A General Study of the Influence of Catastrophic Photometric Redshift Errors on Cosmology with Cosmic Shear Tomography

A goal of forthcoming imaging surveys is to use weak gravitational lensing shear measurements to constrain dark energy. We quantify the importance of uncalibrated photometric redshift outliers to the dark energy goals of forthcoming imaging surveys in a manner that does not assume any particular photometric redshift technique or template. In so doing, we provide an approximate blueprint for computing the influence of specific outlier populations on dark energy constraints. We find that outliers whose photo-z distributions are tightly localized about a significantly biased redshift must be controlled to a per-galaxy rate of <~ a few times 10^-3 to insure that systematic errors on dark energy parameters are rendered negligible. In the complementary limit, a subset of imaged galaxies with uncalibrated photometric redshifts distributed over a broad range must be limited to fewer than a per-galaxy error rate of <~ a few times 10^-4. Additionally, we explore the relative importance of calibrating the photo-z's of a core set of relatively well-understood galaxies as compared to the need to identify potential catastrophic photo-z outliers. We discuss the degradation of the statistical constraints on dark energy parameters induced by excising source galaxies at high- and low-photometric redshifts, concluding that removing galaxies with z_phot >~ 2.4 and z_phot <~ 0.3 may mitigate damaging catastrophic redshift outliers at a relatively small (~ 20%) cost in statistical error. In an appendix, we show that forecasts for the degradation in dark energy parameter constraints due to uncertain photometric redshifts depend sensitively on the treatment of the nonlinear matter power spectrum. Previous work using PD96 may have overestimated the photo-z calibration requirements of future surveys.Comment: 18 pages, 7 figures, references added, minor changes to address points made by referee, accepted for publication in Ap

Corporal punishment and youth externalizing behavior in Santiago, Chile

OBJECTIVES: Corporal punishment is still widely practiced around the globe, despite the large body of child development research that substantiates its short- and long-term consequences. Within this context, this paper examined the relationship between parental use of corporal punishment and youth externalizing behavior with a Chilean sample to add to the growing empirical evidence concerning the potential relationship between increased corporal punishment and undesirable youth outcomes across cultures. METHODS: Analysis was based on 919 adolescents in Santiago, Chile. Descriptive and multivariate analyses were conducted to examine the extent to which parents' use of corporal punishment and positive family measures were associated with youth externalizing behavior. Furthermore, the associations between self-reported externalizing behavior and infrequent, as well as frequent, use of corporal punishment were investigated to understand how varying levels of parental use of corporal punishment were differently related to youth outcomes. RESULTS: Both mothers' and fathers' use of corporal punishment were associated with greater youth externalizing behavior. Additionally, increases in positive parenting practices, such as parental warmth and family involvement, were met with decreases in youth externalizing behavior when controlling for youth demographics, family socioeconomic status, and parents' use of corporal punishment. Finally, both infrequent and frequent use of corporal punishment were positively associated with higher youth problem behaviors, though frequent corporal punishment had a stronger relationship with externalizing behavior than did infrequent corporal punishment. CONCLUSIONS: Parental use of corporal punishment, even on an occasional basis, is associated with greater externalizing behavior for youth while a warm and involving family environment may protect youth from serious problem behaviors. Therefore, findings of this study add to the growing evidence concerning the negative consequences of corporal punishment for youth outcomes.R01 HD033487 - NICHD NIH HHS; R01 DA021181 - NIDA NIH HH

Covalently bonded interfaces for polymer/graphene composites

The interface is well known for taking a critical role in the determination of the functional and mechanical properties of polymer composites. Previous interface research has focused on utilising reduced graphene oxide that is limited by a low structural integrity, which means a high fraction is needed to produce electrically conductive composites. By using 4,40-diaminophenylsulfone, we in this study chemically modified high-structural integrity graphene platelets (GnPs) of 2–4 nm in thickness, covalently bonded GnPs with an epoxy matrix, and investigated the morphology and functional and mechanical performance of these composites. This covalently bonded interface prevented GnPs stacking in the matrix. In comparison with unmodified composites showing no reduction in electrical volume resistivity, the interface-modified composite at 0.489 vol% GnPs demonstrates an eight-order reduction in the resistivity, a 47.7% further improvement in modulus and 84.6% in fracture energy release rate. Comparison of GnPs with clay and multi-walled carbon nanotubes shows that our GnPs are more advantageous in terms of performance and cost. This study provides a novel method for developing interface-tuned polymer/graphene composites

Luminosity Dependence in the Fundamental Plane Projections of Elliptical Galaxies

