Multiscale model of global inner-core anisotropy induced by hcp-alloy plasticity

$\bullet$ Multiscale model of inner-core anisotropy produced by hcp alloy deformation$\bullet$ 5 to 20% single-crystal elastic anisotropy and plastic deformation by pyramidal slip $\bullet$ Low-degree inner-core formation model with faster crystallization at the equatorThe Earth's solid inner-core exhibits a global seismic anisotropy of several percents. It results from a coherent alignment of anisotropic Fe-alloy crystals through the inner-core history that can be sampled by present-day seismic observations. By combining self-consistent polycrystal plasticity, inner-core formation models, Monte-Carlo search for elastic moduli, and simulations of seismic measurements, we introduce a multiscale model that can reproduce a global seismic anisotropy of several percents aligned with the Earth's rotation axis. Conditions for a successful model are an hexagonal-close-packed structure for the inner-core Fe-alloy, plastic deformation by pyramidal \textless{}c+a\textgreater{} slip, and large-scale flow induced by a low-degree inner-core formation model. For global anisotropies ranging between 1 and 3%, the elastic anisotropy in the single crystal ranges from 5 to 20% with larger velocities along the c-axis

Is inner core seismic anisotropy a marker for plastic flow of cubic iron?

International audienceThis paper investigates whether observations of seismic anisotropy are compatible with a cubic structure of the inner core Fe alloy.We assume that anisotropy is the result of plastic deformation within a large scale flow induced by preferred growth at the inner core equator. Based on elastic moduli from the literature, bcc- or fcc-Fe produce seismic anisotropy well below seismic observations ($<0.4\%$). A Monte-Carlo approach allows us to generalize this result to any form of elastic anisotropy in a cubic system. Within our model, inner core global anisotropy is not compatible with a cubic structure of Fe alloy.Hence, if the inner core material is indeed cubic, large scale coherent anisotropic structures, incompatible with plastic deformation induced by large scale flow, must be present

Seismic response and anisotropy of a model hcp iron inner core

International audienceWe present a framework for simulating the measurement of seismic anisotropy in a model inner core by computing travel time residuals of synthetic seismic rays propagated through the model. The method is first tested on simple inner core structural models consisting of layers with distinct anisotropy, as often proposed in the literature. Those models are not consistent with geodynamics. Hence, we extend the method to a numerically grown inner core composed of ε-Fe with flow generated from an excess of crystallization in the equatorial belt, inducing polycrystalline textures. The global inner core anisotropy is 7 times smaller than that of the single crystal. Compositional stratification amplifies the global anisotropy by 15% while the addition of solidification textures reduces it by a factor of 2. As such, and within the tested geodynamical models, no published elastic model of ε-Fe at inner core conditions allows for reproducing the 3% cylindrical anisotropy reported in seismology publications. In addition, our models demonstrate that additional information such as the depth dependence and the spread of the observed anisotropy is a key for revealing the dynamics and history of the inner core

Preparation of Cu(In,Ga)Se2 photovoltaic absorbers by an aqueous metal selenite co-precipitation route

In this paper, we report a novel and simple solution-based approach for the fabrication of chalcopyrite Cu(In,Ga)Se2 thin film solar cells. An aqueous co-precipitation method based on metal selenites, M2(SeO3)x (M = Cu, In, Ga) precursors was investigated. The resulting powder, dispersed in a binder to form an ink, was coated on a substrate by doctor blade technique. A soft annealing treatment allowed the reduction of metal selenites into selenides. Further rapid thermal processing (RTP) achieved crystalline chalcopyrite absorber. The obtained layer provides good compositional control and adequate morphology for solar cell applications. The water-based synthesis is a sustainable and simple procedure, and together with doctor blade printing, provides a potential cost-effective advantage over conventional fabrication processes (vacuum-based deposition techniques). The short circuit current (JSC), open circuit voltage (VOC), fill factor (FF), and total area power conversion efficiency (Eff.) of the device are 26 mA/cm2, 450 mV, 62%, and 7.2%, respectively. The effective band gap of 1.12 eV confirmed Ga-incorporation in the CIGS crystal lattice.This work was supported by the Spanish Ministry of Science and Competiveness under INNPACTO Program (IPT-2011-0913- 920000). The authors would like to thanks to Manuel Ocana Jurado ~ (ICMS-CISC) for his help in the XPS measurements. L. Oliveira would like to thank the support of the National Council for Scientific and Technological Development (CNPq) e Brazil

