4,888 research outputs found

    Evidence for structural stacking and repetition in the greenstones of the Kalgoorlie district, western Australia

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    Most previous stratigraphic interpretations of the southern part of the Norseman-Wiluna Greenstone Belt have proposed polycyclic sequences. These invoked two and sometimes three successive suites of mafic and/or ultimafic volcanics and intrusives separated by felsic volcanics and immature clastic sediments, however no distinctive lithological differences were reported between successive mafic-ultramaic sequences. When interpretations of the area further to the north are integrated, a total of four separate major mafic-ultramafic uites emerges for a large part of the Norseman-Wiluna Belt. Although the author does not intent to imply that all polycyclic stratigraphies are wrong in principle such a situation seems suspiciously over-complex and stimulates the need to look critically at the individual areas where the stratigraphies have seen erected. For the Kalgoorlie area in the south, some of the schemes have already provoked scepticism and a simpler model consisting of one cycle subject to structural repetition has been evolved by workers in the Geological Survey of Western Australia for part of this area. The latter drew attention to the carbon copy similarity between the elements of some polycyclic stratigraphies. Much more regionally extensive integrated structural and stratigraphic data is still required to evaluate the relationship between structure and stratigraphy more fully, an objective substantially limited by poor outcrop and deep weathering, but with due effort, far from unattainable

    Infrared spectrum and stability of a π-type hydrogen-bonded complex between the OH and C2H2 reactants

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    A hydrogen-bonded complex between the hydroxyl radical and acetylene has been stabilized in the reactant channel well leading to the addition reaction and characterized by infrared action spectroscopy in the OH overtone region. Analysis of the rotational band structure associated with the a-type transition observed at 6885.53(1) cm−1 (origin) reveals a T-shaped structure with a 3.327(5) Å separation between the centers of mass of the monomer constituents. The OH (v = 1) product states populated following vibrational predissociation show that dissociation proceeds by two mechanisms: intramolecular vibrational to rotational energy transfer and intermolecular vibrational energy transfer. The highest observed OH product state establishes an upper limit of 956 cm−1 for the stability of the π-type hydrogen-bonded complex. The experimental results are in good accord with the intermolecular distance and well depth at the T-shaped minimum energy configuration obtained from complementary ab initio calculations, which were carried out at the restricted coupled cluster singles, doubles, noniterative triples level of theory with extrapolation to the complete basis set limit

    The relationship between nature relatedness and anxiety.

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    This study investigated the relationship between anxiety and feelings of being connected to nature. Two standardised self-report scales, the Nature Relatedness Scale and the State Trait Inventory for Cognitive and Somatic Anxiety, were used in tandem with a qualitative question. Quantitative results indicated that connection to nature was significantly related to lower levels of overall, state cognitive and trait cognitive anxiety. Qualitative results revealed seven themes: relaxation, time out, enjoyment, connection, expanse, sensory engagement and a healthy perspective. Taken together, these results suggest that opportunities that enhance experiences of being connected to nature may reduce unhelpful anxiety

    ZnO nanorod-arrays as photo-(electro)chemical materials: strategies designed to overcome the material's natural limitations

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    The urgent need for clean and storable energy drives many currently topical areas of materials research. Among the many materials under investigation zinc oxide is one of the most studied in relation to its use in photo-(electro)chemical applications. This study aims to give an overview of some of the main challenges associated with the use of zinc oxide for these applications: the high density of intrinsic defects which can lead to fast recombination, low visible light absorption and the occurrence of photo-corrosion. Employing simple low-temperature solution based methods; it is shown how defect-engineering can be used to increase the photo-electrochemical performance and how doping can strongly increase the visible light absorption of zinc oxide nanorod-arrays. Furthermore the deposition of ultra-thin titanium dioxide layers using atomic layer deposition is investigated as possible route for the protection of zinc oxide against photo-corrosion

    Methods for a rapid systematic review and meta-analysis in evaluating selective serotonin reuptake inhibitors for premature ejaculation

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    The aim of this study was to evaluate a rapid systematic review method in which randomised controlled trial (RCT) data was extracted from existing reviews and subsequent RCTs. The method enabled: identification of RCTs not included by existing reviews; cross-checking RCT data for consistency where there was more than one review; double data extraction due to time saved by extracting data from existing reviews; correction of data synthesis errors in existing reviews; and pooling data across all RCTs to produce contemporary effect estimates. When subsequently compared to extracting data directly from all RCT original publications, the findings and conclusions concurred
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