Determining optimal cadence for an individual road cyclist from field data

The cadence that maximises power output developed at the crank by an individual cyclist is conventionally determined using a laboratory test. The purpose of this study was two-fold: (i) to show that such a cadence, which we call the optimal cadence, can be determined using power output, heart-rate, and cadence measured in the field and (ii) to describe methodology to do so. For an individual cyclist's sessions, power output is related to cadence and the elicited heart-rate using a non-linear regression model. Optimal cadences are found for two riders (83 and 70 revolutions per minute, respectively); these cadences are similar to the riders’ preferred cadences (82–92?rpm and 65–75?rpm). Power output reduces by approximately 6% for cadences 20?rpm above or below optimum. Our methodology can be used by a rider to determine an optimal cadence without laboratory testing intervention: the rider will need to collect power output, heart-rate, and cadence measurements from training and racing sessions over an extended period (>6 months); ride at a range of cadences within those sessions; and calculate his/her optimal cadence using the methodology described or a software tool that implements it

A filter spectrometer concept for facsimile cameras

A concept which utilizes interference filters and photodetector arrays to integrate spectrometry with the basic imagery function of a facsimile camera is described and analyzed. The analysis considers spectral resolution, instantaneous field of view, spectral range, and signal-to-noise ratio. Specific performance predictions for the Martian environment, the Viking facsimile camera design parameters, and a signal-to-noise ratio for each spectral band equal to or greater than 256 indicate the feasibility of obtaining a spectral resolution of 0.01 micrometers with an instantaneous field of view of about 0.1 deg in the 0.425 micrometers to 1.025 micrometers range using silicon photodetectors. A spectral resolution of 0.05 micrometers with an instantaneous field of view of about 0.6 deg in the 1.0 to 2.7 micrometers range using lead sulfide photodetectors is also feasible

Design and evaluation of a filter spectrometer concept for facsimile cameras

The facsimile camera is an optical-mechanical scanning device which was selected as the imaging system for the Viking '75 lander missions to Mars. A concept which uses an interference filter-photosensor array to integrate a spectrometric capability with the basic imagery function of this camera was proposed for possible application to future missions. This paper is concerned with the design and evaluation of critical electronic circuits and components that are required to implement this concept. The feasibility of obtaining spectroradiometric data is demonstrated, and the performance of a laboratory model is described in terms of spectral range, angular and spectral resolution, and noise-equivalent radiance

An analysis of the facsimile-camera response to radiant point sources

In addition to imaging the surrounding terrain, planetary lander cameras may also be used to survey the stars to aid in locating the lander site. The response of the facsimile camera, which was selected for the Viking lander missions to Mars, to a radiant point source is formulated and shown to result in a statistical rather than deterministic signal. The signal statistics are derived and magnitudes are evaluated for the brighter visual and red stars. The probability of detecting the resultant statistical signals in photosensor and preamplifier noise and the associated probability of false alarms are also determined

Spectrometer integrated with a facsimile camera

This invention integrates a spectrometer capability with the basic imagery function of facsimile cameras without significantly increasing mechanical or optical complexity, or interfering with the imaging function. The invention consists of a group of photodetectors arranged in a linear array in the focal plane of the facsimile camera with a separate narrow band interference filter centered over each photodetector. The interference filter photodetector array is on a line in the focal plane of the facsimile camera along the direction of image motion due to the rotation of the facsimile camera's vertical mirror. As the image of the picture element of interest travels down the interference filter photodetector array, the photodetector outputs are synchronously selected and sampled to provide spectral information on the single picture element

