Environmental impact reduction of precast multi-storey buildings by crescent-moon seismic dampers hidden in beam-column joints

The growing demand of sustainable precast structures for multi-storey con-structions is often driven by the optimisation of cross-sections and reinforcement volumes of the structural elements. The present paper describes a real building recently designed and assembled with the installation of crescent-moon hysteretic dampers in the beam-column joints, recently proposed and patented. The joint continuity allows for an optimisation of the lateral load resist-ing system, reducing the size of the columns with respect to the classical precast frame structural arrangement with hinged joints, whilst protecting columns and beams from the large actions deriving from the classical moment-resisting cast-in-situ or partially precast technological solu-tions. After the complete detailed design of the case study building employing the 3 solutions described above, the precast dissipative one being designed with dynamic non-linear analysis, the results of an environmental impact analysis are compared and discussed, confirming a reduced environmental impact for the dissipative solution, with respect to both precast with hinged beam-column joints and moment-resisting cast-in-situ alternatives

A Simplified Parametric Study on Occupant Comfort Conditions in Base Isolated Buildings under Wind Loading

Vibrations in buildings can cause occupant discomfort in the form of annoyance, headache, or sickness. While occupant comfort is considered in international standards regarding the design of high rise buildings against wind loading, it is neglected in the design of buildings with seismic protective base isolation systems. Nevertheless, due to their low flexibility, base isolated buildings can be prone to wind-induced vibrations, which makes occupant discomfort a potentially significant serviceability limit state. This paper presents a study on occupant comfort conditions in wind-excited base isolated buildings. A numerical simplified parametric procedure is proposed in order to evaluate the return period of wind events causing human discomfort. A parametric investigation is then presented to evaluate the effects of salient parameters on comfort conditions. The procedure is based on (i) the nonlinear dynamic analysis of the structure modeled as a single-degree-of-freedom oscillator with hysteretic base isolators, (ii) the digital generation of time histories of turbulent wind velocity, and (iii) comfort evaluations based on international standards. Results demonstrate that discomfort conditions can occur a few times in a year, depending upon the wind-exposure of the site, what suggests considering this serviceability limit state in the design of base isolated buildings

Room-Temperature O3 Detection: Zero-Bias Sensors Based on ZnO Thin Films

ZnO thin films with a thickness of 300 nm were deposited on Si and Al2O3 substrates using an electron beam evaporation technique with the aim of testing them as low cost and low power consumption gas sensors for ozone (O3). Scanning electron microscopy and atomic force microscopy were used to characterize the film surface morphology and quantify the roughness and grain size, recognized as the primary parameters influencing the gas sensitivity due to their direct impact on the effective sensing area. The crystalline structure and elemental composition were studied through Raman spectroscopy and X-ray photoelectron spectroscopy. Gas tests were conducted at room temperature and zero-bias voltage to assess the sensitivity and response as a function of time of the films to O3 pollutant. The results indicate that the films deposited on Al2O3 exhibit promising characteristics, such as high sensitivity and a very short response time (<2 s) to the gas concentration. Additionally, it was observed that the films display pronounced degradation effects after a significant exposure to O3

Low Electron Affinity Silicon/Nanocrystalline Diamond Heterostructures for Photon-Enhanced Thermionic Emission

Photon-enhanced thermionic emission (PETE) is a physical mechanism based on the electron’s emission from photon absorption and thermalization, which can be highly efficient to convert concentrated sunlight. Here, we demonstrate that nanocrystalline diamond thin films deposited on heavily doped p-type silicon absorbers can be potentially efficient PETE cathodes, showing a low χ value of ∼0.4 eV. A detailed analysis has been carried out as a function of the film thickness by correlating the PETE performance under concentrated sunlight with several chemical-physical measurements. The results highlight that grain boundaries are decisive to achieve the highest emission current density obtained with an 80 nm-thick emitter

Photon-enhanced thermionic emission devices with perovskite photovoltaic anodes for conversion of concentrated sunlight

Perovskite photovoltaic (PV) structures have been applied for the first time as anodes in photon-enhanced thermionic emission (PETE) devices to collect electrons as well as to photoelectrically convert the radiation emitted from high temperature silicon/diamond cathodes. Hybrid PETE-PV devices have been tested under concentrated sunlight, reaching the maximum cathode temperature of 650 °C. Experiments show that the PV anodes can operate without damage up to a cathode temperature of 560 °C, corresponding to an approximate surface anode temperature of 130 °C. The proposed converters in a 2-terminals configuration confirm an output voltage boost with respect to the mere PETE converters. Additionally, an effective reduction of the anode work function between 0.45 and 0.6 eV is achieved by depositing a 20 nm-thick scandium oxide coating. Even if the materials used for these proof-of-concept experiments are not optimized for the investigated operating temperature range, this study highlights the feasibility of using perovskites as photovoltaic anodes in PETE devices for the conversion of the concentrated solar radiation, thus opening the path for future development of the concept to large-area and low production cost perovskite PV-based structures in thermionic-based energy converters

