483 research outputs found

    Exactly Solvable Balanced Tenable Urns with Random Entries via the Analytic Methodology

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    This paper develops an analytic theory for the study of some Polya urns with random rules. The idea is to extend the isomorphism theorem in Flajolet et al. (2006), which connects deterministic balanced urns to a differential system for the generating function. The methodology is based upon adaptation of operators and use of a weighted probability generating function. Systems of differential equations are developed, and when they can be solved, they lead to characterization of the exact distributions underlying the urn evolution. We give a few illustrative examples.Comment: 23rd International Meeting on Probabilistic, Combinatorial, and Asymptotic Methods for the Analysis of Algorithms (AofA'12), Montreal : Canada (2012

    Impact of an improved shortwave radiation scheme in the MAECHAM5 General Circulation Model

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    International audienceIn order to improve the representation of ozone absorption in the stratosphere of the MAECHAM5 general circulation model, the spectral resolution of the shortwave radiation parameterization used in the model has been increased from 4 to 6 bands. Two 20-years simulations with the general circulation model have been performed, one with the standard and the other with the newly introduced parameterization respectively, to evaluate the temperature and dynamical changes arising from the two different representations of the shortwave radiative transfer. In the simulation with the increased spectral resolution in the radiation parameterization, a significant warming of almost the entire model domain is reported. At the summer stratopause the temperature increase is about 6 K and alleviates the cold bias present in the model when the standard radiation scheme is used. These general circulation model results are consistent both with previous validation of the radiation scheme and with the offline clear-sky comparison performed in the current work with a discrete ordinate 4 stream scattering line by line radiative transfer model. The offline validation shows a substantial reduction of the daily averaged shortwave heating rate bias (1?2 K/day cooling) that occurs for the standard radiation parameterization in the upper stratosphere, present under a range of atmospheric conditions. Therefore, the 6 band shortwave radiation parameterization is considered to be better suited for the representation of the ozone absorption in the stratosphere than the 4 band parameterization. Concerning the dynamical response in the general circulation model, it is found that the reported warming at the summer stratopause induces stronger zonal mean zonal winds in the middle atmosphere. These stronger zonal mean zonal winds thereafter appear to produce a dynamical feedback that results in a dynamical warming (cooling) of the polar winter (summer) mesosphere, caused by an increased downward (upward) circulation in the winter (summer) hemisphere. In addition, the comparison of the two simulations performed with the general circulation model shows that the increase in the spectral resolution of the shortwave radiation and the associated changes in the cloud optical properties result in a warming (0.5?1 K) and moistening (3%?12%) of the upper tropical troposphere. By comparing these modeled differences with previous works, it appears that the reported changes in the solar radiation scheme contribute to improve the model mean temperature also in the troposphere

    Biomass burning emissions estimated with a global fire assimilation system based on observed fire radiative power

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    The Global Fire Assimilation System (GFASv1.0) calculates biomass burning emissions by assimilating Fire Radiative Power (FRP) observations from the MODIS instruments onboard the Terra and Aqua satellites. It corrects for gaps in the observations, which are mostly due to cloud cover, and filters spurious FRP observations of volcanoes, gas flares and other industrial activity. The combustion rate is subsequently calculated with land cover-specific conversion factors. Emission factors for 40 gas-phase and aerosol trace species have been compiled from a literature survey. The corresponding daily emissions have been calculated on a global 0.5° × 0.5° grid from 2003 to the present. General consistency with the Global Fire Emission Database version 3.1 (GFED3.1) within its accuracy is achieved while maintaining the advantages of an FRP-based approach: GFASv1.0 makes use of the quantitative information on the combustion rate that is contained in the FRP observations, and it detects fires in real time at high spatial and temporal resolution. GFASv1.0 indicates omission errors in GFED3.1 due to undetected small fires. It also exhibits slightly longer fire seasons in South America and North Africa and a slightly shorter fire season in Southeast Asia. GFASv1.0 has already been used for atmospheric reactive gas simulations in an independent study, which found good agreement with atmospheric observations. We have performed simulations of the atmospheric aerosol distribution with and without the assimilation of MODIS aerosol optical depth (AOD). They indicate that the emissions of particulate matter need to be boosted by a factor of 2–4 to reproduce the global distribution of organic matter and black carbon. This discrepancy is also evident in the comparison of previously published top-down and bottom-up estimates. For the time being, a global enhancement of the particulate matter emissions by 3.4 is recommended. Validation with independent AOD and PM10 observations recorded during the Russian fires in summer 2010 show that the global Monitoring Atmospheric Composition and Change (MACC) aerosol model with GFASv1.0 aerosol emissions captures the smoke plume evolution well when organic matter and black carbon are enhanced by the recommended factor. In conjunction with the assimilation of MODIS AOD, the use of GFASv1.0 with enhanced emission factors quantitatively improves the forecast of the aerosol load near the surface sufficiently to allow air quality warnings with a lead time of up to four days

    Direct observation of active material concentration gradients and crystallinity breakdown in LiFePO4 electrodes during charge/discharge cycling of lithium batteries

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    The phase changes that occur during discharge of an electrode comprised of LiFePO4, carbon, and PTFE binder have been studied in lithium half cells by using X-ray diffraction measurements in reflection geometry. Differences in the state of charge between the front and the back of LiFePO4 electrodes have been visualized. By modifying the X-ray incident angle the depth of penetration of the X-ray beam into the electrode was altered, allowing for the examination of any concentration gradients that were present within the electrode. At high rates of discharge the electrode side facing the current collector underwent limited lithium insertion while the electrode as a whole underwent greater than 50% of discharge. This behavior is consistent with depletion at high rate of the lithium content of the electrolyte contained in the electrode pores. Increases in the diffraction peak widths indicated a breakdown of crystallinity within the active material during cycling even during the relatively short duration of these experiments, which can also be linked to cycling at high rate

    Numerical Prediction of Dust

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    Covers the whole breadth of mineral dust research, from a scientific perspective Presents interdisciplinary work including results from field campaigns, satellite observations, laboratory studies, computer modelling and theoretical studies Explores the role of dust as a player and recorder of environmental change This volume presents state-of-the-art research about mineral dust, including results from field campaigns, satellite observations, laboratory studies, computer modelling and theoretical studies. Dust research is a new, dynamic and fast-growing area of science and due to its multiple roles in the Earth system, dust has become a fascinating topic for many scientific disciplines. Aspects of dust research covered in this book reach from timescales of minutes (as with dust devils, cloud processes, and radiation) to millennia (as with loess formation and oceanic sediments), making dust both a player and recorder of environmental change. The book is structured in four main parts that explore characteristics of dust, the global dust cycle, impacts of dust on the Earth system, and dust as a climate indicator. The chapters in these parts provide a comprehensive, detailed overview of this highly interdisciplinary subject. The contributions presented here cover dust from source to sink and describe all the processes dust particles undergo while travelling through the atmosphere. Chapters explore how dust is lifted and transported, how it affects radiation, clouds, regional circulations, precipitation and chemical processes in the atmosphere, and how it deteriorates air quality. The book explores how dust is removed from the atmosphere by gravitational settling, turbulence or precipitation, how iron contained in dust fertilizes terrestrial and marine ecosystems, and about the role that dust plays in human health. We learn how dust is observed, simulated using computer models and forecast. The book also details the role of dust deposits for climate reconstructions. Scientific observations and results are presented, along with numerous illustrations. This work has an interdisciplinary appeal and will engage scholars in geology, geography, chemistry, meteorology and physics, amongst others with an interest in the Earth system and environmental change
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