The dependence of the hydrogen sorption capacity of single-walled carbon nanotubes on the concentration of catalyst

The adsorption of hydrogen on single-walled carbon nanotubes was measured using micro-gravimetric nitrogen and hydrogen adsorption isotherms at 77 K for gas pressures of up to 1 bar (nitrogen) and 12 bar (hydrogen). Results show that surface area and hydrogen uptake depend on the concentration of the iron catalyst used for making the nanotubes. Langmuir fits to the hydrogen uptake curves clearly show two adsorption energies for each sample which we attribute to the groove site for the higher adsorption energy and to the convex tube surface for the lower energy. We also present calculations of the binding energy of hydrogen on these same sites on SWCNTs and confirm that the groove site has a significantly higher (radius-dependent) binding energy than the surface site, consistent with the experimental values. This suggests that the use of the Langmuir model is appropriate to the adsorption of H2 on activated carbons for the temperature and pressure range investigated and could be used as a rapid way of estimating the average tube radius in the sample

Structural and dielectric studies of the phase behaviour of the topological ferroelectric La1-xNdxTaO4

We thank the University of St Andrews and EPSRC (via DTG studentships to CALD and JG) for funding,The layered perovskite LaTaO4 has been prepared in its polar orthorhombic polymorphic form at ambient temperature. Although no structural phase transition is observed in the temperature interval 25° C < T < 500 °C, a very large axial thermal contraction effect is seen, which can be ascribed to an anomalous buckling of the perovskite octahedral layer. The non-polar monoclinic polymorph can be stabilised at ambient temperature by Nd-doping. A composition La0.90Nd0.10TaO4 shows a first-order monoclinic-orthorhombic (non-polar to polar) transition in the region 250° C < T < 350 °C. Dielectric responses are observed at both the above structural events but, despite the ‘topological ferroelectric’ nature of orthorhombic LaTaO4, we have not succeeded in obtaining ferroelectric P–E hysteresis behaviour. Structural relationships in the wider family of AnBnX3n+2 layered perovskites are discussed.Publisher PDFPeer reviewe

Verification of the virtual bandwidth SAR (VB-SAR) scheme for centimetric resolution subsurface imaging from space

This work presents the first experimental demonstration of the virtual bandwidth synthetic aperture radar (VB-SAR) imaging scheme. VB-SAR is a newly-developed subsurface imaging technique which, in stark contrast to traditional close-proximity ground penetrating radar (GPR) schemes, promises imaging from remote standoff platforms such as aircraft and satellites. It specifically exploits the differential interferometric synthetic aperture radar (DInSAR) phase history of a radar wave within a drying soil volume to generate high- resolution vertical maps of the scattering through the soil volume. For this study, a stack of C-band VV polarisation DInSAR images of a sandy soil containing a buried target was collected in the laboratory whilst the soil moisture was varied - firstly during controlled water addition, and then during subsequent drying. The wetting image set established the moisture-phase relationship for the soil, which was then applied to the drying DInSAR image set using the VB-SAR scheme. This allowed retrieval of high resolution VB-SAR imagery with a vertical discrimination of 0.04m from a stack of 1m vertical resolution DInSAR images. This work unequivocally shows that the basic principles of the VB-SAR technique are valid and opens the door to further investigation of this promising technique

Fire Frequency and Time-Since-Fire Effects on the Open-Forest and Woodland Flora of Girraween National Park, South-East Queensland

The effect of recent fire frequency and time-since-fire on plant community composition and species abundance in open-forest and woodland vegetation in Girraween National Park, south-east Queensland, were examined. Cover-abundance data were collected for shrub and vine species in at least ten 400 m2 plots in each of four study areas. Study areas were within one community type and had burnt most recently either four or nine years previously. Variations in fire frequency allowed us to compare areas which had burnt at least three times in the last 25 years with less frequently burnt areas, and also woodlands which experienced a 28-year interfire interval with more frequently burnt areas. While species richness did not differ significantly with either time-since-fire or fire frequency, both these factors affected community composition, fire frequency being the more powerful. Moisture availability also influenced floristics. Of the 67 species found in five or more plots, six were significantly associated with time-since-fire, while 11 showed a significant difference between more and less frequently burnt plots on each of the two fire frequency variables. Most species, however, did not vary in cover-abundance with the fire regime parameters examined. Even those species that showed a marked drop in cover-abundance when exposed to a particular fire regime generally maintained some presence in the community. Six species with the capacity to resprout after fire were considered potentially at risk of local extinction under regimes of frequent fire, while two species were relatively uncommon in long-unburnt areas. Variable fire regimes, which include interfire intervals of at least 15 years, may be necessary for the continuity of all species in the community

Response to comment on "Human-specific gain of function in a developmental enhancer"

Duret and Galtier argue that human-specific sequence divergence and gain of function in the HACNS1 enhancer result from deleterious biased gene conversion (BGC) with no contribution from positive selection. We reinforce our previous conclusion by analyzing hypothesized BGC events genomewide and assessing the effect of recombination rates on human-accelerated conserved noncoding sequence ascertainment. We also provide evidence that AT → GC substitution bias can coexist with positive selection