Modelling of critical power from road data

Background: Performance tests are an integral part of evaluating competitive cyclists. Despite all technological and physiological advances, limited research has been performed addressing the translation of standardized, relevant laboratory tests into the field and consequently into “real world” cycling (i.e. .(i.e. González-Haro et al., 2007: British Journal of Sports Medicine, 41(3), 174–179; Quod et al., 2010:InterInternational Journal of Sports Medicine, 31(6), 397–401; Nimmerichter et al., 2010: International Journal of Sports Medicine, 31(3), 160- 166). For continuous activities between approximately 2 and 30 minutes, the assessment of Critical Power (CP) is one such relevant test. Compromising ecological validity, to date CP testing is mostly constrained to the laboratory. Purpose: To investigate a novel CP road testing protocol. Methods: Laboratory determined CP values using a 30 min intra-trial recovery period (Bishop & Jenkins, 1995: European Journal of Applied Physiology and Occupational Physiology, 72 (1-2), 115-120) were compared with those determined in the field, i.e. on the road. The experiment comprised of planned maximal efforts of 12 min, 7 min and 3 min with a 30 min recovery period between efforts. Linear regression was used to determine CP using the work- Results: There was no significant difference between laboratory and road CP values. The mean difference between the two environments was 0 ± 5.5 W. The standard error of estimates was 1.7% and limits of agreement were -10.8 – 10.8 W (Fig. 1). Discussion: Results suggests that CP can be tested on the road. Gonzales-Haro accepted their incremental velodrome field test as being valid with reported limits of agreement of 130 W to – 24 W and a random error of 13.9%. Our limits of agreement values are considerably higher and standard error of estimate values are considerably lower than those reported by Gonzales-Haro. The experimental protocol provides a practical and easy to use alternative to the conventional testing protocol for coaches and athletes when determining CP in on the road. Conclusion: The aforementioned research provides support for the acceptance of road CP performance testing using a 30 min inter-maximal effort recovery period

Culture and the remembering of trauma

This research investigated the influence of culture and posttraumatic stress disorder (PTSD) on global autobiographical remembering (Study 1a) and on the phenomenological properties (Study 1b) and memory-content variables (Study 1c) of trauma-specific autobiographical remembering. Australian, British, and Iranian trauma survivors with and without PTSD completed the Autobiographical Memory Test, Self-Defining Memory Task, and Autobiographical Memory Questionnaire and provided trauma- and negative-memory narratives. We found that there were pan-cultural deficits and distortions in the global autobiographical remembering of participants with PTSD (Study 1a). In addition, the presence of PTSD moderated the usual effect of culture on the phenomenological properties of the trauma memory (Study 1b). Finally, participants with PTSD, regardless of cultural background, had significantly fewer expressions of autonomy and self-determination in their autobiographical remembering than did those without PTSD (Study 1c). The findings suggest that pan-culturally, individuals with PTSD have similar disruptions and distortions in their autobiographical remembering

Distribution, magnitudes, reactivities, ratios and diurnal patterns of volatile organic compounds in the Valley of Mexico during the MCMA 2002 & 2003 field campaigns

A wide array of volatile organic compound (VOC) measurements was conducted in the Valley of Mexico during the MCMA-2002 and 2003 field campaigns. Study sites included locations in the urban core, in a heavily industrial area and at boundary sites in rural landscapes. In addition, a novel mobile-laboratory-based conditional sampling method was used to collect samples dominated by fresh on-road vehicle exhaust to identify those VOCs whose ambient concentrations were primarily due to vehicle emissions. Four distinct analytical techniques were used: whole air canister samples with Gas Chromatography/Flame Ionization Detection (GC-FID), on-line chemical ionization using a Proton Transfer Reaction Mass Spectrometer (PTR-MS), continuous real-time detection of olefins using a Fast Olefin Sensor (FOS), and long path measurements using UV Differential Optical Absorption Spectrometers (DOAS). The simultaneous use of these techniques provided a wide range of individual VOC measurements with different spatial and temporal scales. The VOC data were analyzed to understand concentration and spatial distributions, diurnal patterns, origin and reactivity in the atmosphere of Mexico City. The VOC burden (in ppbC) was dominated by alkanes (60%), followed by aromatics (15%) and olefins (5%). The remaining 20% was a mix of alkynes, halogenated hydrocarbons, oxygenated species (esters, ethers, etc.) and other unidentified VOCs. However, in terms of ozone production, olefins were the most relevant hydrocarbons. Elevated levels of toxic hydrocarbons, such as 1,3-butadiene, benzene, toluene and xylenes, were also observed. Results from these various analytical techniques showed that vehicle exhaust is the main source of VOCs in Mexico City and that diurnal patterns depend on vehicular traffic in addition to meteorological processes. Finally, examination of the VOC data in terms of lumped modeling VOC classes and its comparison to the VOC lumped emissions reported in other photochemical air quality modeling studies suggests that some alkanes are underestimated in the emissions inventory, while some olefins and aromatics are overestimated

