Large Scale Structures a Gradient Lines: the case of the Trkal Flow

A specific asymptotic expansion at large Reynolds numbers (R)for the long wavelength perturbation of a non stationary anisotropic helical solution of the force less Navier-Stokes equations (Trkal solutions) is effectively constructed of the Beltrami type terms through multi scaling analysis. The asymptotic procedure is proved to be valid for one specific value of the scaling parameter,namely for the square root of the Reynolds number (R).As a result large scale structures arise as gradient lines of the energy determined by the initial conditions for two anisotropic Beltrami flows of the same helicity.The same intitial conditions determine the boundaries of the vortex-velocity tubes, containing both streamlines and vortex linesComment: 27 pages, 2 figure

Direct optical observations of surface thermal motions at sub-shot noise levels

We measure spectral properties of surface thermal fluctuations of liquids, solids, complex fluids and biological matter using light scattering methods. The random thermal fluctuations are delineated from random noise at sub-shot noise levels. The principle behind this extraction, which is quite general and is not limited to surface measurements, is explained. An optical lever is used to measure the spectrum of fluctuations in the inclinations of surfaces down to $\sim 10^{-17}\rm rad^2/Hz$ at $1\sim10 \mu$W optical intensity, corresponding to $\sim 10^{-29} \rm m^2/\rm Hz$ in the vertical displacement, in the frequency range $1{\rm}\rm kHz\sim10 MHz$. The dynamical evolution of the surface properties is also investigated. The measurement requires only a short amount of time and is essentially passive, so that it can be applied to a wide variety of surfaces.Comment: 5pp, 5 figure

The profile of a narrow line after single scattering by Maxwellian electrons: relativistic corrections to the kernel of the integral kinetic equation

The frequency distribution of photons in frequency that results from single Compton scattering of monochromatic radiation on thermal electrons is derived in the mildly relativistic limit. Algebraic expressions are given for (1) the photon redistribution function, K(nu,Omega -> nu',Omega'), and (2) the spectrum produced in the case of isotropic incident radiation, P(nu -> nu'). The former is a good approximation for electron temperatures kT_e < 25 keV and photon energies hnu < 50 keV, and the latter is applicable when hnu(hnu/m_ec^2) < kT_e < 25 keV, hnu < 50 keV. Both formulae can be used for describing the profiles of X-ray and low-frequency lines upon scattering in hot, optically thin plasmas, such as present in clusters of galaxies, in the coronae of accretion disks in X-ray binaries and AGNs, during supernova explosions, etc. Both formulae can also be employed as the kernels of the corresponding integral kinetic equations (direction-dependent and isotropic) in the general problem of Comptonization on thermal electrons. The K(nu,Omega -> nu',Omega') kernel, in particular, is applicable to the problem of induced Compton interaction of anisotropic low-frequency radiation of high brightness temperature with free electrons in the vicinity of powerful radiosources and masers. Fokker-Planck-type expansion (up to fourth order) of the integral kinetic equation with the P(nu -> nu') kernel derived here leads to a generalization of the Kompaneets equation. We further present (1) a simpler kernel that is necessary and sufficient to derive the Kompaneets equation and (2) an expression for the angular function for Compton scattering in a hot plasma, which includes temperature and photon energy corrections to the Rayleigh angular function.Comment: 29 pages, 17 figures, accepted for publication in ApJ, uses emulateapj.sty, corrects misprints in previous astro-ph versio

Nonlinear Dynamics of Capacitive Charging and Desalination by Porous Electrodes

The rapid and efficient exchange of ions between porous electrodes and aqueous solutions is important in many applications, such as electrical energy storage by super-capacitors, water desalination and purification by capacitive deionization (or desalination), and capacitive extraction of renewable energy from a salinity difference. Here, we present a unified mean-field theory for capacitive charging and desalination by ideally polarizable porous electrodes (without Faradaic reactions or specific adsorption of ions) in the limit of thin double layers (compared to typical pore dimensions). We illustrate the theory in the case of a dilute, symmetric, binary electrolyte using the Gouy-Chapman-Stern (GCS) model of the double layer, for which simple formulae are available for salt adsorption and capacitive charging of the diffuse part of the double layer. We solve the full GCS mean-field theory numerically for realistic parameters in capacitive deionization, and we derive reduced models for two limiting regimes with different time scales: (i) In the "super-capacitor regime" of small voltages and/or early times where the porous electrode acts like a transmission line, governed by a linear diffusion equation for the electrostatic potential, scaled to the RC time of a single pore. (ii) In the "desalination regime" of large voltages and long times, the porous electrode slowly adsorbs neutral salt, governed by coupled, nonlinear diffusion equations for the pore-averaged potential and salt concentration

Nonlinear dynamics of surfactant-laden two-fluid Couette flows in the presence of inertia