Recycling of multilayer packaging waste with switchable anionic surfactants

Switchable Anionic Surfactants (SAS) were used for delaminating flexible packaging waste composed of various plastic layers and aluminium, thereby promoting the recycling of such waste streams from a circular economy perspective. The delamination protocol was optimized on de-pulped food and beverage cartons containing low-density polyethylene (LDPE) and aluminium, varying the carboxylic acid and its counterion constituting the SAS (C8[sbnd]C18 carboxylic acids as the anionic part; inorganic bases and primary, secondary and tertiary amines as the cationic one) their molar ratio (carboxylic acid: base molar ratio from 1:1 to 1:3), SAS concentration (0.15, 0.3 and 0.5 wt%), time (0.5–3 h) and material weight in input (1–10 wt%). High-quality LDPE and aluminium were separated and recovered by using a diluted solution of a surfactant based on lauric acid and triethanolamine (C12-TEA), with performances not achievable with other anionic or cationic surfactants available on the market. The C12-TEA solution was then applied to a large variety of multilayer waste materials composed of polypropylene and aluminium, polyolefins/polyethylene terephthalate/aluminium, giving a material separation dependant on the structure and composition of the material in input. At the end of the process, lauric acid was recovered from the aqueous solution used for washing the separated materials by tuning its water solubility with CO2

Charge transport mechanisms of black diamond at cryogenic temperatures

Black diamond is an emerging material for solar applications. The femtosecond laser surface treatment of pristine transparent diamond allows the solar absorptance to be increased to values greater than 90% from semi-transparency conditions. In addition, the defects introduced by fs-laser treatment strongly increase the diamond surface electrical conductivity and a very-low activation energy is observed at room temperature. In this work, the investigation of electronic transport mechanisms of a fs-laser nanotextured diamond surface is reported. The charge transport was studied down to cryogenic temperatures, in the 30–300 K range. The samples show an activation energy of a few tens of meV in the highest temperature interval and for T < 50 K, the activation energy diminishes to a few meV. Moreover, thanks to fast cycles of measurement, we noticed that the black-diamond samples also seem to show a behavior close to ferromagnetic materials, suggesting electron spin influence over the transport properties. The mentioned properties open a new perspective in designing novel diamond-based biosensors and a deep knowledge of the charge-carrier transport in black diamond becomes fundamental

Aluminum (Oxy)nitride thin films grown by fs-PLD as electron emitters for thermionic applications

Thin films based on aluminum nitride were obtained by fs-laser assisted Pulsed Laser Deposition (fs-PLD) at room temperature on tantalum substrates for studying the electron emission performance in the temperature range 700- 1600 °C, so to investigate the possibility of their exploitation as thermionic cathodes. Results of structural, chemical and morphological analyses show the growth of nanostructured thin films with a significant oxygen contamination, forming a mixture of crystalline aluminum nitride and aluminum oxide as well as metallic aluminum inclusions. Despite the considerable presence of oxygen, the developed cathodes demonstrate to possess promising thermionic emission characteristics, with a work function of 3.15 eV, a valuable Richardson constant of 20.25 A/(cm²K²), and a highly thermo-electronic stability up to operating temperatures of 1600 °C

Enhancement of Magnetic Stability in Antiferromagnetic CoO Films by Adsorption of Organic Molecules

Antiferromagnets are a class of magnetic materials of great interest in spintronic devices because of their stability and ultrafast dynamics. When interfaced with an organic molecular layer, antiferromagnetic (AF) films are expected to form a spinterface that can allow fine control of specific AF properties. In this paper, we investigate spinterface effects on CoO, an AF oxide. To access the magnetic state of the antiferromagnet, we couple it to a ferromagnetic Co film via an exchange bias (EB) effect. In this way, the formation of a spinterface is detected through changes induced on the CoO/Co EB system. We demonstrate that C60 and Gaq3 adsorption on CoO shifts its blocking temperature; in turn, an increase in both the EB fields and the coercivities is observed on the EB-coupled Co layer. Ab initio calculations for the CoO/C60 interface indicate that the molecular adsorption is responsible for a charge redistribution on the CoO layer that alters the occupation of the d orbitals of Co atoms and, to a smaller extent, the p orbitals of oxygen. As a result, the AF coupling between Co atoms in the CoO is enhanced. Considering the granular nature of CoO, a larger AF stability upon molecular adsorption is then associated with a larger number of AF grains that are stable upon reversal of the Co layer