Comparison of aromatic hydrocarbon measurements made by PTR-MS, DOAS and GC-FID during the MCMA 2003 Field Experiment

A comparison of aromatic hydrocarbon measurements is reported for the CENICA supersite in the district of Iztapalapa during the Mexico City Metropolitan Area field experiment in April 2003 (MCMA 2003). Data from three different measurement methods were compared: a Proton Transfer Reaction Mass Spectrometer (PTR-MS), long path measurements using a UV Differential Optical Absorption Spectrometer (DOAS), and Gas Chromatography-Flame Ionization analysis (GC-FID) of canister samples. The principle focus was on the comparison between PTR-MS and DOAS data. Lab tests established that the PTR-MS and DOAS calibrations were consistent for a suite of aromatic compounds including benzene, toluene, p-xylene, ethylbenzene, 1,2,4-trimethylbenzene, phenol and styrene. The point sampling measurements by the PTR-MS and GC-FID showed good correlations (r=0.6), and were in reasonable agreement for toluene, C2-alkylbenzenes and C3-alkylbenzenes. The PTR-MS benzene data were consistently high, indicating interference from ethylbenzene fragmentation for the 145 Td drift field intensity used in the experiment. Correlations between the open-path data measured at 16-m height over a 860-m path length (retroreflector in 430 m distance), and the point measurements collected at 37-m sampling height were best for benzene (r=0.61), and reasonably good for toluene, C2-alkylbenzenes, naphthalene, styrene, cresols and phenol (r>0.5). There was good agreement between DOAS and PTR-MS measurements of benzene after correction for the PTR-MS ethylbenzene interference. Mixing ratios measured by DOAS were on average a factor of 1.7 times greater than the PTR-MS data for toluene, C2-alkylbenzenes, naphthalene and styrene. The level of agreement for the toluene data displayed a modest dependence on wind direction, establishing that spatial gradients – horizontal, vertical, or both – in toluene mixing ratios were significant, and up to a factor of 2 despite the fact that all measurements were conducted above roof level. Our analysis highlights a potential problem in defining a VOC sampling strategy that is meaningful for the comparison with photochemical transport models: meaningful measurements require a spatial fetch that is comparable to the grid cell size of models, which is typically a few 10 km2. Long-path DOAS measurements inherently average over a larger spatial scale than point measurements. The spatial representativeness can be further increased if observations are conducted outside the surface roughness sublayer, which might require measurements at altitudes as high as 10 s of metres above roof level.Alexander von Humboldt-Stiftung (Feodor Lynen fellowship)Henry & Camille Dreyfus Foundation (Postdoctral Fellowship in Environmental Chemistry

Atmospheric oxidation in the Mexico City Metropolitan Area (MCMA) during April 2003

International audienceThe Mexico City Metropolitan Area (MCMA) study in April 2003 had measurements of most atmospheric constituents including OH and HO2. It provided a unique opportunity to examine atmospheric oxidation in a megacity that has more pollution than typical US and European cities. OH typically reached 0.35 pptv (~7×106 cm?3), comparable to amounts observed in US cities, but HO2 reached 40 pptv in the early afternoon, more than observed in most US cities. A steady-state photochemical model simulated the measured OH and HO2 for day and night to within combined measurement and modeling uncertainties for 2/3 of the results. For OH, measured = 0.65 (modeled) + 0.026 pptv, with R2=0.80. For HO2, observed = 0.70 (modeled) + 3.4 pptv, with R2=0.64. Measurements tended to be higher during night and rush hour; the model was higher by ~30% during midday. With a large median measured OH reactivity of more than 120 s?1 during morning rush hour, median ozone production from observed HO2 reached 50 ppb hr?1; RO2 was calculated to have a similar ozone production rate. For both the HO2/OH ratio and the ozone production, the measured values have the essentially same dependence on NO as the modeled values. This similarity is unlike other urban studies in which the NO-dependence of the measured HO2/OH ratio was much less than the modeled ratio and the ozone production rate that was calculated from measured HO2 unexpectedly appeared to increase as a function of NO with no obvious peak