Phase transitions in generalized chiral or Stiefel's models

We study the phase transition in generalized chiral or Stiefel's models using Monte Carlo simulations. These models are characterized by a breakdown of symmetry O(N)/O(N-P). We show that the phase transition is clearly first order for N >= 3 when P=N and P=N-1, contrary to predictions based on the Renormalization Group in 4-\epsilon expansion but in agreement with a recent non perturbative Renormalization Group approach.Comment: 9 pages, 8 figure

Origine, phylogénie, évolution des espèces du genre Ananas

Après un bref rappel de l'état des connaissances bibliographiques sur la classification et l'origine des espèces d'ananas, l'auteur se base sur les résultats obtenus par l'IRFA en matière d'analyse des ressources génétiques du genre pour proposer une évolution continue de la plante expliquée par l'utilisation de la reproduction sexuée au niveau des populations naturelles organisées en complexes d'espèces. Il en ressort une thèse dynamique qui se démarque des nombreux essais de classifications à caractère statique trouvés jusqu'à présent dans la littérature. (Résumé d'auteur

Fluctuations and Defects in Lamellar Stacks of Amphiphilic Bilayers

We review recent molecular dynamics simulations of thermally activated undulations and defects in the lamellar $L_\alpha$ phase of a binary amphiphile-solvent mixture, using an idealized molecular coarse-grained model: Solvent particles are represented by beads, and amphiphiles by bead-and-spring tetramers. We find that our results are in excellent agreement with the predictions of simple mesoscopic theories: An effective interface model for the undulations, and a line tension model for the (pore) defects. We calculate the binding rigidity and the compressibility modulus of the lamellar stack as well as the line tension of the pore rim. Finally, we discuss implications for polymer-membrane systems.Comment: to appear in Computer Physics Communications (2005

Fabricating management practices : "Responsible Care" and Corporate Social Responsibility.

Purpose this study focuses on the policy of Corporate Social Responsibility (CSR) launched in the chemical industry in the 1980s and known as “Responsible Care”. The debate surrounding this issue prompts us to question the ever-changing nature of this policy and the way to measure the performance achieved. Methodology Our findings are drawn from analysis of a double set of data including a longitudinal survey and a current case study. Blending these two data sets allows a better understanding of the ongoing building process of “Responsible Care” and, more broadly, of corporate social responsibility. Findings this paper asserts that, contrary to the common wisdom developed in research, companies do not simply react to stakeholder pressure. Companies autonomously develop ways to protect their environment and so contribute to changing Society's expectations. Thus, performance cannot be read without a dynamic perspective in mind. Research limitations/implications Our findings lead us to reconsider the assessment of companies' sustainable performances by taking into account the fabricating process of sustainable activities. The main limitation of this research stems from the single unit of analysis considered. Broader studies will be necessary to enrich our understanding of corporate policies. Originality/value of the paper Our paper stands apart from the traditional view of organizations as cynical actors and attempts to provide a more complex picture of the behaviours observed.Performance management; Performance measurement; “Responsible Care”; Corporate Social Responsibility;

Isotopic fractionation of carbon, deuterium and nitrogen : a full chemical study

Context. The increased sensitivity and high spectral resolution of millimeter telescopes allow the detection of an increasing number of isotopically substituted molecules in the interstellar medium. The 14N/ 15N ratio is difficult to measure directly for carbon containing molecules. Aims. We want to check the underlying hypothesis that the 13C/ 12C ratio of nitriles and isonitriles is equal to the elemental value via a chemical time dependent gas phase chemical model. Methods. We have built a chemical network containing D, 13C and 15N molecular species after a careful check of the possible fractionation reactions at work in the gas phase. Results. Model results obtained for 2 different physical conditions corresponding respectively to a moderately dense cloud in an early evolutionary stage and a dense depleted pre-stellar core tend to show that ammonia and its singly deuterated form are somewhat enriched in 15N, in agreement with observations. The 14N/ 15N ratio in N2H+ is found to be close to the elemental value, in contrast to previous models which obtain a significant enrichment, as we found that the fractionation reaction between 15N and N2H+ has a barrier in the entrance channel. The large values of the N2H+/15NNH+ and N2H+/ N15NH+ ratios derived in L1544 cannot be reproduced in our model. Finally we find that nitriles and isonitriles are in fact significantly depleted in 13C, questioning previous interpretations of observed C15N, HC15N and H15NC abundances from 13C containing isotopologues.Comment: 21 pages, 9 figures in the text, 3 Figures in the appendices. 7 tables in the text, 4 tables in the appendices. Accepted for publication by Astronomy Astrophysic

The interstellar gas-phase chemistry of HCN and HNC

We review the reactions involving HCN and HNC in dark molecular clouds to elucidate new chemical sources and sinks of these isomers. We find that the most important reactions for the HCN-HNC system are Dissociative Recombination (DR) reactions of HCNH+ (HCNH+ + e-), the ionic CN + H3+, HCN + C+, HCN and HNC reactions with H+/He+/H3+/H3O+/HCO+, the N + CH2 reaction and two new reactions: H + CCN and C + HNC. We test the effect of the new rate constants and branching ratios on the predictions of gas-grain chemical models for dark cloud conditions. The rapid C + HNC reaction keeps the HCN/HNC ratio significantly above one as long as the carbon atom abundance remains high. However, the reaction of HCN with H3+ followed by DR of HCNH+ acts to isomerize HCN into HNC when carbon atoms and CO are depleted leading to a HCN/HNC ratio close to or slightly greater than 1. This agrees well with observations in TMC-1 and L134N taking into consideration the overestimation of HNC abundances through the use of the same rotational excitation rate constants for HNC as for HCN in many radiative transfer models.Comment: Accepted for publication in MNRA