On the extra phase correction to the semiclassical spin coherent-state propagator

The problem of an origin of the Solary-Kochetov extra-phase contribution to the naive semiclassical form of a generalized phase-space propagator is addressed with the special reference to the su(2) spin case which is the most important in applications. While the extra-phase correction to a flat phase-space propagator can straightforwardly be shown to appear as a difference between the principal and the Weyl symbols of a Hamiltonian in the next-to-leading order expansion in the semiclassical parameter, the same statement for the semiclassical spin coherent-state propagator holds provided the Holstein-Primakoff representation of the su(2) algebra generators is employed.Comment: 19 pages, no figures; a more general treatment is presented, some references are added, title is slightly changed; submitted to JM

Spin Tunneling in Magnetic Molecules: Quasisingular Perturbations and Discontinuous SU(2) Instantons

Spin coherent state path integrals with discontinuous semiclassical paths are investigated with special reference to a realistic model for the magnetic degrees of freedom in the Fe8 molecular solid. It is shown that such paths are essential to a proper understanding of the phenomenon of quenched spin tunneling in these molecules. In the Fe8 problem, such paths are shown to arise as soon as a fourth order anisotropy term in the energy is turned on, making this term a singular perturbation from the semiclassical point of view. The instanton approximation is shown to quantitatively explain the magnetic field dependence of the tunnel splitting, as well as agree with general rules for the number of quenching points allowed for a given value of spin. An accurate approximate formula for the spacing between quenching points is derived

Bounds on Slow Roll at the Boundary of the Landscape

We present strong evidence that the tree level slow roll bounds of arXiv:1807.05193 and arXiv:1810.05506 are valid, even when the tachyon has overlap with the volume of the cycle wrapped by the orientifold. This extends our previous results in the volume-dilaton subspace to a semi-universal modulus. Emboldened by this and other observations, we investigate what it means to have a bound on (generalized) slow roll in a multi-field landscape. We argue that for $any$ point $\phi_0$ in an $N$-dimensional field space with $V(\phi_0) > 0$, there exists a path of monotonically decreasing potential energy to a point $\phi_1$ within a path length $\lesssim {\cal O}(1)$, such that $\sqrt{N}\ln \frac{V(\phi_1)}{V(\phi_0)} \lesssim - {\cal O} (1)$. The previous de Sitter swampland bounds are specific ways to realize this stringent non-local constraint on field space, but we show that it also incorporates (for example) the scenario where both slow roll parameters are intermediate-valued and the Universe undergoes a small number of e-folds, as in the Type IIA set up of arXiv:1310.8300. Our observations are in the context of tree level constructions, so we take the conservative viewpoint that it is a characterization of the classical "boundary" of the string landscape. To emphasize this, we argue that these bounds can be viewed as a type of Dine-Seiberg statement.Comment: v4: one more referenc

Quantum phase interference (Berry phase) in single-molecule magnets of Mn12

Magnetization measurements of a molecular clusters Mn12 with a spin ground state of S = 10 show resonance tunneling at avoided energy level crossings. The observed oscillations of the tunnel probability as a function of the magnetic field applied along the hard anisotropy axis are due to topological quantum phase interference of two tunnel paths of opposite windings. Mn12 is therefore the second molecular clusters presenting quantum phase interference.Comment: 3 pages, 4 figures, MMM'01 conference (12-16 Nov.

A two-step approach to achieve secondary amide transamidation enabled by nickel catalysis.

A long-standing challenge in synthetic chemistry is the development of the transamidation reaction. This process, which involves the conversion of one amide to another, is typically plagued by unfavourable kinetic and thermodynamic factors. Although some advances have been made with regard to the transamidation of primary amide substrates, secondary amide transamidation has remained elusive. Here we present a simple two-step approach that allows for the elusive overall transformation to take place using non-precious metal catalysis. The methodology proceeds under exceptionally mild reaction conditions and is tolerant of amino-acid-derived nucleophiles. In addition to overcoming the classic problem of secondary amide transamidation, our studies expand the growing repertoire of new transformations mediated by base metal catalysis

Where we stand on structure dependence of ISGMR in the Zr-Mo region: Implications on K_\infty

Isoscalar giant resonances, being the archetypal forms of collective nuclear behavior, have been studied extensively for decades with the goal of constraining bulk nuclear properties of the equation of state, as well as for modeling dynamical behaviors within stellar environments. An important such mode is the isoscalar electric giant monopole resonance (ISGMR) that can be understood as a radially symmetric density vibration within the saturated nuclear volume. The field has a few key open questions, which have been proposed and remain unresolved. One of the more provocative questions is the extra high-energy strength in the $A\approx 90$ region, which manifested in large percentages of the $E0$ sum rule in $^{92}$Zr and $^{92}$Mo above the main ISGMR peak. The purpose of this article is to introduce these questions within the context of experimental investigations into the phenomena in the zirconium and molybdenum isotopic chains, and to address, via a discussion of previously published and preliminary results, the implications of recent experimental efforts on extraction of the nuclear incompressibility from this data.Comment: 9 pages, 7 figures, invited to be submitted to a special issue of EPJA honoring Prof. P. F. Bortigno

Efficient algorithms for tensor scaling, quantum marginals and moment polytopes

We present a polynomial time algorithm to approximately scale tensors of any format to arbitrary prescribed marginals (whenever possible). This unifies and generalizes a sequence of past works on matrix, operator and tensor scaling. Our algorithm provides an efficient weak membership oracle for the associated moment polytopes, an important family of implicitly-defined convex polytopes with exponentially many facets and a wide range of applications. These include the entanglement polytopes from quantum information theory (in particular, we obtain an efficient solution to the notorious one-body quantum marginal problem) and the Kronecker polytopes from representation theory (which capture the asymptotic support of Kronecker coefficients). Our algorithm can be applied to succinct descriptions of the input tensor whenever the marginals can be efficiently computed, as in the important case of matrix product states or tensor-train decompositions, widely used in computational physics and numerical mathematics. We strengthen and generalize the alternating minimization approach of previous papers by introducing the theory of highest weight vectors from representation theory into the numerical optimization framework. We show that highest weight vectors are natural potential functions for scaling algorithms and prove new bounds on their evaluations to obtain polynomial-time convergence. Our techniques are general and we believe that they will be instrumental to obtain efficient algorithms for moment polytopes beyond the ones consider here, and more broadly, for other optimization problems possessing natural symmetries