11,177 research outputs found

    Quantum-state input-output relations for absorbing cavities

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    The quantized electromagnetic field inside and outside an absorbing high-QQ cavity is studied, with special emphasis on the absorption losses in the coupling mirror and their influence on the outgoing field. Generalized operator input-output relations are derived, which are used to calculate the Wigner function of the outgoing field. To illustrate the theory, the preparation of the outgoing field in a Schr\"{o}dinger cat-like state is discussed.Comment: 12 pages, 5 eps figure

    Total synthesis and biological evaluation of the tetramic acid based natural product harzianic acid and its stereoisomers

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    Financial support for this project was provided by Cancer Research UK (Grant No. C21383/A6950)The bioactive natural product harzianic acid was prepared for the first time in just six steps (longest linear sequence) with an overall yield of 22%. The identification of conditions to telescope amide bond formation and a Lacey-Dieckmann reaction into one pot proved important. The three stereoisomers of harzianic acid were also prepared, providing material for comparison of their biological activity. While all of the isomers promoted root growth, improved antifungal activity was unexpectedly associated with isomers in the enantiomeric series opposite that of harzianic acid.Publisher PDFPeer reviewe

    Rapid, selective and stable HaloTag-Lb ADH immobilization directly from crude cell extract for the continuous biocatalytic production of chiral alcohols and epoxides

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    A strategy for biocatalyst immobilization in flow directly from the crude cell extract is described.EPSRC (Award Nos. EP/K009494/1 and EP/K039520/1), the German Federal Ministry of Education and Research (BMBF) within the project “Molecular Interaction Engineering” (funding code 031A095)

    Competitiveness and sustainability: can ‘smart city regionalism’ square the circle?

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    Increasingly, the widely established, globalisation-driven agenda of economic competitiveness meets a growing concern with sustainability. Yet, the practical and conceptual co-existence—or fusion—of these two agendas is not always easy. This includes finding and operationalising the ‘right’ scale of governance, an important question for the pursuit of the distinctly transscalar nature of these two policy fields. ‘New regionalism’ has increasingly been discussed as a pragmatic way of tackling the variable spatialities associated with these policy fields and their changing articulation. This paper introduces ‘smart (new) city-regionalism’, derived from the principles of smart growth and new regionalism, as a policy-shaping mechanism and analytical framework. It brings together the rationales, agreed principles and legitimacies of publicly negotiated polity with collaborative, network-based and policy-driven spatiality. The notion of ‘smartness’, as suggested here as central feature, goes beyond the implicit meaning of ‘smart’ as in ‘smart growth’. When introduced in the later 1990s the term embraced a focus on planning and transport. Since then, the adjective ‘smart’ has become used ever more widely, advocating innovativeness, participation, collaboration and co-ordination. The resulting ‘smart city regionalism’ is circumscribed by the interface between the sectorality and territoriality of policy-making processes. Using the examples of Vancouver and Seattle, the paper looks at the effects of the resulting specific local conditions on adopting ‘smartness’ in the scalar positioning of policy-making

    Positronium Hyperfine Splitting in Non-commutative Space at the Order α6\alpha^6

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    We obtain positronium Hyperfine Splitting owing to the non-commutativity of space and show that, in the leading order, it is proportional to θα6\theta \alpha^6 where, θ\theta is the parameter of non-commutativity. It is also shown that spatial non-commutativity splits the spacing between n=2n=2 triplet excited levels E(23S1)E(23P2)E(2^3S_1)\to E(2^3P_2) which provides an experimental test on the non-commutativity of space.Comment: 7 pages, 2 figures, to appear in Phys. Rev.

    Dynamics of core and occasional species in the marine plankton: tintinnid ciliates in the north-west Mediterranean Sea

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    International audienceTo assess short-term variability in the community composition and community structure of tintinnid ciliates, herbivores of the microzooplankton. Location North-west Mediterranean Sea. We sampled on 18 dates over a 4-week period in 2004 at an openwater site. Species were classified as 'core species', found on every date, or 'occasional species', absent on one or more dates. Species abundance distributions of the entire community, and separately the core and occasional species, were compared with geometric, log-series and log-normal distributions. Core and occasional species were compared in terms of the shell or lorica oral diameter (LOD), analogous to gape size. We found 11 core and 49 occasional species. Diversity metrics were stable compared with shifts in abundances. Core species accounted for the majority of individuals in all samples. On each date, 9-22 occasional species, representing 10-15% of the population, were found. Species richness of the occasionals was positively related to population size. The identities of the occasional species found were unrelated to the time between sampling. The species abundance distribution of the occasional population was best fit by a log-series distribution, while that of the core species was best fit by a log-normal distribution. The species abundance distribution of the entire community was best fit by a log-series distribution. Most of the occasional species had LODs distinct from that of a core species and occupied size classes left empty by the core population. However, the most abundant and frequent of the occasional species had a LOD similar to that of a core species. Among tintinnids, which are planktonic protists, occasional species have a species abundance distribution pattern distinct from that of core species. Occasional species appeared to be composed of two groups, one of relatively abundant species and similar to core species, and a second group of ephemeral species with morphologies distinct from core species. The existence of two categories of occasional or rare species may be common: (1) those similar to, and thus perhaps able to replace, dominant species in the absence of a change in the environment; and (2) those distinct from dominant species and requiring different conditions to prosper

    First Digit Distribution of Hadron Full Width

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    A phenomenological law, called Benford's law, states that the occurrence of the first digit, i.e., 1,2,...,91,2,...,9, of numbers from many real world sources is not uniformly distributed, but instead favors smaller ones according to a logarithmic distribution. We investigate, for the first time, the first digit distribution of the full widths of mesons and baryons in the well defined science domain of particle physics systematically, and find that they agree excellently with the Benford distribution. We also discuss several general properties of Benford's law, i.e., the law is scale-invariant, base-invariant, and power-invariant. This means that the lifetimes of hadrons follow also Benford's law.Comment: 8 latex pages, 4 figures, final version in journal publicatio
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