Nickel aluminum shape memory alloys via molecular dynamics

Shape memory materials are an important class of active materials with a wide range of applications in the aerospace, biomedical, and automobile industries. These materials exhibit the two unique properties of shape memory and superelasticity. Shape memory is the ability to recover its original shape by applying heat after undergoing large deformations. Superelasticity is the ability to undergo large, reversible deformations (up to 10%) that revert back when the load is removed. These special properties originate from a reversible, diffusionless solid-solid phase transformation that occurs between a high temperature austenite phase and a low temperature martensite phase. The development of the martensite microstructure is not well understood; this is especially true in regards to the role of size and mechanical constraints that dominate the properties in nanoscale samples. The goals of this research are to use molecular dynamics (MD) to (1) study the effects of simulation size on the martensite transformation to determine the ultimate limit of miniaturization, (2) to investigate the effects of mechanical constraints on the martensite transformation and resulting microstructure, and (3) to explore the effects of grain size in polycrystalline shape memory alloys. MD is well suited to study the transformation, as it shares a similar time scale with the extremely fast, diffusionless transformation.^ An extensive set of cooling and heating simulations were performed on Ni63Al37 disordered shape memory alloys (SMAs) to determine the effect of system size on the transformation. Simulation cell sizes in the range of 4.2 to 20 nm were studied. We discovered that decreasing system size only resulted in a slight increase of both transformation temperatures. However, the variability of the austenite transformation temperature increased considerably with decreasing simulation cell size, reaching 10% of the mean value for a system size of 10 nm. This variability can impose a fundamental limit on the miniaturization of this class of materials, as the reliability of device performance comes into question. Also, mechanical constraints were applied to force the cell angles to remain 90° in order to emulate the environment of a partially transformed polycrystal where grains are constricted by their neighbors. The mechanical constraints caused the austenite transformation temperature to decrease with decreasing size by up to 50%, and resulted in a two-domain microstructure for system sizes above 4.2 nm in order to accommodate the internal stresses. Finally, large scale MD simulations were done on polycrystalline samples with grain sizes ranging from 2.5 to 20 nm. We found that a critical grain size of 7.5 nm resulted in a minimum in the percent transformation to martensite. Below this critical size, martensite forms at the grain boundaries and the grains are able to rotate via grain boundary sliding to relieve internal stresses. In larger grains, martensite can nucleate and grow within the grains more easily. A uniaxial strain of up to 10% was applied to investigate the stress induced martensite transformation. Larger grains showed considerable work hardening when strained beyond about 2%. Plastic recovery was also calculated by unloading and relaxing at 4 and 10% strain. Samples strained to 10% were generally able to recover about 20-30% of the plastic strain, while samples strained to 4% showed varying amounts of recovery that peaked at 66% for a grain size of 7.5 nm

PARP-3 and APLF function together to accelerate nonhomologous end joining

PARP-3 is a member of the ADP-ribosyl transferase superfamily of unknown function. We show that PARP-3 is stimulated by DNA double-strand breaks (DSBs) in vitro and functions in the same pathway as the poly (ADP-ribose)-binding protein APLF to accelerate chromosomal DNA DSB repair. We implicate PARP-3 in the accumulation of APLF at DSBs and demonstrate that APLF promotes the retention of XRCC4/DNA ligase IV complex in chromatin, suggesting that PARP-3 and APLF accelerate DNA ligation during nonhomologous end-joining (NHEJ). Consistent with this, we show that class switch recombination in Aplf−/− B cells is biased toward microhomology-mediated end-joining, a pathway that operates in the absence of XRCC4/DNA ligase IV, and that the requirement for PARP-3 and APLF for NHEJ is circumvented by overexpression of XRCC4/DNA ligase IV. These data identify molecular roles for PARP-3 and APLF in chromosomal DNA double-strand break repair reactions

Explaining anomalies in SAR and scatterometer soil moisture retrievals from dry soils with sub-surface scattering

This paper presents the results of a laboratory investigation to explain anomalously-high soil moisture estimates observed in retrievals from SAR and scatterometer backscatter, affecting extensive areas of the world associated with arid climates. High resolution C-band tomographic profiling was applied in experiments to understand the mechanisms underlying these anomalous retrievals. The imagery captured unique high-resolution profiles of the variations in the vertical backscattering patterns though a sandy soil with moisture change. The relative strengths of the surface and sub-surface returns were dependent upon both soil moisture and soil structure, incidence-angle, and polarization. Co-polarised returns could be dominated by both surface and sub-surface returns at times, whereas cross-polarised returns were strongly associated with sub-surface features. The work confirms suspicions that anomalous moisture estimates can arise from the presence of sub-surface features. Diversity in polarization and incidence angle may provide sufficient diagnostics to flag and correct these erroneous estimates, allowing their incorporation into global soil moisture productsMorriso

Mapping forest cover and forest cover change with airborne S-band radar

Assessments of forest cover, forest carbon stocks and carbon emissions from deforestation and degradation are increasingly important components of sustainable resource management, for combating biodiversity loss and in climate mitigation policies. Satellite remote sensing provides the only means for mapping global forest cover regularly. However, forest classification with optical data is limited by its insensitivity to three-dimensional canopy structure and cloud cover obscuring many forest regions. Synthetic Aperture Radar (SAR) sensors are increasingly being used to mitigate these problems, mainly in the L-, C- and X-band domains of the electromagnetic spectrum. S-band has not been systematically studied for this purpose. In anticipation of the British built NovaSAR-S satellite mission, this study evaluates the benefits of polarimetric S-band SAR for forest characterisation. The Michigan Microwave Canopy Scattering (MIMICS-I) radiative transfer model is utilised to understand the scattering mechanisms in forest canopies at S-band. The MIMICS-I model reveals strong S-band backscatter sensitivity to the forest canopy in comparison to soil characteristics across all polarisations and incidence angles. Airborne S-band SAR imagery over the temperate mixed forest of Savernake Forest in southern England is analysed for its information content. Based on the modelling results, S-band HH- and VV-polarisation radar backscatter and the Radar Forest Degradation Index (RFDI) are used in a forest/non-forest Maximum Likelihood classification at a spatial resolution of 6 m (70% overall accuracy, κ = 0.41) and 20 m (63% overall accuracy, κ = 0.27). The conclusion is that S-band SAR such as from NovaSAR-S is likely to be suitable for monitoring forest cover and its change