The nonlinear stability of immiscible two–fluid Couette flows in the presence of inertia is considered. The interface between the two viscous fluids can support insoluble surfactants and the interplay between the underlying hydrodynamic instabilities and Marangoni ef- fects is explored analytically and computationally in both two and three dimensions. Asymptotic analysis when one of the layers is thin relative to the other yields a coupled system of nonlinear equations describing the spatiotemporal evolution of the interface and its local surfactant concentration. The system is nonlocal and arises by appropri- ately matching solutions of the linearised Navier–Stokes equations in the thicker layer to the solution in the thin layer. The scaled models are used to study different physical mechanisms by varying the Reynolds number, the viscosity ratio between the two layers, the total amount of surfactant present initially and a scaled P ́eclet number measuring diffusion of surfactant along the interface. The linear stability of the underlying flow to two– and three–dimensional disturbances is investigated and a Squire’s type theorem is found to hold when inertia is absent. When inertia is present, three–dimensional distur- bances can be more unstable than two–dimensional ones and so Squire’s theorem does not hold. The linear instabilities are followed into the nonlinear regime by solving the evo- lution equations numerically; this is achieved by implementing highly accurate linearly implicit schemes in time with spectral discretisations in space. Numerical experiments for finite Reynolds numbers indicate that for two–dimensional flows the solutions are mostly nonlinear travelling waves of permanent form, even though these can lose stabil- ity via Hopf bifurcations to time–periodic travelling waves. As the length of the system (that is the wavelength of periodic waves) increases, the dynamics become more complex and include time–periodic, quasi–periodic as well as chaotic fluctuations. It is also found that one–dimensional interfacial travelling waves of permanent form can become unstable to spanwise perturbations for a wide range of parameters, producing three–dimensional flows with interfacial profiles that are two–dimensional and travel in the direction of the underlying shear. Nonlinear flows are also computed for parameters which predict linear instability to three–dimensional disturbances but not two–dimensional ones. These are found to have a one–dimensional interface in a rotated frame with respect to the direction of the underlying shear and travel obliquely without changing form

Random Sequential Adsorption: From Continuum to Lattice and Pre-Patterned Substrates

The random sequential adsorption (RSA) model has served as a paradigm for diverse phenomena in physical chemistry, as well as in other areas such as biology, ecology, and sociology. In the present work, we survey aspects of the RSA model with emphasis on the approach to and properties of jammed states obtained for large times in continuum deposition versus that on lattice substrates, and on pre-patterned surfaces. The latter model has been of recent interest in the context of efforts to use pre-patterning as a tool to improve selfassembly in micro- and nanoscale surface structure engineering

Einstein's "Zur Elektrodynamik..." (1905) Revisited, with Some Consequences

Einstein, in his "Zur Elektrodynamik bewegter Korper", gave a physical (operational) meaning to "time" of a remote event in describing "motion" by introducing the concept of "synchronous stationary clocks located at different places". But with regard to "place" in describing motion, he assumed without analysis the concept of a system of co-ordinates. In the present paper, we propose a way of giving physical (operational) meaning to the concepts of "place" and "co-ordinate system", and show how the observer can define both the place and time of a remote event. Following Einstein, we consider another system "in uniform motion of translation relatively to the former". Without assuming "the properties of homogeneity which we attribute to space and time", we show that the definitions of space and time in the two systems are linearly related. We deduce some novel consequences of our approach regarding faster-than-light observers and particles, "one-way" and "two-way" velocities of light, symmetry, the "group property" of inertial reference frames, length contraction and time dilatation, and the "twin paradox". Finally, we point out a flaw in Einstein's argument in the "Electrodynamical Part" of his paper and show that the Lorentz force formula and Einstein's formula for transformation of field quantities are mutually consistent. We show that for faster-than-light bodies, a simple modification of Planck's formula for mass suffices. (Except for the reference to Planck's formula, we restrict ourselves to Physics of 1905.)Comment: 55 pages, 4 figures, accepted for publication in "Foundations of Physics

Statics and Dynamics of an Interface in a Temperature Gradient

The response and nonconserved dynamics of a two-phase interface in the presence of a temperature gradient oriented normally to the interface are considered. Two types of boundary conditions on the order parameter are considered, and the structure of the effective free energy and the Langevin equation for the collective coordinate specifying the interface position are analyzed.Comment: 15 pages, Revtex 3.0, 5 figures available upon reques

Anomalous temperature dependence of surface tension and capillary waves at liquid gallium

The temperature dependence of surface tension \gamma(T) at liquid gallium is studied theoretically and experimentally using light scattering from capillary waves. The theoretical model based on the Gibbs thermodynamics relates the temperature derivative of \gamma to the surface excess entropy -\Delta S. Although capillary waves contribute to the surface entropy with a positive sign the effect of dipole layer on \Delta S is negative. Experimental data collected at a free Ga surface in the temperature range from 30 to 160 C show that the temperature derivative of the tension changes sign near 100 C.Comment: 11 pages, 1 Postscript figure, submitted to J. Phys.