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Das System der Obligations foncières und der Pfandbriefe ::in Frankreich, Deutschland, Österreich und nach den Bestimmungen des schweiz. Zivilgesetzbuches /
First Enantioselective Synthesis of Vinyl Oxiranes from Aldehydes and Ylides Generated from Allyl Halides and Chiral Sulfides.
First Enantioselective Synthesis of Vinyl Oxiranes from Aldehydes and Ylides Generated from Allyl Halides and Chiral Sulfides
Asymmetric allylidenation of aldehydes with
sulfur ylides is possible with proper substitution of the initial
sulfide, to avoid the [2,3] sigmatropic rearrangement of the
unsaturated ylides. One-pot reaction of (2R,5R)-dimethylthiolane with allyl halides, aldehydes, and sodium hydroxide
in tert-butyl alcohol affords vinyl oxiranes in good yields.
Enantiomeric excesses up to 90% and trans selectivities have
been achieved with methallyl-type halides
