Charge Freezing in Zig-zag Chain Cuprates PrBa2Cu4O8 Observed by Cu Nuclear Quadrupole Resonance

We report nuclear quadrupole resonance (NQR) studies on the chain Cu sites of PrBa$_{2}$Cu$_{4}$O$_{8}$, a quasi-one-dimensional conductor with a nearly quarter-filled band. The nuclear spin-lattice relaxation rate $1/T_{1}$ shows a pronounced peak near 100 K caused by fluctuations of electric field gradient (EFG). Similar peak was observed for the spin-echo decay rate $1/T_{2}$, however, at a different temperature near 50 K. These results and broadening of the NQR spectrum at low temperatures indicate that slow charge fluctuations of either electronic or ionic origin freeze gradually at low temperatures.Comment: 5 pages, 4 figure

Compensation of Effective Field in the Field-Induced Superconductor k-(BETS)2FeBr4 Observed by 77Se NMR

We report results of 77Se NMR frequency shift in the normal state of the organic charge-transfer-salt k-(BETS)2FeBr4 which shows magnetic field-induced superconductivity (FISC). From a simple mean field analysis, we determined the field and the temperature dependences of the magnetization m_{pi} of the \pi conduction electrons on BETS molecules. We found that the Fe spins are antiferromagnetically coupled to the pi electrons and determined the exchange field to be J = -2.3T/mu_B. The exchange field from the fully saturated Fe moments (5 mu_B) is compensated by an external field of 12T. This is close to the central field of the FISC phase, consistent with the Jaccarino-Peter local field-compensation mechanism for FISC (Phys. Rev. Lett. 9, 290 (1962))

Cluster dynamical mean-field study of the Hubbard model on a 3D frustrated hyperkagome lattice

We study the Hubbard model on a geometrically-frustrated hyperkagome lattice by a cluster extension of the dynamical mean field theory. We calculate the temperature ($T$) dependences of the specific heat ($C$) and the spin-lattice relaxation time ($T_1$) in correlated metallic region. $C/T$ shows a peak at $T=T_{p1}$ and rapidly decreases as $T->0$. On the other hand, $1/T_1T$ has a peak at a higher temperature $T_{p2}$ than $T_{p1}$, and largely decreases below $T_{p2}$, followed by the Korringa law $1/T_1 propto T$ as $T->0$. Both peak temperatures are suppressed and the peaks become sharper as electron correlation is increased. These behaviors originate from strong renormalization of the energy scales in the peculiar electronic structure in this frustrated system; a pseudo-gap like feature, the van-Hove singularity, and the flat band. The results are discussed in comparison with the experimental data in the hyperkagome material, Na$_4$Ir$_3$O$_8$.Comment: 4 pages, 4 figures, Conference proceedings for Highly Frustrated Magnetism 200

Weak antiferromagnetism of J_eff=1/2 band in bilayer iridate Sr3Ir2O7

The antiferromagnetic structure of Sr3Ir2O7, the bilayer analogue of a spin-orbital Mott insulator Sr2IrO4, was revealed by resonant magnetic x-ray diffraction. Contrasting intensities of the magnetic diffraction at the Ir LIII and LII edges show a Jeff=1/2 character of the magnetic moment as is argued in Sr2IrO4. The magnitude of moment, however, was found to be smaller than that of Sr2IrO4 by a factor of 5-6, implying that Sr3Ir2O7 is no longer a Mott insulator but a weak antiferromagnet. An evident change of the temperature dependence of the resistivity at TN, from almost temperature-independent resistivity to insulating, strongly suggests that the emergent weak magnetism controls the charge gap. The magnetic structure was found to be an out-of-plane collinear antiferromagnetic ordering in contrast to the inplane canted antiferromagnetism in Sr2IrO4, originating from the strong bilayer antiferromagnetic coupling

Temperature-driven transition from the Wigner Crystal to the Bond-Charge-Density Wave in the Quasi-One-Dimensional Quarter-Filled band

It is known that within the interacting electron model Hamiltonian for the one-dimensional 1/4-filled band, the singlet ground state is a Wigner crystal only if the nearest neighbor electron-electron repulsion is larger than a critical value. We show that this critical nearest neighbor Coulomb interaction is different for each spin subspace, with the critical value decreasing with increasing spin. As a consequence, with the lowering of temperature, there can occur a transition from a Wigner crystal charge-ordered state to a spin-Peierls state that is a Bond-Charge-Density Wave with charge occupancies different from the Wigner crystal. This transition is possible because spin excitations from the spin-Peierls state in the 1/4-filled band are necessarily accompanied by changes in site charge densities. We apply our theory to the 1/4-filled band quasi-one-dimensional organic charge-transfer solids in general and to 2:1 tetramethyltetrathiafulvalene (TMTTF) and tetramethyltetraselenafulvalene (TMTSF) cationic salts in particular. We believe that many recent experiments strongly indicate the Wigner crystal to Bond-Charge-Density Wave transition in several members of the TMTTF family. We explain the occurrence of two different antiferromagnetic phases but a single spin-Peierls state in the generic phase diagram for the 2:1 cationic solids. The antiferromagnetic phases can have either the Wigner crystal or the Bond-Charge-Spin-Density Wave charge occupancies. The spin-Peierls state is always a Bond-Charge-Density Wave.Comment: 12 pages, 8 EPS figures. Longer version of previous manuscript. Contains new numerical data as well as greatly expanded discussio

Superconductivity in Pr2Ba4Cu7O15-delta with metallic double chains

We report superconductivity with $T_{c,onset}$=$\sim$10K in Pr$_{2}$Ba$_{4}$Cu$_{7}$O$_{15-\delta}$ compound possessing metallic double chains. A reduction treatment on as-sintered samples causes not only the enhanced metallic conduction but also the appearance of superconductivity accompanied by the c-axis elongation due to oxygen deficiency

Spin dynamics and antiferromagnetic order in PrBa2Cu4O8 studied by Cu nuclear respnance

Results of the nuclear resonance experiments for the planar Cu sites in PrBa2Cu4O8 are presented. The NMR spectrum at 1.5 K in zero magnetic field revealed an internal field of 6.1 T, providing evidence for an antiferromagnetic order of the planar Cu spins. This confirms that the CuO2 planes are insulating, therefore, the metallic conduction in this material is entirely due to the one-dimensional zigzag Cu2O2 chains. The results of the spin-lattice relaxation rates measured by zero field NQR above 245 K in the paramagnetic state are explained by the theory for a Heisenberg model on a square lattice.Comment: 4 pages, 2 figure

Charge Segregation, Cluster Spin-Glass and Superconductivity in La1.94Sr0.06CuO4

A 63Cu and 139La NMR/NQR study of superconducting (Tc=7 K) La1.94Sr0.06CuO4 single crystal is reported. Coexistence of spin-glass and superconducting phases is found below ~5 K from 139La NMR relaxation. 63Cu and 139La NMR spectra show that, upon cooling, CuO2 planes progressively separate into two magnetic phases, one of them having enhanced antiferromagnetic correlations. These results establish the AF-cluster nature of the spin-glass. We discuss how this phase can be related to the microsegregation of mobile holes and to the possible pinning of charge-stripes.Comment: 4 pages. Modified manuscript with clarification