We analyze the fundamental plane projections of elliptical galaxies as a function of luminosity, using a sample of approximately 80,000 galaxies drawn from Data Release 4 (DR4) of the Sloan Digital Sky Survey (SDSS). We separate brightest cluster galaxies (BCGs) from our main sample and reanalyze their photometry due to a problem with the default pipeline sky subtraction for BCGs. The observables we consider are effective radius (R_e), velocity dispersion (sigma), dynamical mass (M_dyn ~ R_e sigma2), effective density (sigma2/R_e2), and effective surface brightness (mu_e). With the exception of the L-M_dyn correlation, we find evidence of variations in the slope (i.e. the power-law index) of the fundamental plane projections with luminosity for our normal elliptical galaxy population. In particular, the radius-luminosity and Faber-Jackson relations are steeper at high luminosity relative to low luminosity, and the more luminous ellipticals become progressively less dense and have lower surface brightnesses than lower luminosity ellipticals. These variations can be understood as arising from differing formation histories, with more luminous galaxies having less dissipation. Data from the literature and our reanalysis of BCGs show that BCGs have radius-luminosity and Faber-Jackson relations steeper than the brightest non-BCG ellipticals in our sample, consistent with significant growth of BCGs via dissipationless mergers. The variations in slope we find in the Faber-Jackson relation of non-BCGs are qualitatively similar to that reported in the black hole mass-velocity dispersion (M_BH-sigma) correlation. This similarity is consistent with a roughly constant value of M_BH/M_star over a wide range of early type galaxies, where M_star is the stellar mass.Comment: v2: expanded analysis of BCGs; 17 pages, 9 figures; accepted in MNRA

An alternate proton acceptor for excited-state proton transfer in green fluorescent protein: Rewiring GFP

The neutral form of the chromophore in wild-type green fluorescent protein (wtGFP) undergoes excited-state proton transfer (ESPT) upon excitation, resulting in characteristic green (508 nm) fluorescence. This ESPT reaction involves a proton relay from the phenol hydroxyl of the chromophore to the ionized side chain of E222, and results in formation of the anionic chromophore in a protein environment optimized for the neutral species (the I* state). Reorientation or replacement of E222, as occurs in the S65T and E222Q GFP mutants, disables the ESPT reaction and results in loss of green emission following excitation of the neutral chromophore. Previously, it has been shown that the introduction of a second mutation (H148D) into S65T GFP allows the recovery of green emission, implying that ESPT is again possible. A similar recovery of green fluorescence is also observed for the E222Q/H148D mutant, suggesting that D148 is the proton acceptor for the ESPT reaction in both double mutants. The mechanism of fluorescence emission following excitation of the neutral chromophore in S65T/H148D and E222Q/H148D has been explored through the use of steady state and ultrafast time-resolved fluorescence and vibrational spectroscopy. The data are contrasted with those of the single mutant S65T GFP. Time-resolved fluorescence studies indicate very rapid (<1 ps) formation of I* in the double mutants, followed by vibrational cooling on the picosecond time scale. The time-resolved IR difference spectra are markedly different to those of wtGFP or its anionic mutants. In particular, no spectral signatures are apparent in the picosecond IR difference spectra that would correspond to alteration in the ionization state of D148, leading to the proposal that a low-barrier hydrogen bond (LBHB) is present between the phenol hydroxyl of the chromophore and the side chain of D148, with different potential energy surfaces for the ground and excited states. This model is consistent with recent high-resolution structural data in which the distance between the donor and acceptor oxygen atoms is =2.4 Å. Importantly, these studies indicate that the hydrogen-bond network in wtGFP can be replaced by a single residue, an observation which, when fully explored, will add to our understanding of the various requirements for proton-transfer reactions within proteins

Micro-encapsulated phase change material (MPCM) slurries: characterization and building applications

© 2017 Micro-encapsulated Phase Change Material (MPCM) slurries, acting as the heat transfer fluids or thermal storage mediums, have gained applications in various building thermal energy systems, significantly enhancing their energy efficiency and operational performance. This paper presents a review of research on MPCM slurries and their building applications. The research collects information on the currently available MPCM particles and shells, studies of the physical, structural and thermal stability, and rheological properties of MPCM slurries, and identification/determination of the critical parameters and dimensionless numbers relating to the MPCM slurries’ heat transfer. The research suggests possible approaches for enhancing the heat transfer between a MPCM slurry and its surroundings, while several controversial phenomena and potential causes were also investigated. Furthermore, the research presents mathematical correlations established between different thermal and physical parameters relating to the MPCM slurries, and introduces a number of practical applications of the MPCM slurries in building thermal energy systems. Based on such extensive review and analyses, the research will help in identifying the current status, potential problems in existence, and future directions in research, development and practical application of MPCM slurries. It will also promote the development and application of cost-effective and energy-efficient PCM materials and thus contribute to achieving the UK and international targets in energy saving and carbon emission reductions in the building sector and beyond