Fluctuation-enhanced electric conductivity in electrolyte solutions

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged multispecies diffusion coupled with the fluctuating fluid momentum equation, result in enhanced charge transport. Although this transport is advective in nature, it can macroscopically be represented as electrodiffusion with renormalized electric conductivity. We calculate the renormalized electric conductivity by deriving and integrating the structure factor coefficients of the fluctuating quantities and show that the renormalized electric conductivity and diffusion coefficients are consistent although they originate from different noise terms. In addition, the fluctuating hydrodynamics approach recovers the electrophoretic and relaxation corrections obtained by Debye-Huckel-Onsager theory, and provides a quantitative theory that predicts a non-zero cross-diffusion Maxwell-Stefan coefficient that agrees well with experimental measurements. Finally, we show that strong applied electric fields result in anisotropically enhanced velocity fluctuations and reduced fluctuations of salt concentrations.Comment: 12 pages, 1 figur

Low Mach Number Fluctuating Hydrodynamics for Electrolytes

We formulate and study computationally the low Mach number fluctuating hydrodynamic equations for electrolyte solutions. We are interested in studying transport in mixtures of charged species at the mesoscale, down to scales below the Debye length, where thermal fluctuations have a significant impact on the dynamics. Continuing our previous work on fluctuating hydrodynamics of multicomponent mixtures of incompressible isothermal miscible liquids (A. Donev, et al., Physics of Fluids, 27, 3, 2015), we now include the effect of charged species using a quasielectrostatic approximation. Localized charges create an electric field, which in turn provides additional forcing in the mass and momentum equations. Our low Mach number formulation eliminates sound waves from the fully compressible formulation and leads to a more computationally efficient quasi-incompressible formulation. We demonstrate our ability to model saltwater (NaCl) solutions in both equilibrium and nonequilibrium settings. We show that our algorithm is second-order in the deterministic setting, and for length scales much greater than the Debye length gives results consistent with an electroneutral/ambipolar approximation. In the stochastic setting, our model captures the predicted dynamics of equilibrium and nonequilibrium fluctuations. We also identify and model an instability that appears when diffusive mixing occurs in the presence of an applied electric field.Comment: 37 pages, 5 figure

Organizational impact of evidence-informed decision making training initiatives : a case study comparison of two approaches

Background The impact of efforts by healthcare organizations to enhance the use of evidence to improve organizational processes through training programs has seldom been assessed. We therefore endeavored to assess whether and how the training of mid- and senior-level healthcare managers could lead to organizational change. Methods We conducted a theory-driven evaluation of the organizational impact of healthcare leaders’ participation in two training programs using a logic model based on Nonaka’s theory of knowledge conversion. We analyzed six case studies nested within the two programs using three embedded units of analysis (individual, group and organization). Interviews were conducted during intensive one-week data collection site visits. A total of 84 people were interviewed. Results We found that the impact of training could primarily be felt in trainees’ immediate work environments. The conversion of attitudes was found to be easier to achieve than the conversion of skills. Our results show that, although socialization and externalization were common in all cases, a lack of combination impeded the conversion of skills. We also identified several individual, organizational and program design factors that facilitated and/or impeded the dissemination of the attitudes and skills gained by trainees to other organizational members. Conclusions Our theory-driven evaluation showed that factors before, during and after training can influence the extent of skills and knowledge transfer. Our evaluation went further than previous research by revealing the influence—both positive and negative—of specific organizational factors on extending the impact of training programs

Metachronal wave and hydrodynamic interaction for deterministic switching rowers

We employ a model system, called rowers, as a generic physical framework to define the problem of the coordinated motion of cilia (the metachronal wave) as a far from equilibrium process. Rowers are active (two-state) oscillators interacting solely through forces of hydrodynamic origin. In this work, we consider the case of fully deterministic dynamics, find analytical solutions of the equation of motion in the long wavelength (continuum) limit, and investigate numerically the short wavelength limit. We prove the existence of metachronal waves below a characteristic wavelength. Such waves are unstable and become stable only if the sign of the coupling is reversed. We also find that with normal hydrodynamic interaction the metachronal pattern has the form of stable trains of traveling wave packets sustained by the onset of anti-coordinated beating of consecutive rowers.Comment: 11 pages, 7 figure

