Juxtaposition of Spin Freezing and Long Range Order in a Series of Geometrically Frustrated Antiferromagnetic Gadolinium Garnets

Specific heat measurements in zero magnetic field are presented on a homologous series of geometrically frustrated, antiferromagnetic, Heisenberg garnet systems. Measurements of Gd3Ga5O12, grown with isotopically pure Gd, agree well with previous results on samples with naturally abundant Gd, showing no ordering features. In contrast, samples of Gd3Te2Li3O12 and Gd3Al5O12 are found to exhibit clear ordering transitions at 243 mK and 175 mK respectively. The effects of low level disorder are studied through dilution of Gd3+ with non-magnetic Y3+ in Gd3Te2Li3O12. A thorough structural characterization, using X-ray diffraction, is performed on all of the samples studied. We discuss possible explanations for such diverse behavior in very similar systems.Comment: Accepted for publication in Physical Review

Laser-based powder bed fusion of Ti-6Al-4V structures with different surface-area-to-volume ratios in oxygen-reduced and oxygen-free environment

Titanium alloys, such as Ti-6Al-4V, are particularly susceptible to oxidation, which is why their processing in the laser-based powder bed fusion process is carried out conventionally in a protective gas atmosphere. However, this atmosphere still contains critical residual oxygen levels, which are to be eliminated as part of a new approach. This approach envisages doping the argon protective gas atmosphere with small amounts of the highly reactive gas silane (ratio < 1:1000). The residual oxygen content is particularly critical in filigree and thin-walled structures that have a high surface-area-to-volume ratio and are a typical field of application for this additive manufacturing process. Therefore, this work focuses on the manufacturing of Ti-6Al-4V structures with different surface-area-to-volume ratios in conventional argon (< 200 ppm residual oxygen) and argon-silane atmospheres (< 10-14 ppm residual oxygen) on an innovative laboratory machine. After processing, the specimens are analyzed for surface topography, microstructure, and Vickers hardness. In addition, energy-dispersive X-ray spectroscopy and X-ray diffraction measurements are carried out to further investigate the chemical composition and present phases in the as-built specimens. The influence of the different atmospheres and their residual oxygen content, the surface-to-volume ratio, and possible interactions between them are discussed

Influence of process parameters on single weld seam geometry and process stability in Laser Hot-Wire Cladding of AISI 52100

Steels with high carbon content can hardly or not at all be welded, but are of great interest for cladding applications due to their high hardness. In this study, the influence of process parameters on weld seam geometry and process stability is investigated when welding AISI 52100 bearing steel using the laser hot-wire cladding process. Process stability is evaluated using actual and set values for the wire feed rate and current parameters to determine a process window for a stable welding process. Weld seams are measured and analyzed in terms of width, height, contact angle, and shape. The effect of the process parameters on the weld seam geometry is investigated and appropriate mathematical functions to describe the geometry are determined. Process parameter sets in the range of 1-2 m/min wire feed rate and 45-75 A hot wire current were investigated. Unstable parameter sets occur clustered at high wire feed rate of 2 m/min for all hot wire currents. In addition, the process is unstable at high hot wire current of 75 A and low wire feed speed of 1 m/min. The remaining parameter sets resulted in a stable process. The investigated functions parabolic, cosinusoidal and circular arc for the mathematical description of the weld seam geometry, no clearly significant result could be determined. Only a trend towards the circular arc function and the parabolic function is apparent

Functional coatings of sol-gel on glass substrate using CO2 laser irradiation

Often Glass products achieve their component functionality only by a specific surface finishing, such as coating or patterning. Compared to vacuum based CVD and PVD coating techniques, the equipment for wet-chemical deposition of sol-gels is less expensive. Heat is needed for a chemical reaction to cure gels and form solid functional layers. In this study, sols with titanium and zirconium were applied on glass substrates by dip coating. The investigated layer thicknesses were in the range between 320 nm and 650 nm. The gel layers were annealed with CO2 laser radiation. Different scanning speeds and laser powers were investigated. Microscope images were used to compare the laser-annealed layers with oven-annealed layers. To conclude, the oven-process can be substituted by laser annealing and additionally enables local patterning. This allows gradient coating solutions for architecture applications

