Competing interactions of spin and lattice in the Kondo lattice model

The magnetic properties of a system of coexisting localized spins and conduction electrons are investigated within an extended version of the one dimensional Kondo lattice model in which effects stemming from the electron-lattice and on-site Coulomb interactions are explicitly included. After bosonizing the conduction electrons, is it observed that intrinsic inhomogeneities with the statistical scaling properties of a Griffiths phase appear, and determine the spin structure of the localized impurities. The appearance of the inhomogeneities is enhanced by appropriate phonons and acts destructively on the spin ordering. The inhomogeneities appear on well defined length scales, can be compared to the formation of intrinsic mesoscopic metastable patterns which are found in two-fluid systems.Comment: 9 pages, to appear in Jour. Superconductivit

Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters

The first enantioselective Pd-catalyzed construction of all-carbon quaternary stereocenters via 1,4-addition of arylboronic acids to β-substituted cyclic enones is reported. Reaction of a wide range of arylboronic acids and cyclic enones using a catalyst prepared from Pd(OCOCF_3)_2 and a chiral pyridinooxazoline ligand yields enantioenriched products bearing benzylic stereocenters. Notably, this transformation is tolerant to air and moisture, providing a practical and operationally simple method of synthesizing enantioenriched all-carbon quaternary stereocenters

Microlensing By a Prolate All-Macho Halo

It is widely believed that dark matter halos are flattened, that is closer to oblate than prolate. The evidence cited is based largely on observations of galaxies which do not look anything like our own and on numerical simulations which use ad hoc initial conditions. Given what we believe to be a ``reasonable doubt'' concerning the shape of dark Galactic halo we calculate the optical depth and event rate for microlensing of stars in the LMC assuming a wide range of models that include both prolate and oblate halos. We find, in agreement with previous analysis, that the optical depth for a spherical (E0) halo and for an oblate (E6) halo are roughly the same, essentially because two competing effects cancel approximately. However the optical depth for an E6 prolate halo is reduced by ~35%. This means that an all-Macho prolate halo with reasonable parameters for the Galaxy is consistent with the published microlensing event rate.Comment: 7 pages (24K), LaTeX; 2 Postscript figure

The ‘Diverse Economies’ of Participation

This article begins to construct a theory of participation in architecture, urban design and urban planning as a range of practices undertaken across a landscape of economies that largely exists outside of the capitalist economy. These practices themselves overlap in terms of their material forms, bodily and mental activities with the practices undertaken by labour employed to produce the built environment within the capitalist marketplace. With respect to participation, our aim in articulating practices is to move away from a discussion of levels of participation and legitimacy within individual projects and towards an understanding of the organising, productive and reproductive work that is done in participating in the production of the built environment as part of an ongoing process of social change. They proliferate through multiple instances of performance and those who undertake them act as carriers of these practices, including forms of knowhow, understanding, motivational and emotional knowledge, creating resources through these acts of performance. The article contends that participatory practices are liable to be exploited re-presented or co-opted as commodified resources and this fragility limits the socially transformative potential of participation. Drawing on J.K Gibson-Graham’s conception of ‘diverse economies’, an alternative representation is developed to recognize the landscape of practices constructing alternative economic systems, and exploring means and methods of resistance to co-option or enclosure

Mechanistic analysis of an asymmetric palladium-catalyzed conjugate addition of arylboronic acids to β-substituted cyclic enones.

An asymmetric palladium-catalyzed conjugate addition reaction of arylboronic acids to enone substrates was investigated mechanistically. Desorption electrospray ionization coupled to mass spectrometry was used to identify intermediates of the catalytic cycle and delineate differences in substrate reactivity. Our findings provide evidence for the catalytic cycle proceeding through formation of an arylpalladium(II) cation, subsequent formation of an arylpalladium-enone complex, and, ultimately, formation of the new C-C bond. Reaction monitoring in both positive and negative ion modes revealed that 4-iodophenylboronic acid formed a relatively stable trimeric species under the reaction conditions

External Shear in Quadruply Imaged Lens Systems

We use publicly available N-body simulations and semi-analytic models of galaxy formation to estimate the levels of external shear due to structure near the lens in gravitational lens systems. We also describe two selection effects, specific to four-image systems, that enhance the probability of observing systems to have higher external shear. Ignoring additional contributions from "cosmic shear" and assuming that lens galaxies are not significantly flattened, we find that the mean shear at the position of a quadruple lens galaxy is 0.11, the rms shear is roughly 0.15, and there is roughly a 45% likelihood of external shear greater than 0.1. This is much larger than previous estimates and in good agreement with typical measured external shear. The higher shear primarily stems from the tendency of early-type galaxies, which are the majority of lenses, to reside in overdense regions.Comment: 5 pages, 2 figures, ApJ in press, minor revision

An LED-based Flasher System for VERITAS

We describe a flasher system designed for use in monitoring the gains of the photomultiplier tubes used in the VERITAS gamma-ray telescopes. This system uses blue light-emitting diodes (LEDs) so it can be operated at much higher rates than a traditional laser-based system. Calibration information can be obtained with better statistical precision with reduced loss of observing time. The LEDs are also much less expensive than a laser. The design features of the new system are presented, along with measurements made with a prototype mounted on one of the VERITAS telescopes.Comment: Accepted for publication in Nuclear Instruments and Methods in Physics Research

Are patient specific meshes required for EIT head imaging?

Head imaging with electrical impedance tomography (EIT) is usually done with time-differential measurements, to reduce time-invariant modelling errors. Previous research suggested that more accurate head models improved image quality, but no thorough analysis has been done on the required accuracy. We propose a novel pipeline for creation of precise head meshes from magnetic resonance imaging and computed tomography scans, which was applied to four different heads. Voltages were simulated on all four heads for perturbations of different magnitude, haemorrhage and ischaemia, in five different positions and for three levels of instrumentation noise. Statistical analysis showed that reconstructions on the correct mesh were on average 25% better than on the other meshes. However, the stroke detection rates were not improved. We conclude that a generic head mesh is sufficient for monitoring patients for secondary strokes following head trauma