Charge diffusion constant in hot and dense hadronic matter - A Hadro-molecular-dynamic calculation

We evaluate charge diffusion constant of dense and hot hadronic matter based on the molecular dynamical method by using a hadronic collision generator which describes nuclear collisions at energies 10 < E < 100 GeV/A and satisfies detailed balance at low temperatures (T < 200 MeV). For the hot and dense hadronic matter of the temperature range, 100 < T < 200 MeV and baryon number density, 0.16 < nB < 0.32 fm^-3, charge diffusion constant D gradually increases from 0.5 fm c to 2 fm c with temperature and is almost independent of baryon number density. Based on the obtained diffusion constant we make simple discussions on the diffusion of charge fluctuation in ultrarelativistic nuclear collisions.Comment: 13 pages, 4 figure

Perceptions of knowledge sharing among small family firm leaders: a structural equation model

Small family firms have many unique relational qualities with implications for how knowledge is passed between individuals. Extant literature posits leadership approach as important in explaining differences in knowledge-sharing climate from one firm to another. This study investigates how leadership approaches interact with family influence to inform perceptions of knowledge sharing. We utilize survey data (n = 110) from owner-managers of knowledge-intensive small family firms in Scotland. Our findings present a choice in leadership intention, contrasting organization-focused participation against family-influenced guidance. Insight is offered on the implications of this leadership choice at both organizational and familial level

QGP flow fluctuations and the characteristics of higher moments

The dynamical development of expanding Quark-gluon Plasma (QGP) flow is studied in a 3+1D fluid dynamical model with a globally symmetric, initial condition. We minimize fluctuations arising from complex dynamical processes at finite impact parameters and from fluctuating random initial conditions to have a conservative fluid dynamical background estimate for the statistical distributions of the thermodynamical parameters. We also avoid a phase transition in the equation of state, and we let the matter supercool during the expansion. Then central Pb+Pb collisions at $\sqrt{s_{NN}} = 2.76$ TeV are studied in an almost perfect fluid dynamical model, with azimuthally symmetric initial state generated in a dynamical flux-tube model. The general development of thermodynamical extensives are also shown for lower energies. We observe considerable deviations from a thermal equilibrium source as a consequence of the fluid dynamical expansion arising from a least fluctuating initial state

Hydrodynamics: Fluctuating Initial Conditions and Two-particle Correlations

Event-by-event hydrodynamics (or hydrodynamics with fluctuating initial conditions) has been developed in the past few years. Here we discuss how it may help to understand the various structures observed in two-particle correlations.Comment: 7 pages, 9 figures, presented at the Workshop on Saturation, the Color Glass Condensate and Glasma: What Have we Learned from RHIC

Hydrodynamical evolution near the QCD critical end point

Hydrodynamical calculations have been successful in describing global observables in ultrarelativistic heavy ion collisions, which aim to observe the production of the quark-gluon plasma. On the other hand, recently, a lot of evidence that there exists a critical end point (CEP) in the QCD phase diagram has been accumulating. Nevertheless, so far, no equation of state with the CEP has been employed in hydrodynamical calculations. In this paper, we construct the equation of state with the CEP on the basis of the universality hypothesis and show that the CEP acts as an attractor of isentropic trajectories. We also consider the time evolution in the case with the CEP and discuss how the CEP affects the final state observables, such as the correlation length, fluctuation, chemical freezeout, kinetic freezeout, and so on. Finally, we argue that the anomalously low kinetic freezeout temperature at the BNL Relativistic Heavy Ion Collider suggests the possibility of the existence of the CEP.Comment: 13 pages, 12 figures, accepted for publication in Physical Review