11,025 research outputs found

    Four cytotoxic N4-substituted thiosemicarbazones derived from 2-hydroxynaphthalene-1-carboxaldehyde

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    The X-ray crystal structures are reported of four novel and potentially O,N,S-tridentate donor ligands that demonstrate antitumour activity. These ligands are 1-[(4-methylthiosemicarbazono)methyl]-2-naphthol, C13H13N3OS, (III), 1-[(4-ethylthiosemicarbazono)methyl]-2-naphthol, C14H15N3OS, (IV), 1-[(4-phenylthiosemicarbazono)methyl]-2-naphthol, C18H15N3OS, (V), and 1-[(4,4-dimethylthiosemicarbazono)methyl]-2-naphthol dimethyl sulfoxide solvate, C14H15N3OS.C2H6OS, (VI). These chelators are N4-substituted thiosemicarbazones, each based on the same parent aldehyde, namely 2-zhydroxynaphthalene-1-carboxaldehyde isonicotinoylhydrazone. Conformational variations within this series are discussed in relation to the optimum conformation for metal-ion binding

    The effects of Chern-Simons gravity on bodies orbiting the Earth

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    One of the possible low-energy consequences of string theory is the addition of a Chern-Simons term to the standard Einstein-Hilbert action of general relativity. It can be argued that the quintessence field should couple to this Chern-Simons term, and if so, it drives in the linearized theory a parity-violating interaction between the gravito-electric and gravitomagnetic fields. In this paper, the linearized spacetime for Chern-Simons gravity around a massive spinning body is found to include new modifications to the gravitomagnetic field that have not appeared in previous work. The orbits of test bodies and the precession of gyroscopes in this spacetime are calculated, leading to new constraints on the Chern-Simons parameter space due to current satellite experiments.Comment: 9 pages, 2 figures; minor corrections made; to appear in PR

    Cosmic Shear of the Microwave Background: The Curl Diagnostic

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    Weak-lensing distortions of the cosmic-microwave-background (CMB) temperature and polarization patterns can reveal important clues to the intervening large-scale structure. The effect of lensing is to deflect the primary temperature and polarization signal to slightly different locations on the sky. Deflections due to density fluctuations, gradient-type for the gradient of the projected gravitational potential, give a direct measure of the mass distribution. Curl-type deflections can be induced by, for example, a primordial background of gravitational waves from inflation or by second-order effects related to lensing by density perturbations. Whereas gradient-type deflections are expected to dominate, we show that curl-type deflections can provide a useful test of systematics and serve to indicate the presence of confusing secondary and foreground non-Gaussian signals.Comment: 8 pages, 3 figures; PRD submitte

    Large Extra Dimensions, Sterile neutrinos and Solar Neutrino Data

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    Solar, atmospheric and LSND neutrino oscillation results require a light sterile neutrino, νB\nu_B, which can exist in the bulk of extra dimensions. Solar νe\nu_e, confined to the brane, can oscillate in the vacuum to the zero mode of νB\nu_B and via successive MSW transitions to Kaluza-Klein states of νB\nu_B. This new way to fit solar data is provided by both low and intermediate string scale models. From average rates seen in the three types of solar experiments, the Super-Kamiokande spectrum is predicted with 73% probability, but dips characteristic of the 0.06 mm extra dimension should be seen in the SNO spectrum.Comment: 4 pages, 2 figure

    High resolution, low temperature photoabsorption cross-section of C2H2 with application to Saturn's atmosphere

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    New laboratory observations of the VUV absorption cross-section of C2H2, obtained under physical conditions approximating stratospheres of the giant planets, were combined with IUE observations of the albedo of Saturn, for which improved data reduction techniques have been used, to produce new models for that atmosphere. When the effects of C2H2 absorption are accounted for, additional absorption by other molecules is required. The best-fitting model also includes absorption by PH3, H2O, C2H6 and CH4. A small residual disagreement near 1600 A suggests that an additional trace species may be required to complete the model

    Large Angular Scale CMB Anisotropy Induced by Cosmic Strings

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    We simulate the anisotropy in the cosmic microwave background (CMB) induced by cosmic strings. By numerically evolving a network of cosmic strings we generate full-sky CMB temperature anisotropy maps. Based on 192192 maps, we compute the anisotropy power spectrum for multipole moments 20\ell \le 20. By comparing with the observed temperature anisotropy, we set the normalization for the cosmic string mass-per-unit-length μ\mu, obtaining Gμ/c2=1.050.20+0.35×106G\mu/c^2=1.05 {}^{+0.35}_{-0.20} \times10^{-6}, which is consistent with all other observational constraints on cosmic strings. We demonstrate that the anisotropy pattern is consistent with a Gaussian random field on large angular scales.Comment: 4 pages, RevTeX, two postscript files, also available at http://www.damtp.cam.ac.uk/user/defects/ to appear in Physical Review Letters, 23 September 199

    The Shape and Scale of Galactic Rotation from Cepheid Kinematics

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    A catalog of Cepheid variables is used to probe the kinematics of the Galactic disk. Radial velocities are measured for eight distant Cepheids toward l = 300; these new Cepheids provide a particularly good constraint on the distance to the Galactic center, R_0. We model the disk with both an axisymmetric rotation curve and one with a weak elliptical component, and find evidence for an ellipticity of 0.043 +/- 0.016 near the Sun. Using these models, we derive R_0 = 7.66 +/- 0.32 kpc and v_circ = 237 +/- 12 km/s. The distance to the Galactic center agrees well with recent determinations from the distribution of RR Lyrae variables, and disfavors most models with large ellipticities at the solar orbit.Comment: 36 pages, LaTeX, 10 figure

    Gravitational wave bursts from cusps and kinks on cosmic strings

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    The strong beams of high-frequency gravitational waves (GW) emitted by cusps and kinks of cosmic strings are studied in detail. As a consequence of these beams, the stochastic ensemble of GW's generated by a cosmological network of oscillating loops is strongly non Gaussian, and includes occasional sharp bursts that stand above the ``confusion'' GW noise made of many smaller overlapping bursts. Even if only 10% of all string loops have cusps these bursts might be detectable by the planned GW detectors LIGO/VIRGO and LISA for string tensions as small as Gμ1013G \mu \sim 10^{-13}. In the implausible case where the average cusp number per loop oscillation is extremely small, the smaller bursts emitted by the ubiquitous kinks will be detectable by LISA for string tensions as small as Gμ1012G \mu \sim 10^{-12}. We show that the strongly non Gaussian nature of the stochastic GW's generated by strings modifies the usual derivation of constraints on GμG \mu from pulsar timing experiments. In particular the usually considered ``rms GW background'' is, when G \mu \gaq 10^{-7}, an overestimate of the more relevant confusion GW noise because it includes rare, intense bursts. The consideration of the confusion GW noise suggests that a Grand Unified Theory (GUT) value Gμ106 G \mu \sim 10^{-6} is compatible with existing pulsar data, and that a modest improvement in pulsar timing accuracy could detect the confusion noise coming from a network of cuspy string loops down to Gμ1011 G \mu \sim 10^{-11}. The GW bursts discussed here might be accompanied by Gamma Ray Bursts.Comment: 24 pages, 3 figures, Revtex, submitted to Phys. Rev.
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