Hydrogen diffusion and the percolation of austenite in nanostructured bainitic steel

The diffusion of hydrogen in austenite is slower than in ferrite. Experiments have been conducted to study the behaviour of hydrogen in a nanostructured steel sample consisting of a mixture of thin plates of bainitic ferrite and intervening films of retained austenite, with the latter phase present in a quantity larger than the percolation threshold, i.e. it has three-dimensional connectivity. The structure was then heat treated to control the fraction of austenite, and hence to study the role of hydrogen when the austenite decomposes below the value required to sustain percolation. The experiments have involved both thermal desorption analysis and permeation, and when combined with theoretical analysis, indicate a significant influence of percolating austenite in hindering the passage of hydrogen into the steel during hydrogen charging, and its permeation through the composite nanostructure. The effect is not as large as might be expected from a simple comparison of independent data on the diffusivities of hydrogen in the two lattices, because the effective diffusivity in ferrite is found to be much smaller than in the defect-free ferrite, owing to trapping effects. The morphology of the austenite is demonstrated to play a role by comparing with a sample containing a larger volume fraction of austenite but present as isolated grains which are ineffective to the permeation of hydrogen.X1199Ysciescopu

Strength and toughness of clean nanostructured bainite

A nanostructured steel has been produced using a clean steel-making technique. The mechanical properties have been comprehensively characterised. The maximum strength of the material recorded was 2.2 GPa at yield, with an ultimate tensile strength of 2.5 GPa, accompanied by a Charpy impact energy of 5 J, achieved by heat treatment to refine the prior austenite grain size from 145 to 20 µm. This increased the strength by 40% and the Charpy V-notch energy more than doubled. In terms of resistance of the hardness to tempering, the behaviour observed was similar to previous alloys. Despite reducing the hardness and strength, tempering was observed to reduce the plane-strain fracture toughness.This work was supported by Rolls-Royce

Shear band structure in ballistically tested bainitic steels

Adiabatic shear bands represent intense plastic deformation that is localised because the rate at which the heat generated by deformation is greater than that at which it is dissipated. The structure of such bands generated by ballistic testing is examined in order to reveal the governing mechanisms. We attempt to distinguish in particular whether local reaustenitisation occurs, or if the microstructural change are a reflection simply of intense deformation.This is the preprint version of the article originally submitted to the journal. The final version is published by Maney and can be found here: http://www.maneyonline.com/doi/abs/10.1179/1743284713Y.0000000403

Hydrogen diffusion and the percolation of austenite in nanostructured bainitic steel

The diffusion of hydrogen in austenite is slower than in ferrite. Experiments have been conducted to study the behaviour of hydrogen in a nanostructured steel sample consisting of a mixture of thin plates of bainitic ferrite and intervening films of retained austenite, with the latter phase present in a quantity larger than the percolation threshold, i.e. it has three-dimensional connectivity. The structure was then heat treated to control the fraction of austenite, and hence to study the role of hydrogen when the austenite decomposes below the value required to sustain percolation. The experiments have involved both thermal desorption analysis and permeation, and when combined with theoretical analysis, indicate a significant influence of percolating austenite in hindering the passage of hydrogen into the steel during hydrogen charging, and its permeation through the composite nanostructure. The effect is not as large as might be expected from a simple comparison of independent data on the diffusivities of hydrogen in the two lattices, because the effective diffusivity in ferrite is found to be much smaller than in the defect-free ferrite, owing to trapping effects. The morphology of the austenite is demonstrated to play a role by comparing with a sample containing a larger volume fraction of austenite but present as isolated grains which are ineffective to the permeation of hydrogen.The authors are grateful to the Worshipful Company of Ironmongers, Tata Steel UK, the EPSRC, to theWorld Class University Programme of the National Research Foundation of Korea, Ministry of Education, Science and Technology, project number R32–2008–000–10147–0, and the POSCO Steel Innovation Programme for supporting this work.This is the final published version. It's also available from the Royal Society at http://rspa.royalsocietypublishing.org/content/470/2168/20140108.full