Determination of the complex refractive index and optical bandgap of CH3NH3PbI3 thin films

We report the complex refractive index of methylammonium lead iodide CH3NH3PbI3 perovskite thin films obtained by means of variable angle spectroscopic ellipsometry and transmittance reflectance spectrophotometry in the wavelength range of 190 amp; 8201;nm to 2500 amp; 8201;nm. The film thickness and roughness layer thickness are determined by minimizing a global unbiased estimator in the region where the spectrophotometry and ellipsometry spectra overlap. We then determine the optical bandgap and Urbach energy from the absorption coefficient, by means of a fundamental absorption model based on band fluctuations in direct emiconductors. This model merges both the Urbach tail and the absorption edge regions in a single equation. In this way, we increase the fitting region and extend the conventional amp; 945; amp; 8463; amp; 969; 2 plot method to obtain accurate bandgap value

Ginzburg Criterion for Coulombic Criticality

To understand the range of close-to-classical critical behavior seen in various electrolytes, generalized Debye-Hueckel theories (that yield density correlation functions) are applied to the restricted primitive model of equisized hard spheres. The results yield a Landau-Ginzburg free-energy functional for which the Ginzburg criterion can be explicitly evaluated. The predicted scale of crossover from classical to Ising character is found to be similar in magnitude to that derived for simple fluids in comparable fashion. The consequences in relation to experiments are discussed briefly.Comment: 4 pages, revtex, 2 tables (latex2.09 required due to revtex's incompatibility with latex2e tables

Universality class of criticality in the restricted primitive model electrolyte

The 1:1 equisized hard-sphere electrolyte or restricted primitive model has been simulated via grand-canonical fine-discretization Monte Carlo. Newly devised unbiased finite-size extrapolation methods using temperature-density, (T, rho), loci of inflections, Q = ^2/ maxima, canonical and C_V criticality, yield estimates of (T_c, rho_c) to +- (0.04, 3)%. Extrapolated exponents and Q-ratio are (gamma, nu, Q_c) = [1.24(3), 0.63(3); 0.624(2)] which support Ising (n = 1) behavior with (1.23_9, 0.630_3; 0.623_6), but exclude classical, XY (n = 2), SAW (n = 0), and n = 1 criticality with potentials phi(r)>Phi/r^{4.9} when r \to \infty

Towards accurate and precise T1 and extracellular volume mapping in the myocardium: a guide to current pitfalls and their solutions

Mapping of the longitudinal relaxation time (T1) and extracellular volume (ECV) offers a means of identifying pathological changes in myocardial tissue, including diffuse changes that may be invisible to existing T1-weighted methods. This technique has recently shown strong clinical utility for pathologies such as Anderson- Fabry disease and amyloidosis and has generated clinical interest as a possible means of detecting small changes in diffuse fibrosis; however, scatter in T1 and ECV estimates offers challenges for detecting these changes, and bias limits comparisons between sites and vendors. There are several technical and physiological pitfalls that influence the accuracy (bias) and precision (repeatability) of T1 and ECV mapping methods. The goal of this review is to describe the most significant of these, and detail current solutions, in order to aid scientists and clinicians to maximise the utility of T1 mapping in their clinical or research setting. A detailed summary of technical and physiological factors, issues relating to contrast agents, and specific disease-related issues is provided, along with some considerations on the future directions of the field. Towards accurate and precise T1 and extracellular volume mapping in the myocardium: a guide to current pitfalls and their solutions. Available from: https://www.researchgate.net/publication/317548806_Towards_accurate_and_precise_T1_and_extracellular_volume_mapping_in_the_myocardium_a_guide_to_current_pitfalls_and_their_solutions [accessed Jun 13, 2017]

Dipolar origin of the gas-liquid coexistence of the hard-core 1:1 electrolyte model

We present a systematic study of the effect of the ion pairing on the gas-liquid phase transition of hard-core 1:1 electrolyte models. We study a class of dipolar dimer models that depend on a parameter R_c, the maximum separation between the ions that compose the dimer. This parameter can vary from sigma_{+/-} that corresponds to the tightly tethered dipolar dimer model, to R_c --> infinity, that corresponds to the Stillinger-Lovett description of the free ion system. The coexistence curve and critical point parameters are obtained as a function of R_c by grand canonical Monte Carlo techniques. Our results show that this dependence is smooth but non-monotonic and converges asymptotically towards the free ion case for relatively small values of R_c. This fact allows us to describe the gas-liquid transition in the free ion model as a transition between two dimerized fluid phases. The role of the unpaired ions can be considered as a perturbation of this picture.Comment: 16 pages, 13 figures, submitted to Physical Review

Classical-to-critical crossovers from field theory

We extent the previous determinations of nonasymptotic critical behavior of Phys. Rev B32, 7209 (1985) and B35, 3585 (1987) to accurate expressions of the complete classical-to-critical crossover (in the 3-d field theory) in terms of the temperature-like scaling field (i.e., along the critical isochore) for : 1) the correlation length, the susceptibility and the specific heat in the homogeneous phase for the n-vector model (n=1 to 3) and 2) for the spontaneous magnetization (coexistence curve), the susceptibility and the specific heat in the inhomogeneous phase for the Ising model (n=1). The present calculations include the seventh loop order of Murray and Nickel (1991) and closely account for the up-to-date estimates of universal asymptotic critical quantities (exponents and amplitude combinations) provided by Guida and Zinn-Justin [J. Phys. A31, 8103 (1998)].Comment: 4 figs, 4 program documents in appendix, some corrections adde

T1 mapping in cardiac MRI

Quantitative myocardial and blood T1 have recently achieved clinical utility in numerous pathologies, as they provide non-invasive tissue characterization with the potential to replace invasive biopsy. Native T1 time (no contrast agent), changes with myocardial extracellular water (edema, focal or diffuse fibrosis), fat, iron, and amyloid protein content. After contrast, the extracellular volume fraction (ECV) estimates the size of the extracellular space and identifies interstitial disease. Spatially resolved quantification of these biomarkers (so-called T1 mapping and ECV mapping) are steadily becoming diagnostic and prognostically useful tests for several heart muscle diseases, influencing clinical decision-making with a pending second consensus statement due mid-2017. This review outlines the physics involved in estimating T1 times and summarizes the disease-specific clinical and research impacts of T1 and ECV to date. We conclude by highlighting some of the remaining challenges such as their community-wide delivery, quality control, and standardization for clinical practice