Sulfate and MSA in the air and snow on the Greenland Ice Sheet

Sulfate and methanesulfonic acid (MSA) concentrations in aerosol, surface snow, and snowpit samples have been measured at two sites on the Greenland Ice Sheet. Seasonal variations of the concentrations observed for these chemical species in the atmosphere are reproduced in the surface snow and preserved in the snowpit sequence. The amplitude of the variations over a year are smaller in the snow than in the air, but the ratios of the concentrations are comparable. The seasonal variations for sulfate are different at the altitude of the Ice Sheet compared to those observed at sea level, with low concentrations in winter and short episodes of elevated concentrations in spring. In contrast, the variations in concentrations of MSA are similar to those measured at sea level, with a first sequence of elevated concentrations in spring and another one during summer, and a winter low resulting from low biogenic production. The ratio MSA/sulfate clearly indicates the influence of high-latitude sources for the summer maximum of MSA, but the large impact of anthropogenic sulfate precludes any conclusion for the spring maximum. The seasonal pattern observed for these species in a snowpit sampled according to stratigraphy indicates a deficit in the accumulation of winter snow at the summit of the Greenland Ice Sheet, in agreement with some direct observations. A deeper snowpit covering the years 1985–1992 indicates the consistency of the seasonal pattern for MSA over the years, which may be linked to transport and deposition processes

Prevalence of respiratory pathogens in nasal swabs from horses with acute respiratory disease in Belgium

Contagious respiratory infections are an important cause of respiratory disease in horses, resulting in impaired pulmonary function, poor performance and sometimes severe illness. Although bacterial infections are often suspected to be involved, viruses are frequently overlooked and are an underestimated cause of respiratory disease outbreaks in horses. In this study, nasal swabs of 103 horses with acute symptoms of respiratory disease were analyzed for the presence of 13 different respiratory pathogens. Gamma herpesviruses were the most commonly detected, with 60% of the samples being positive, followed by streptococcus equi subsp. zooepidemicus infection (30%). Rhinovirus B, streptococcus equi subsp. equi, adenovirus 1 and EHV-4 were more rarely detected. Further research is necessary to correctly interpret the importance of gamma herpesviruses in horses, for example by screening a healthy control population. National surveillance of respiratory viruses in horses by PCR analysis on nasal swabs might be a useful, early warning system for viral epidemics

Flux Jumps Driven by a Pulsed Magnetic Field

The understanding of flux jumps in the high temperature superconductors is of importance since the occurrence of these jumps may limit the perspectives of the practical use of these materials. In this work we present the experimental study of the role of heavy ion irradiation in stabilizing the HTSC against flux jumps by comparing un-irradiated and 7.5 10^10 Kr-ion/cm2 irradiated (YxTm1-x)Ba2Cu3O7 single crystals. Using pulsed field magnetization measurements, we have applied a broad range of field sweep rates from 0.1T/s up to 1800 T/s to investigate the behavior of the flux jumps. The observed flux jumps, which may be attributed to thermal instabilities, are incomplete and have different amplitudes. The flux jumps strongly depend on the magnetic field, on the magneto-thermal history of the sample, on the magnetic field sweep rate, on the critical current density jc, on the temperature and on the thermal contact with the bath in which the sample is immersed.Comment: 5 pages, PDF-fil

Self-Organized Criticality Effect on Stability: Magneto-Thermal Oscillations in a Granular YBCO Superconductor

We show that the self-organized criticality of the Bean's state in each of the grains of a granular superconductor results in magneto-thermal oscillations preceding a series of subsequent flux jumps. We find that the frequency of these oscillations is proportional to the external magnetic field sweep rate and is inversely proportional to the square root of the heat capacity. We demonstrate experimentally and theoretically the universality of this dependence that is mainly influenced by the granularity of the superconductor.Comment: submitted to Physical Review Letters, 4 pages, RevTeX, 4 figures available as uufile

Atmospheric nitrogen oxides (NO and NO2) at Dome C, East Antarctica, during the OPALE campaign

Mixing ratios of the atmospheric nitrogen oxides NO and NO2 were measured as part of the OPALE (Oxidant Production in Antarctic Lands & Export) campaign at Dome C, East Antarctica (75.1 degrees S, 123.3 degrees E, 3233 m), during December 2011 to January 2012. Profiles of NOx mixing ratios of the lower 100m of the atmosphere confirm that, in contrast to the South Pole, air chemistry at Dome C is strongly influenced by large diurnal cycles in solar irradiance and a sudden collapse of the atmospheric boundary layer in the early evening. Depth profiles of mixing ratios in firn air suggest that the upper snowpack at Dome C holds a significant reservoir of photolytically produced NO2 and is a sink of gas-phase ozone (O-3). First-time observations of bromine oxide (BrO) at Dome C show that mixing ratios of BrO near the ground are low, certainly less than 5 pptv, with higher levels in the free troposphere. Assuming steady state, observed mixing ratios of BrO and RO2 radicals are too low to explain the large NO2 : NO ratios found in ambient air, possibly indicating the existence of an unknown process contributing to the atmospheric chemistry of reactive nitrogen above the Antarctic Plateau. During 2011-2012, NOx mixing ratios and flux were larger than in 2009-2010, consistent with also larger surface O-3 mixing ratios resulting from increased net O-3 production. Large NOx mixing ratios at Dome C arise from a combination of continuous sunlight, shallow mixing height and significant NOx emissions by surface snow (F-NOx). During 23 December 2011-12 January 2012, median F-NOx was twice that during the same period in 20092010 due to significantly larger atmospheric turbulence and a slightly stronger snowpack source. A tripling of F-NOx in December 2011 was largely due to changes in snowpack source strength caused primarily by changes in NO3- concentrations in the snow skin layer, and only to a secondary order by decrease of total column O-3 and associated increase in NO3- photolysis rates. A source of uncertainty in model estimates of F-NOx is the quantum yield of NO3- photolysis in natural snow, which may change over time as the snow ages

