EXAFS study of nickel tetracarbonyl and nickel clusters in zeolite Y

Adsorption and thermal decomposition of Ni(CO)4 in the cage system of zeolite Y have been studied with EXAFS, electron microscopy and IR spectroscopy , Ni(CO)4 is adsorbed as an intact molecule in both cation - free zeolite Y and NaY. Symmetry changes of the molecule in NaY are assigned to the formation of Na—OC-IMi bridges. Thermal treatment of the Ni(CO)4/NaY adduct leads to loss of CO concomitant with the formation of a binodal Ni phase. A major part of the forms clusters with diameter between 0.5 and about 1.5 nm, in addition to larger crystallites (5-30 nm), sticking at the outer surface of the zeolite matrix., The Ni-Ni scattering amplitude indicates increasing average particle size with increasing temperature

EXAFS Analysis of Size-Constrained Semiconducting Materials

Semiconducting materials such as CdSe, CdS, PbS and GaP are included in crystalline zeolite Y and mordenite and structurally flexible ethylene-methacrylic acid copolymer solid matrices. EXAFS analysis reveals formation of species with dimensions of molecular size up to ca. 13 A in the crystalline hosts, while the polymer matrices allow agglomeration of larger semiconducting particles. Zeolite anchored structures are distinctively different to small particles with bulk crystal structure as usually found in colloidal systems

Constraining the Λ\LambdaCDM and Galileon models with recent cosmological data

The Galileon theory belongs to the class of modified gravity models that can explain the late-time accelerated expansion of the Universe. In previous works, cosmological constraints on the Galileon model were derived, both in the uncoupled case and with a disformal coupling of the Galileon field to matter. There, we showed that these models agree with the most recent cosmological data. In this work, we used updated cosmological data sets to derive new constraints on Galileon models, including the case of a constant conformal Galileon coupling to matter. We also explored the tracker solution of the uncoupled Galileon model. After updating our data sets, especially with the latest \textit{Planck} data and BAO measurements, we fitted the cosmological parameters of the $\Lambda$CDM and Galileon models. The same analysis framework as in our previous papers was used to derive cosmological constraints, using precise measurements of cosmological distances and of the cosmic structure growth rate. We showed that all tested Galileon models are as compatible with cosmological data as the $\Lambda$CDM model. This means that present cosmological data are not accurate enough to distinguish clearly between both theories. Among the different Galileon models, we found that a conformal coupling is not favoured, contrary to the disformal coupling which is preferred at the $2.3\sigma$ level over the uncoupled case. The tracker solution of the uncoupled Galileon model is also highly disfavoured due to large tensions with supernovae and \textit{Planck}+BAO data. However, outside of the tracker solution, the general uncoupled Galileon model, as well as the general disformally coupled Galileon model, remain the most promising Galileon scenarios to confront with future cosmological data. Finally, we also discuss constraints coming from Lunar Laser Ranging experiment and gravitational wave speed of propagation.Comment: 22 pages, 17 figures, published version in A&

Proton-neutron quadrupole interactions: an effective contribution to the pairing field

We point out that the proton-neutron energy contribution, for low multipoles (in particular for the quadrupole component), effectively renormalizes the strength of the pairing interaction acting amongst identical nucleons filling up a single-j or a set of degenerate many-j shells. We carry out the calculation in lowest-order perturbation theory. We perform a study of this correction in various mass regions. These results may have implications for the use of pairing theory in medium-heavy nuclei and for the study of pairing energy corrections to the liquid drop model when studying nuclear masses.Comment: 19 pages, TeX, 3 tables, 2 figures. Accepted in PR

An O(M(n) log n) algorithm for the Jacobi symbol

The best known algorithm to compute the Jacobi symbol of two n-bit integers runs in time O(M(n) log n), using Sch\"onhage's fast continued fraction algorithm combined with an identity due to Gauss. We give a different O(M(n) log n) algorithm based on the binary recursive gcd algorithm of Stehl\'e and Zimmermann. Our implementation - which to our knowledge is the first to run in time O(M(n) log n) - is faster than GMP's quadratic implementation for inputs larger than about 10000 decimal digits.Comment: Submitted to ANTS IX (Nancy, July 2010

Quantificação de caulinita em latossolo por difração de raios-X.

bitstream/item/31910/1/CPATU-BP39.pd

KCa 3.1-a microglial target ready for drug repurposing?

Over the past decade, glial cells have attracted attention for harboring unexploited targets for drug discovery. Several glial targets have attracted de novo drug discovery programs, as highlighted in this GLIA Special Issue. Drug repurposing, which has the objective of utilizing existing drugs as well as abandoned, failed, or not yet pursued clinical development candidates for new indications, might provide a faster opportunity to bring drugs for glial targets to patients with unmet needs. Here, we review the potential of the intermediate-conductance calcium-activated potassium channels KCa 3.1 as the target for such a repurposing effort. We discuss the data on KCa 3.1 expression on microglia in vitro and in vivo and review the relevant literature on the two KCa 3.1 inhibitors TRAM-34 and Senicapoc. Finally, we provide an outlook of what it might take to harness the potential of KCa 3.1 as a bona fide microglial drug target. GLIA 2016;64:1733-1741