banks and firms, which can be calculated by solving an eigenvalue problem determined the weight of the credit network. We found that a few largest eigenvalues and corresponding eigenvectors are significant by using a null hypothesis of random bipartite graphs, and that the scores can quantitatively describe the stability or fragility of the credit network during the 25 years

    Concentration Dependence of Dinucleotide Phosphorescence at 77°K

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    A new synthetic route to TTF-vinylogues

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