338 research outputs found
Self-Organization of Vortex Length Distribution in Quantum Turbulence: An Approach from the Barabasi-Albert Model
The energy spectrum of quantum turbulence obeys Kolmogorov's law. The vortex
length distribution (VLD), meaning the size distribution of the vortices, in
Kolmogorov quantum turbulence also obeys a power law. We propose here an
innovative idea to study the origin of the power law of the VLD. The nature of
quantized vortices allows one to describe the decay of quantum turbulence with
a simple model that is similar to the Barabasi-Albert model of large networks.
We show here that such a model can reproduce the power law of the VLD well.Comment: 4 pages including 5 figure
A Kelvin-wave cascade on a vortex in superfluid He at a very low temperature
A study by computer simulation is reported of the behaviour of a quantized
vortex line at a very low temperature when there is continuous excitation of
low-frequency Kelvin waves. There is no dissipation except by phonon radiation
at a very high frequency. It is shown that non-linear coupling leads to a net
flow of energy to higher wavenumbers and to the development of a simple
spectrum of Kelvin waves that is insensitive to the strength and frequency of
the exciting drive. The results are likely to be relevant to the decay of
turbulence in superfluid He at very low temperatures
The effective preparation of secondary amines bearing a vinylsilane functionality via the reaction of primary amines with alpha-chlorine-substituted allylsilanes catalysed by CuCl
http://www.ingentaconnect.com/content/stl/jcr/2007/00002007/00000008/art00009ArticleJOURNAL OF CHEMICAL RESEARCH-S. 2007(8): 464-467 (2007)journal articl
Effects of Gold Substrates on the Intrinsic and Extrinsic Activity of High-Loading Nickel-Based Oxyhydroxide Oxygen Evolution Catalysts
We systematically investigate the effects of Au substrates on the oxygen evolution activities of cathodically electrodeposited nickel oxyhydroxide (NiOOH), nickel–iron oxyhydroxide (NiFeOOH), and nickel–cerium oxyhydroxide (NiCeOOH) at varying loadings from 0 to 2000 nmol of metal/cm2. We determine that the geometric current densities, especially at higher loadings, were greatly enhanced on Au substrates: NiCeOOH/Au reached 10 mA/cm2 at 259 mV overpotential, and NiFeOOH/Au achieved 140 mA/cm2 at 300 mV overpotential, which were much greater than those of the analogous catalysts on graphitic carbon (GC) substrates. By performing a loading quantification using both inductively coupled plasma optical emission spectrometry and integration of the Ni2+/3+ redox peak, we show that the enhanced activity is predominantly caused by the stronger physical adhesion of catalysts on Au. Further characterizations using impedance spectroscopy and in situ X-ray absorption spectroscopy revealed that the catalysts on Au exhibited lower film resistances and higher number of electrochemically active metal sites.We attribute this enhanced activity to a more homogeneous electrodeposition on Au, yielding catalyst films with very high geometric current densities on flat substrates. By investigating the mass and site specific activities as a function of loading, we bridge the practical geometric activity to the fundamental intrinsic activity
Instability of vortex array and transitions to turbulent states in rotating helium II
We consider superfluid helium inside a container which rotates at constant
angular velocity and investigate numerically the stability of the array of
quantized vortices in the presence of an imposed axial counterflow. This
problem was studied experimentally by Swanson {\it et al.}, who reported
evidence of instabilities at increasing axial flow but were not able to explain
their nature. We find that Kelvin waves on individual vortices become unstable
and grow in amplitude, until the amplitude of the waves becomes large enough
that vortex reconnections take place and the vortex array is destabilized. The
eventual nonlinear saturation of the instability consists of a turbulent tangle
of quantized vortices which is strongly polarized. The computed results compare
well with the experiments. Finally we suggest a theoretical explanation for the
second instability which was observed at higher values of the axial flow
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