Biocompatible functionalisation of nanoclays for improved environmental remediation

Among the wide range of materials used for remediating environmental contaminants, modified and functionalised nanoclays show particular promise as advanced sorbents, improved dispersants, or biodegradation enhancers. However, many chemically modified nanoclay materials are incompatible with living organisms when they are used in natural systems with detrimental implications for ecosystem recovery. Here we critically review the pros and cons of functionalised nanoclays and provide new perspectives on the synthesis of environmentally friendly varieties. Particular focus is given to finding alternatives to conventional surfactants used in modified nanoclay products, and to exploring strategies in synthesising nanoclay-supported metal and metal oxide nanoparticles. A large number of promising nanoclay-based sorbents are yet to satisfy environmental biocompatibility in situ but opportunities are there to tailor them to produce "biocompatible" or regenerative/reusable materials

Cretaceous age, composition, and microstructure of pseudotachylyte in the Otago Schist, New Zealand

At Tucker Hill, in Central Otago, New Zealand, a series of pseudotachylyte veins are hosted in quartzofeldspathic schist. Chilled margins, microlites, flow banding, and the crystallisation of mineral phases absent from the host rock provide unequivocal evidence for melting during pseudotachylyte formation. Whole rock analyses of pseudotachylyte reveal c. 3× enrichment of K2O, Ba, and Rb, and similar depletion of Na2O, CaO, Sr, and Eu, as compared to host schist. Formation age of pseudotachylyte is 95.9±1.8 Ma as measured by total fusion 40Ar/39Ar analyses. Stepwise heating of pseudotachylyte matrix yields an excellently defined 40Ar/39Ar plateau age of 96.0±0.3 Ma. These well-defined ages are attributed to the presence of potassium feldspar, low abundance of inherited lithic material from the host rock, and few fluid inclusions containing extraneous Ar. We propose that formation of these pseudotachylyte veins was related to Cretaceous extensional uplift and exhumation of the Otago Schist