Electrodeposition of In2S3 buffer layer for Cu(In,Ga)Se2 solar cells

AbstractThe electrochemical deposition of In2S3 thin films was carried out from an aqueous solution of InCl3 and Na2S2O3. The effect of the potential of deposition was studied on the cell parameters of CIGSe based solar cells. The obtained films depending on the deposition potential and thickness exhibited complete substrate coverage or nanocolumnar layers. XPS measurements detected the presence of indium sulphide and hydroxide depending on the deposition parameters. Maximum photoelectric conversion efficiency of 10.2% was obtained, limited mainly by a low fill factor (56%). Further process optimization is expected to lead to efficiencies comparable to CdS buffer layers

Electrochemical integration of graphene with light absorbing copper-based thin films

We present an electrochemical route for the integration of graphene with light sensitive copper-based alloys used in optoelectronic applications. Graphene grown using chemical vapor deposition (CVD) transferred to glass is found to be a robust substrate on which photoconductive Cu_{x}S films of 1-2 um thickness can be deposited. The effect of growth parameters on the morphology and photoconductivity of Cu_{x}S films is presented. Current-voltage characterization and photoconductivity decay experiments are performed with graphene as one contact and silver epoxy as the other

Electro-plating and characterisation of cadmium sulphide thin films using ammonium thiosulphate as the sulphur source

Cadmium sulphide (CdS) thin films have been successfully prepared from an aqueous electrolyte bath containing CdCl2 and ammonium thiosulphate ((NH4)2S2O3) using electrodeposition technique. The structural, compositional, optical, morphological and electrical properties of these thin films have been characterized using X-ray diffraction (XRD), Raman spectroscopy, energy dispersive X-ray spectroscopy, UV–Vis spectrophotometry, scanning electron microscopy (SEM), atomic force microscopy (AFM), photoelectrochemical cell and D.C. current–voltage (I–V) measurements. The optimum deposition cathodic potential has been observed at 1,455 mV, in a 2-electrode system with respect to carbon anode. Structural analysis using XRD shows a mixture of hexagonal and cubic phases in the as-deposited CdS samples and a phase transformation to the hexagonal structure occurred after heat treatment at 400 °C for 20 min. Optical studies demonstrate an improvement in the band edge, producing 2.42 eV for the band gap of the films after heat treatment. The heat treated CdS thin films show better transmission for wavelengths longer than 500 nm. SEM and AFM show that the heat-treated samples are more uniform, smoother and have larger grain size. Electrical studies confirm that the CdS thin films have n-type electrical conductivity and heat treated CdS thin films have resistivities of the order of 105 Ω cm

Shu-mei Shih, Visuality and Identity. Sinophone Articulation across the Pacific, Berkeley, University Press of California, 2007, 244 p.

Professeur de littérature comparée à l’université de Californie de Los Angeles (UCLA), spécialiste des « gender studies », Shu-mei Shih aborde d’une manière originale, dans ce nouvel ouvrage, la question de l’identité dans le monde sinophone actuel. Long de 244 pages, Visuality and Identity. Sinophone Articulations across the Pacific, est composé d’une introduction et de six parties : la première porte sur la globalisation et ses effets sur les minorités, la deuxième sur le cas, plus précis, ..

Wu Hung, Making History: Wu Hung on Contemporary Art andWu Hung on Contemporary Chinese Artists

Wu Hung, Making History: Wu Hung on Contemporary Art, Hong Kong, Time Zone 8, 2008. Wu Hung on Contemporary Chinese Artists, Hong Kong, Time Zone 8, 2009. University of Chicago art history professor Wu Hung has written two important works published by Time Zone 8, a publisher specialising in Chinese contemporary art under the direction of Beijing-based Robert Bernell. Making History is reminiscent of L’écriture de l’histoire (The Writing of History)by Michel de Certeau, but focuses on an enti..