Thermoforming of planar polymer optical waveguides for integrated optics in smart packaging materials

The innovations in smart packaging will open up a wide range of opportunities in the future. This work describes the processing of additive manufactured and planar integrated polymer optical waveguides for use in smart packaging products. The previously published combination of flexographic and Aerosol Jet printing is complemented by thermoforming and thus creates three-dimensional integrated multimode waveguides with optical attenuation of 1.9 dB/cm ± 0.1 dB/cm @ 638 nm. These properties will be the basis to develop smart applications in packaging materials

Low noise 400 W coherently combined single frequency laser beam for next generation gravitational wave detectors

Design studies for the next generation of interferometric gravitational wave detectors propose the use of low-noise single-frequency high power laser sources at 1064 nm. Fiber amplifiers are a promising design option because of their high output power and excellent optical beam properties. We performed filled-aperture coherent beam combining with independently amplified beams from two low-noise high-power single-frequency fiber amplifiers to further scale the available optical power. An optical power of approximately 400 W with a combining efficiency of more than 93% was achieved. The combined beam contained 370 W of linearly polarized TEM00-mode and was characterized with respect to the application requirements of low relative power noise, relative beam pointing noise, and frequency noise. The noise performance of the combined beam is comparable to the single amplifier noise. This represents, to our knowledge, the highest measured power in the TEM00-mode of single frequency signals that fulfills the low noise requirements of gravitational wave detectors

PROCESS-INTEGRATED ALLOY ADJUSTMENT IN LASER DEPOSITION WELDING WITH TWO WIRES

For Direct Energy Deposition (DED) with wire as filler material, the material selection is mostly limited to commercially available welding wires. This limits the achievable material properties for cladding and Additive Manufacturing purposes. Using a coaxial deposition welding head, in which two different wires can be fed and controlled individually, the alloy composition can be adjusted in the common process zone in-situ. In this study, the two wire materials AISI 316L and ER 70S-6 are used in different mixing ratios to fabricate single weld seams. The different mixing ratios are achieved by varying the wire feed rates. The material content in the weld is varied between 0% and 100% in 20% steps. The weld seams are examined with regard to the distribution of alloying elements, hardness and microstructure. Homogeneous mixing of the two materials was achieved at all mixing ratios. At a content of 40% or more of ER 70S-6 in the weld seam, there was a drastic change in the microstructure and a significant increase in hardness. The microstructure changed from austenitic to ferritic-pearlitic, which was accompanied by an increase in hardness from 170 HV0.1 to 428 HV0.1.Mechanical Engineerin

The future of short-range high-speed data transmission: Printed polymer optical waveguides (POW) innovation, fabrication, and challenges

One of today's megatrends in the industrial environment is additive manufacturing. Faster prototyping, customized products like hearing devices, integrated functions like heatsinks and many other opportunities are offered by this technological development. The opportunity of using different materials and build up 3-D structures is virtually infinite. Another one is the digitalization of almost any product to build up a smart world. This trend leads to a tremendously rising amount of data to be transferred from one place to another. If a wireless transmission is not possible and if the distance is over 100 m glass fiber is the fastest and most secure way for these requirements. In case of most short-range applications up to 100 m primary copper cables or circuit paths are in use because the electrical data transfer is well known. The limited bandwidth of copper asks for new inventions to meet the demands of tomorrow. Regarding both megatrends, the solution for this upcoming bottleneck could be 3-D printed photonic packages. This paper shows a new and innovative way for the customized fabricating of short-range data transmission networks. By Aerosol Jet Printing (AJP) the so called polymer optical waveguides (POW), it is possible to build up 3-D printed light guiding structures with low attenuation on almost any three-dimensional surface. The main advantages of the here presented research are high flexibility, low weight and low costs. After three years of intensive studies the most important key facts (machine settings, geometry, performance) are summarized in this publication. © 2018 SPIE