Water adsorption on amorphous silica surfaces: A Car-Parrinello simulation study

A combination of classical molecular dynamics (MD) and ab initio Car-Parrinello molecular dynamics (CPMD) simulations is used to investigate the adsorption of water on a free amorphous silica surface. From the classical MD SiO_2 configurations with a free surface are generated which are then used as starting configurations for the CPMD.We study the reaction of a water molecule with a two-membered ring at the temperature T=300K. We show that the result of this reaction is the formation of two silanol groups on the surface. The activation energy of the reaction is estimated and it is shown that the reaction is exothermic.Comment: 12 pages, 6 figures, to be published in J. Phys.: Condens. Matte

An imaging and spectroscopic study of the very metal-deficient blue compact dwarf galaxy Tol 1214--277

We present a spectrophotometric study based on VLT/FORS I observations of one of the most metal-deficient blue compact dwarf (BCD) galaxies known, Tol 1214-277 (Z ~ Zsun/25). The data show that roughly half of the total luminosity of the BCD originates from a bright and compact starburst region located at the northeastern tip of a faint dwarf galaxy with cometary appearance. The starburst has ignited less than 4 Myr ago and its emission is powered by several thousands O7V stars and ~ 170 late-type nitrogen Wolf-Rayet stars located within a compact region with < 500 pc in diameter. For the first time in a BCD, a relatively strong [Fe V] 4227 emission line is seen which together with intense He II 4686 emission indicates the presence of a very hard radiation field in Tol 1214-277. We argue that this extraordinarily hard radiation originates from both Wolf--Rayet stars and radiative shocks in the starburst region. The structural properties of the low-surface-brightness (LSB) component underlying the starburst have been investigated by means of surface photometry down to 28 B mag/sq.arcsec. We find that, for a surface brightness level fainter than ~ 24.5 B mag/sq.arcsec, an exponential fitting law provides an adequate approximation to its radial intensity distribution. The broad-band colors in the outskirts of the LSB component of Tol 1214-277 are nearly constant and are consistent with an age below one Gyr. This conclusion is supported by the comparison of the observed spectral energy distribution (SED) of the LSB host with theoretical SEDs.Comment: 17 pages, 11 Postscript figures, uses emulateapj.sty, to appear in Astronomical Journa

Greenland ice core “signal” characteristics: An expanded view of climate change

The last millenium of Earth history is of particular interest because it documents the environmental complexities of both natural variability and anthropogenic activity. We have analyzed the major ions contained in the Greenland Ice Sheet Project 2 (GISP 2) ice core from the present to ∼674 A.D. to yield an environmental reconstruction for this period that includes a description of nitrogen and sulfur cycling, volcanic emissions, sea salt and terrestrial influences. We have adapted and extended mathematical procedures for extracting sporadic (e.g., volcanic) events, secular trends, and periodicities found in the data sets. Finally, by not assuming that periodic components (signals) were “stationary” and by utilizing evolutionary spectral analysis, we were able to reveal periodic processes in the climate system which change in frequency, “turn on,” and “turn off” with other climate transitions such as\u27that between the little ice age and the medieval warm period

A spectroscopic study of component C and the extended emission around I Zw 18

Long-slit Keck II, 4m Kitt Peak, and 4.5m MMT spectrophotometric data are used to investigate the stellar population and the evolutionary status of I Zw 18C, the faint C component of the nearby blue compact dwarf galaxy I Zw 18. Hydrogen H$\alpha$ and H$\beta$ emission lines are detected in the spectra of I Zw 18C, implying that ionizing massive stars are present. High signal-to-noise Keck II spectra of different regions in I Zw 18C reveal H$\gamma$, H$\delta$ and higher order hydrogen lines in absorption. Several techniques are used to constrain the age of the stellar population in I Zw 18C. Ages derived from two different methods, one based on the equivalent widths of the H$\alpha$, H$\beta$ emission lines and the other on H$\gamma$, H$\delta$ absorption lines are consistent with a 15 Myr instantaneous burst model. We find that a small extinction in the range $A_V$ = 0.20 -- 0.65 mag is needed to fit the observed spectral energy distribution of I Zw 18C with that model. In the case of constant star formation, all observed properties are consistent with stars forming continuously between ~ 10 Myr and < 100 Myr ago. We use all available observational constraints for I Zw 18C, including those obtained from Hubble Space Telescope color-magnitude diagrams, to argue that the distance to I Zw 18 should be as high as ~ 15 Mpc. The deep spectra also reveal extended ionized gas emission around I Zw 18. H$\alpha$ emission is detected as far as 30" from it. To a B surface brightness limit of ~ 27 mag arcsec$^{-2}$ we find no observational evidence for extended stellar emission in the outermost regions, at distances > 15" from I Zw 18.Comment: 38 pages, 11 Postscript figures, accepted for publication in the Astrophysical Journa

Optical second harmonic generation probe of two-dimensional ferroelectricity

Optical second harmonic generation (SHG) is used as a noninvasive probe of two-dimensional (2D) ferroelectricity in Langmuir-Blodgett (LB) films of copolymer vinylidene fluoride with trifluorethylene. The surface 2D ferroelectric-paraelectric phase transition in the topmost layer of LB films and a thickness independent (almost 2D) transition in the bulk of these films are observed in temperature studies of SHG.Comment: 9 pages, 2 figures, Optics Letters, in prin